粒状羟基氧化铁对废水中硝酸盐的吸附

本实验研究了粒状羟基氧化铁(GFH)对人工配制含氮废水中NO3--N吸附的影响因素、吸附等温线和吸附动力学。结果表明,GFH的吸附平衡时间为80 min,增加NO3--N溶液的初始浓度,去除率下降;pH值为5时GFH对NO3--N的吸附能力最强,pH值升高和降低,吸附能力均下降;GFH对NO3--N的吸附能力随着温度的升高略有降低;在25℃下,以Langmuir方程和Freundlich方程分别对GFH吸附NO3--N的等温线进行拟合,拟合效果以Langmuir方程较好,相关性达到0.9930。GFH吸附NO3--N的过程符合拟二级动力学方程,初始时刻的吸附速率h在35℃时最大,为1.653 mg/(g.mg),吸附速率常数随温度的升高而增大;吸附反应的活化能Ea为54.72 kJ/mol。本研究结果表明,GFH在饮用水脱氮和含氮浓度较低的污水再生回用领域有实际应用的潜力。     

Photocatalytic oxidation of heptane in the gas-phase over TiO2.

In this paper, gas-phase photocatalytic oxidation (PCO) of heptane over UV-illuminated TiO2 was carried out at ambient temperature in a batch reactor. Complete oxidation of heptane with almost stoichiometric production of CO2 and H2O was observed. The intermediates detected were propanal, butanal, 3-heptanone, 4-heptanone and carbon monoxide. A scheme of the possible mechanism for PCO of heptane over TiO2 was suggested. Langmuir-Hinshelwood kinetics equation was obtained from the results at different initial concentrations of heptane, oxygen, moisture and light intensity. The photocatalytic activity of TiO2 can be sustained indefinitely. This can be attributed to the production of water in the system, which can replenish the consumed hydroxyl radicals.     

不同共代谢基质对四氯乙烯的厌氧生物降解研究

用驯化好的厌氧污泥对葡萄糖、乳酸盐和醋酸盐作为电子供体时四氯乙烯(PCE)的降解进行研究。实验结果表明,PCE是通过还原脱氯发生生物降解的。实验的回归结果表明,反应均符合一级动力学反应速率,常数的大小依次为k乳酸>k葡萄糖>k醋酸。表明乳酸盐作为电子供体时PCE的降解速率较快,说明在实验条件下乳酸盐是最合适的电子供体。并且在整个实验过程中由共代谢基质提供的电子供体不是PCE降解的限制因素。     

HPLC-UVD/FLD测定海洋环境样品中PAHs的研究

建立了ＨＰＬＣ－ＵＶＤ／ＦＬＤ测定海洋环境样品中ＰＡＨｓ的分析方法，探讨了紫外可变波长，荧光激发／发射波长，梯度斜率对ＰＡＨｓ响应因子和分离度的影响，得出了仪器的重复性，线性区间，检出限以及不同层析柱的回收率，测定了沉积物和贻贝样品中的ＰＡＨｓ。结果表明，方法的精密度和准确度是令人满意的。     

浅析绿色制造的战略环境评价

绿色制造的战略环境评价是实现可持续发展的关键技术 ,是协调环境与社会经济发展的重要手段。它要求在绿色制造初期———绿色设计阶段就考虑整个制造过程的环境影响 ,从决策源头上控制环境污染的产生和生态环境的破坏。本文从绿色制造的广义内涵入手 ,分析了绿色制造战略环境评价的理论基础和综合集成特性 ,并提出了战略环境评价的指标体系和综合集成评价方法。     

长春经济技术开发区环境风险预警系统

建立了一个环境风险预警系统的总体组织结构，探讨了具有多层次模块问题的模块管理系统，并结合长春经济技术开发区进行了实证分析。     

船舶生活污水处理中COD监测分析条件的控制

针对以粪便冲洗水为主的船舶生活污水中含有大量悬浮物的特点，提出了测定此类污水中ＣＯＤ时分析条件的控制方法。     

论战略环境评价中的公众参与

介绍了公众参与对于战略环境评价 ( SEA)的意义 ;着重分析了 SEA中公众参与实施的关键环节 :即公众参与者界定 ,公众参与内容 ,公众参与时机 ,公众参与方式及公众参与反馈信息处理 ,并阐述了 SEA中公众参与的局限性。     

不同共代谢基质对四氯乙烯的厌氧生物降解研究

用驯化好的厌氧污泥对葡萄糖、乳酸盐和醋酸盐作为电子供体时四氯乙烯（PCE）的降解进行研究.实验结果表明,PCE是通过还原脱氯发生生物降解的.实验的回归结果表明,反应均符合一级动力学反应速率,常数的大小依次为k乳酸＞k葡萄糖＞k醋酸.表明乳酸盐作为电子供体时PCE的降解速率较快,说明在实验条件下乳酸盐是最合适的电子供体.并且在整个实验过程中由共代谢基质提供的电子供体不是PCE降解的限制因素.     

The impacts of different kinds of dust events on PM10 pollution in northern China

In this study the frequencies of PM₁₀ (as key urban pollutant) in 14 key environmental protection cities in northern China were analyzed. It follows that the PM₁₀ concentration in the high-frequency period is higher with an extent 0.009–0.066 mg m⁻³ than in the low-frequency period of 2001–2002. Further the impacts of three kinds of dust events on the PM₁₀ concentration in four cities (Beijing, Hohhot, Xi’an and Lanzhou) were explored. The results showed that different kinds of dust events have different influences on variation of PM₁₀ concentration in these four cities. In Lanzhou and Hohhot, which are near the source areas of dust events, the contribution degree of these three dust events to the PM₁₀ is: floating dust>dust storm>blowing dust. Whereas, in Beijing and Xi’an situated in dust event passing areas, the mean value of PM₁₀ concentration is higher in blowing dust than in floating dust (no dust storm). In addition, the influences of dust events on PM₁₀ concentration are different in the cities on different dust event paths. In Beijing and Hohhot (on the northern path), the high PM₁₀ concentration is usually caused by blowing dust. But in both Lanzhou and Xi’an (on the western/northwestern path) the high PM₁₀ pollution concentration is usually caused by floating dust.