全文获取类型
收费全文 | 742篇 |
免费 | 68篇 |
国内免费 | 429篇 |
专业分类
安全科学 | 72篇 |
废物处理 | 28篇 |
环保管理 | 44篇 |
综合类 | 637篇 |
基础理论 | 125篇 |
污染及防治 | 233篇 |
评价与监测 | 36篇 |
社会与环境 | 40篇 |
灾害及防治 | 24篇 |
出版年
2024年 | 8篇 |
2023年 | 21篇 |
2022年 | 62篇 |
2021年 | 55篇 |
2020年 | 63篇 |
2019年 | 60篇 |
2018年 | 54篇 |
2017年 | 61篇 |
2016年 | 65篇 |
2015年 | 81篇 |
2014年 | 56篇 |
2013年 | 62篇 |
2012年 | 81篇 |
2011年 | 77篇 |
2010年 | 51篇 |
2009年 | 50篇 |
2008年 | 51篇 |
2007年 | 37篇 |
2006年 | 35篇 |
2005年 | 24篇 |
2004年 | 34篇 |
2003年 | 23篇 |
2002年 | 16篇 |
2001年 | 16篇 |
2000年 | 13篇 |
1999年 | 21篇 |
1998年 | 7篇 |
1997年 | 9篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 7篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 6篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有1239条查询结果,搜索用时 15 毫秒
161.
A model for evaluation of the phytoavailability of trace elements to vegetables under the field conditions 总被引:7,自引:0,他引:7
Currently, several single extraction methods are used for the evaluation of the phytoavailability of metals using pot experiments. A systematic comparison, however, is lacking. It is especially true for the field studies. This study was to investigate the phytoavailability of trace elements to vegetables grown on metal-contaminated soils under the field conditions. All soils collected were typical calcareous soils in northern China. Four frequently used methods using CaCl2, diethylenetriaminepentaacetic acid (DTPA), CH3COOH, and water as extractants were compared for phyto-availability. The concentrations of metals extracted by these four extraction methods ranged from 3.42 to 815, 1.51- 6965, 0.732-24473, 0.688-7863, 0.246-685, 1.99-5337 0.203-4649 ng/g for Cr, Ni, Zn, Cu, Cd, Pb and REEs, respectively. Simple correlation analysis indicated that a significant correlation (Cr: r = 0.5411**; Zn: r = 0.6352**; Cd: r = 0.6979**; Pb: r = 0.5537** and REEs: r = 0.5185** -0.6684**) was observed between the CaCl2-extractable metals in soil solution and that in Chinese cabbage. In addition, soil pH, organic matter (OM), and cation exchange capacity (CEC) also affect the phytoavailability. An empirical model was developed to express the combined effect of soil properties on the phytoavailability. The stepwise multiple regression analysis demonstrated that the phytoavailability of trace elements strongly correlated with the extractable fraction by CaCl2, total metal concentration in soils, and soil pH, OM, CEC. This model can describe approximately 75-95% of the variability of metal uptake and the r2 values ranged from 0.741** to 0.954**, which were much better than the single correlation analysis. For celery and cole, a strong correlation was obtained for Cr, Ni, Zn, Cu, Cd, La, Ce, Pr and Nd. For spinach and Chinese cabbage, however, a positive correlation was only observed for 1 and 3 metals, respectively. Generally, the developed empirical model can integrate the combined effects of soil properties, extractable metal fractions in soil solutions and plant species on the phytoavailability of metals to vegetables in the field conditions. 相似文献
162.
An analytical solution for vertical transport of volatile chemicals in the vadose zone 总被引:1,自引:0,他引:1
An analytical solution is presented for one-dimensional vertical transport of volatile chemicals through the vadose zone to groundwater. The solution accounts for the important transport mechanisms of the steady advection of water and gas, diffusion and dispersion in water and gas, as well as adsorption, and first-order degradation. By assuming a linear, equilibrium partitioning between water, gas and the adsorbed chemical phases, the dependent variable in the mathematical model becomes the total resident concentration. The general solution was derived for cases having a constant initial total concentration over a discrete depth interval and a zero initial total concentration elsewhere. A zero concentration gradient is assumed at the groundwater table. Examples are given to demonstrate the application of the new solution for calculating the case of a non-uniform initial source concentration, and estimating the transport of chemicals to the groundwater and the atmosphere. The solution was also used to verify a numerical code called VLEACH. We discovered an error in VLEACH, and found that the new solution agreed very well with the numerical results by corrected VLEACH. A simplified solution to predict the migration of volatile organic chemical due to the gas density effect has shown that a high source concentration may lead to significant downward advective gas-phase transport in a soil with a high air-permeability. 相似文献
163.
