危险化学品道路运输安全评价体系的建立

近年来,危险化学品道路运输事故呈不断上升趋势,其危害性极强,社会影响极坏,危险化学品道路运输安全问题正成为人们普遍关注的问题。本文分析了国内外危险化学品道路运输安全现状,从我国危险化学品道路运输事故的影响因素、危险化学品事故原因等方面分析了我国危险化学品道路运输的特点。在此基础上,建立了我国危险化学品道路运输安全评价体系,对减少危险化学品道路运输事故具有一定的实践指导意义。     

隐患排查分析及治理对策

通过对北京经济技术开发区重点代表企业隐患排查实施的研究,将医药、印刷等不同行业存在的隐患加以分析,对分析出的突出问题进行剖析并提出相应的对策。     

Levels and distribution of polybrominated diphenyl ethers in plant, shellfish and sediment samples from Laizhou Bay in China

Polybrominated diphenyl ethers (PBDEs) are potentially harmful and persistent environmental pollutants. PBDEs concentrations are reported in plant, shellfish and sediment samples collected from Chinese Laizhou Bay. The summation operator(11)PBDE concentrations in plant and shellfish samples from Laizhou Bay were in the range of 70-5900ngg(-1) and 230-720ngg(-1) lipid, respectively. The summation operator(11)PBDEs concentrations in river sediment intervals samples ranged from 1.3 to 1800ng g(-1) dry weight. Pearson correlation analyses were performed on concentrations of PBDEs congeners of different sediment sample intervals. There were significant positive correlations for BDE 28 and BDE 100 (r=0.945, p<0.01), BDE 47 and BDE 99 (r=0.879, p<0.01), BDE 153 and BDE 154 (r=0.934, p<0.01), nona-BDEs and BDE 209 (r>0.934, p<0.01). BDE 209 was the predominant congener in all analyzed samples, consistent with the fact that deca-BDE technical mixtures are the dominant PBDEs product in Laizhou Bay. Data showed that PBDEs should be considered as an increasing pollution problem in the Laizhou Bay region.     

Pedological characteristics of Mn mine tailings and metal accumulation by native plants

In southern China revegetation and ecological restoration of many abandoned Mn tailings has become a major concern. To determine the major constraints for plant establishment and evaluate the feasibility of remediation, a comparative study was conducted on Mn tailings and rhizosphere soils at the boundary of the tailings pond. Both tailings and rhizosphere soils had neutral to slightly alkaline pH and normal electrical conductivity. They were both enriched with organic matter (6.8-9.2%), total N (1.77-5.94 g kg(-1)), available P (41.78-73.83 mg kg(-1)) and K (146.7-906.9 mg kg(-1)), suggesting the tailings were a nutrient rich substrate for revegetation. Mn tailings were clay textured, while rhizosphere soils were silty loam or clay loam. The compaction and anoxic nature of Mn tailings were considered to be the major constraints for plant establishment. Total Mn (31903 mg kg(-1)), Cd (119 mg kg(-1)), Cu (126 mg kg(-1)) and Zn (2490 mg kg(-1)) in tailings were all at phytotoxic levels, but did not differ significantly from those in rhizosphere soils. In both tailings and rhizosphere soils, percentages of water- and DTPA-extractable metals were less than 1% and 2% of the total metal pools, respectively. Sequential extraction revealed that the majority of Mn, Cu and Zn were associated with the residual fraction, while the majority of Cd occurred as Fe-Mn oxides. The natural succession of plants around Mn tailings formed a distinctive metal-tolerant plant community, mainly comprising nine species such as Cynodon dactylon and Humulus scandens and so on. All species studied could be good candidates for revegetation of Mn tailings.     

Atmospheric transport of urban-derived NH(x): Evidence from nitrogen concentration and delta(15)N in epilithic mosses at Guiyang, SW China

Nitrogen concentration and δ¹⁵N in 175 epilithic moss samples were investigated along four directions from urban to rural sites in Guiyang, SW China. The spatial variations of moss N concentration and δ¹⁵N revealed that atmospheric N deposition is dominated by NH_x-N from two major sources (urban sewage NH₃ and agricultural NH₃), the deposition of urban-derived NH_x followed a point source pattern characterized by an exponential decline with distance from the urban center, while the agricultural-derived NH_x was shown to be a non-point source. The relationship between moss N concentration and distance (y = 1.5e^−0.13x + 1.26) indicated that the maximum transporting distance of urban-derived NH_x averaged 41 km from the urban center, and it could be determined from the relationship between moss δ¹⁵N and distance [y = 2.54 ln(x) − 12.227] that urban-derived NH_x was proportionally lower than agricultural-derived NH_x in N deposition at sites beyond 17.2 km from the urban center. Consequently, the variation of urban-derived NH_x with distance from the urban center could be modeled as y = 56.272e^−0.116x − 0.481 in the Guiyang area.     

Predicted distributed state effects on enhanced biological phosphorus removal in a 5-stage Bardenpho wastewater treatment configuration.

Conventional wastewater treatment simulation programs use a "lumped" approach, where process rates are calculated using bulk concentrations of biomass and microbial storage products. A recently developed distributed, or agent-based, approach, where individual bacteria are modeled to account for their potentially variable hydraulic experiences, was applied to the 5-stage Bardenpho process, a type of enhanced biological phosphorus removal (EBPR) that includes internal recycle flows, which were hypothesized to affect distributed state development. Consistent with previous results, the EBPR predicted performance was worse according to the distributed approach than the lumped approach. In addition, increasing the internal recycle rate increased the anoxic reactor nitrate concentrations, tending to decrease EBPR performance. However, in the distributed approach, differences in the state distributions in internal recycle-linked reactors decreased with increasing recycle flow, tending to improve EBPR. These phenomena tend to have simultaneous and opposite effects on EBPR. The net effect will depend largely on the specific systems and the nitrate concentration in anoxic reactors.     

低温环境下手部温度主动加热技术的研究

本文介绍了一种低温环境下手部温度主动加热技术.通过热力学有关理论知识分析得出:人的手部是极易遭受低温损伤的重要部位之一.本研究设计了一种全新的手部温度主动加热系统,打破了传统的被动式手部加热防护体系,实现了手部温度的自动调节.该系统既可以保障人手部的工效性能,同时又可以满足手部精细操控作业的要求.     

面向安全评价的化工事故推理系统

针对流程工业的安全评价,开发了基于案例推理的化工事故分析系统,为依赖人工推理的HAZOP方法提供可靠性依据,激发专家头脑风暴.简要介绍了CBR的实现过程,描述了化工事故推理系统的结构,包括案例的表达、案例的检索、案例的推理以及学习.其中,案例属性的表达是依据对化工事故的分类思想.案例索引采用的是分步策略,第一步得到案例检索的子集,第二步在子集中匹配案例并排序.着重研究了数字属性和语义属性的匹配以及相似度的算法,并结合模糊技术和语义分词技术给出了具体实现方法.实际案例的应用结果表明本系统有效的提高了事故推理的自动化程度,具有很高的实际意义.     

Vitrification of bottom ash from a municipal solid waste incinerator

During incineration of municipal solid waste (MSW), various environmentally harmful elements and heavy metals are liberated either into bottom ash, or carried away with the off-gases and subsequently trapped in fly-ash. If these minor but harmful elements are not properly isolated and immobilized, it can lead to secondary environmental pollution to the air, soil and water. The stricter environmental regulations to be implemented in the near future in The Netherlands require a higher immobilization efficiency of the bottom ash treatment. In the present study, MSW incinerator bottom ash was vitrified at higher temperatures and the slag formed and metal recovered were examined. The behaviour of soluble elements that remain in the slag is evaluated by standard leaching test. The results obtained can provide a valuable route to treat the ashes from incinerators, and to make recycling and more efficient utilization of the bottom ash possible.