164.
利用UV/Fenton工艺对模拟间-甲苯酚废水进行了处理,研究了H2O2加入量、FeSO4加入量、pH、原水初始COD值、环境温度、反应时间等因素对COD去除率的影响.实验表明:间-甲苯酚浓度为100mg/L、初始COD值251 mg/L的废水,在30℃下,pH为4.Q,[H2O2]/[Fe2 ]=15(质量浓度比),紫外灯照射3 h后,COD去除率达86.3%,若再经Ca(OH)2絮凝沉降,则COD去除率提高到92.6%.同时,对Fenton及UV/Fenton的处理效果进行了比较,实验表明:UV/Fenton的处理效果明显优于Fenton法. 相似文献
165.
Comparison between fractionation and bioavailability of trace elements in rhizosphere and bulk soils 总被引:16,自引:0,他引:16
Rhizosphere is a microbiosphere and has quite different chemical, physical and biological properties from bulk soils. A greenhouse experiment was performed to compare the difference of fractionation and bioavailability of trace elements Cr, Ni, Zn, Cu, Pb and Cd between rhizosphere soil and bulk soil. In the meantime, the influence of air-drying on the fractionation and bioavailability was also investigated by using wet soil sample as a control. Soils in a homemade rhizobox were divided into four zones: rhizosphere, near rhizosphere, near bulk soil and bulk soil zones, which was designated as S1, S2, S3 and S4. Elemental speciations were fractionated to water soluble, exchangeable and carbonate bound (B1), Fe-Mn oxide bound (B2), and organic and sulfide bound (B3) by a sequential extraction procedure. Speciation differences were observed for elements Cr, Ni, Zn, Cu, Pb and Cd between the rhizosphere and bulk soils, and between the air-dried and wet soils as well. The concentrations of all six heavy metals in fraction B1 followed the order of S2 > S3 > S1 > S4 and for B2, the order was S2 > S3 S4 > S1. For B3, the order was S1 > S3 S4 > S2, while for Cd the order was S2 > S3 approximately/= S4 > S1. The air-drying increased elemental concentration in fractions B1 and B2 by 20-50% and decreased in fraction B3 by about 20-100%. Correlation analysis also indicated that the bioavailability correlation coefficient of fraction B1 in rhizosphere wet soil to plants was better than that between either air-dried or nonrhizosphere soils. Therefore, application of rhizosphere wet soils should be recommended in the future study on the speciation analysis of trace elements in soils and bioavailability. 相似文献
166.
167.
168.
污泥资源化是污泥处置的发展趋势,以脱水污泥为主料,添加适量粉煤灰和粘土,制备生物膜载体填料是实验研究的主要内容。实验表明,污泥使用量为70%、粉煤灰和粘土各15%时,烧成温度为1000±25℃、保温时间为40min,烧制的填料抗压强度能达到25mpa、吸水率17%;用于药厂废水处理测试,在常温下的化学需氧量(CODCr)的平均去除率为74.0%、悬浮物(SS)的去除率为54.1%。使用扫描电镜、显微镜像检测,分析了填料烧制中孔隙形成机理、填料外貌、表面微孔结构等。实验表明,以污泥代替天然原料,在一定条件下可以烧制成填料,并能用作污水处理中生物膜载体。 相似文献
169.
170.
Guobin Shan Rao Y. Surampalli Rajeshwar D. Tyagi Tian C. Zhang 《Frontiers of Environmental Science & Engineering in China》2009,3(3):249-264
Nanomaterials are applicable in the areas of reduction of environmental burden, reduction/treatment of industrial and agricultural
wastes, and nonpoint source (NPS) pollution control. First, environmental burden reduction involves green process and engineering,
emissions control, desulfurization/denitrification of nonrenewable energy sources, and improvement of agriculture and food
systems. Second, reduction/treatment of industrial and agricultural wastes involves converting wastes into products, groundwater
remediation, adsorption, delaying photocatalysis, and nanomembranes. Third, NPS pollution control involves controlling water
pollution. Nanomaterials alter physical properties on a nanoscale due to their high specific surface area to volume ratio.
They are used as catalysts, adsorbents, membranes, and additives to increase activity and capability due to their high specific
surface areas and nano-sized effects. Thus, nanomaterials are more effective at treating environmental wastes because they
reduce the amount of material needed. 相似文献