Ti-天然沸石的钛掺杂取代法制备、表征和光催化性能

以酸处理脱铝后信阳天然斜发沸石为载体,硫酸钛、钛酸正丁酯和四氯化钛为钛源,分别采用浸渍法和气相法制备出钛掺杂沸石光催化剂。采用X-射线衍射和傅立叶红外光谱分析了沸石酸处理及钛取代前后结构。结果表明,80℃下,4 mol/L盐酸处理10 h后沸石结构发生了显著变化,但仍保持Al-O-Si骨架结构。红外光谱结果证明Ti4+与沸石形成稳定的Ti-O-Si键。在以300 W紫外灯为光源进行罗丹明B脱色反应,考察了含钛沸石的光催化活性。初始浓度为80 mg/L,光照1.5 h后罗丹明B的去除率为98.18%。     

The short-term effect of cadmium on low molecular weight organic acid and amino acid exudation from mangrove (Kandelia obovata (S., L.) Yong) roots

The aim of this study was to evaluate short-term concentration and time effects of cadmium on Kandelia obovata (S., L.) Yong root exudation, thereby evaluating and predicting the ecophysiological effects of mangrove to heavy metals at the root level. Mature K. obovata propagules were cultivated in a sandy medium for 3 months, and then six concentrations of Cd (0, 2.5, 5, 10, 20, and 40 mg L^?1) were applied. After exposure time of 24 h and 7 days, respectively, the root exudates of K. obovata were collected and low molecular weight organic acids (LMWOAs) and amino acids of which were analyzed. In addition, we measured glutathione, soluble protein content, and Cd concentration in the plant. We found 10 and 15 types of LMWOAs and amino acids in root exudates of K. obovata with total concentrations ranging from 29.54 to 43.08 mg g^?1 dry weight (DW) roots and from 737.35 to 1,452.46 ng g^?1 DW roots, respectively. Both of them varied in quality and quantity under different Cd treatment strengths and exposure times. Oxalic, acetic, l-malic, tartaric acid, tyrosine, methionine, cysteine, isoleucine, and arginine were dominant. Both LMWOAs and amino acids excreted from K. obovata roots play a key role in Cd toxicity resistance. The responsiveness of amino acids was less than that of LMWOAs. We suggest that the ecological effect of root-excreted free amino acids in the rhizosphere is mainly based on the role of nutrients, supplemented with detoxification to heavy metals.     

CS-Fe和CS-Fe/Ni的制备及其用于去除钴离子

以氯化铁为铁源,硼氢化钠为还原剂,壳聚糖为稳定剂,采用液相还原法制备壳聚糖稳定纳米铁（CS-Fe）;并以氯化铁为铁源,硫酸镍为镍源,硼氢化钠为还原剂,壳聚糖为稳定剂,采用液相还原共沉淀法制备壳聚糖稳定纳米铁镍（CS-Fe/Ni）。通过SEM、EDS、XRD、FT-IR等表征手段,对所制备的CS-Fe和CS-Fe/Ni的形貌及微观结构进行表征,并以Co²⁺为目标去除物评价CS-Fe和CS-Fe/Ni的反应活性。初步研究表明,制成的CS-Fe含有单质纳米铁,颗粒多数以30~90 nm球形颗粒为主;而CS-Fe/Ni材料中含有纳米铁镍,颗粒多数以30~60 nm球形颗粒为主;在相同的实验条件下,反应60 min,CS-Fe/Ni对Co²⁺的去除率高达100%,但是CS-Fe仅为88%,即CS-Fe/Ni对Co²⁺的去除率比CS-Fe高。     

环境保护督察巡视:党政同责的顶层制度

环境保护督察巡视是党政同责的核心制度安排。本文从环保督察巡视与党政同责的关系与实践出发,认为该制度是从决策源头监督,既有法律依据,也有政策要求,其他部门的督察以及环保考核、约谈等实践为环保督察巡视积累了经验。从环保督察巡视制度的内涵与特征来看,该制度有明确的行动指南、统一的党政同责督察体系、较高的督察组权威、明确的巡视重点与突破方向等特点。最后,本文从理顺环境目标责任制度、制定督察实施细则、提升督察巡视权威性、开展第三方评估与社会监督等方面提出了政策建议。     

Application of integrated micro sensor in internal measurement of high temperature fuel cell

This study developed an integrated (flow, voltage, and temperature) micro sensor using the micro-electro-mechanical systems (MEMS) technology. It was inserted into the high temperature proton exchange membrane fuel cell (HT-PEMFC) for local real-time measurement. The integrated micro sensor is made of 40 µm thick stainless steel base material, and its protective layer is formed by polyimide (PI) that has better temperature resistance. The integrated micro sensor has three functions, and is favorably characterized by small size, good acid resistance and temperature resistance, quick response, real-time measurement, and being able to be put in any place for measurement. After calibration, and its reliability confirmed, the integrated micro sensor is inserted into the HT-PEMFC for local microcosmic measurement.     

Levels, sources, and health risks of carbonyls in residential indoor air in Hangzhou, China

Concentrations of formaldehyde, acetaldehyde, acetone, propionaldehyde, i-pentanal, and butyraldehyde in residential indoor air in Hangzhou were determined. The mean concentration of the total carbonyl compounds in summer was 222.6 μg/m³, higher than that in winter (68.5 μg/m³). The concentration of a specific carbonyl in indoor air was higher than the outdoor air measurement, indicating the release of carbonyls from the indoor sources. Formaldehyde and acetone were the most abundant carbonyls detected in summer and winter, respectively. Multiple regression analysis indicated that carbonyl concentrations in residential indoor air depended on the age of decoration and furniture, as well as their concentrations in outdoor air. In addition, a primary estimation showed that the health risks of carbonyls in summer were higher than those in winter.     

浙江省辐射环境监测现状及对策研究

辐射环境是生态环境的重要组成部分,核与辐射环境安全是国家环境安全的重要内容.详述了目前浙江省辐射环境监测网络的建设情况,以及对核设施、铀矿及伴生矿放射性污染源、核技术运用、电磁辐射环境、辐射应急等进行辐射环境监测的情况,分析了存在的主要问题,并提出了相应的对策,为浙江省辐射环境监管提供技术支撑和科学依据,同时也对全国辐射环境监测和管理具有积极的指导意义.     

催化臭氧化降解技术中的两个问题

探讨了有机物特性及中间产物H₂O₂在催化臭氧化中的作用。结果表明,有机物在自由基链反应过程中的特性直接影响催化臭氧化的降解效率。当目标有机物是对链反应具有促进作用的甲酸时,自由基引发反应可以明显提高甲酸的臭氧化效率。当目标有机物是对自由基链反应具有抑制剂作用的乙酸时,O₃和Fe²⁺/O₃对乙酸有着相似的降解效率。以上结果表明,自由基引发反应并不是臭氧化降解效率提高的充分条件。另外,当臭氧化过程有H₂O₂产生时,必须考虑类Fenton反应对臭氧化效率的影响。     

整地施肥对尾叶桉生长及土壤性状的影响

整地施肥试验结果表明，全垦、带垦和穴垦三种整地方式以及施肥对尾叶按造林成活率和保存率均无明显的影响，成活率在９５％－９８．８％之间，保存率在９２．１％－９７．７％之间．整地能改变土壤性状，如土壤孔隙度全垦为５７．８８％。穴垦为４９．４２％；对林木生长有促进作用，但作用效果很快减少，如造林３年后的林木材积全垦、带垦分别为穴垦的１３６．４％和１２０．０％，５年后却分别下降到１１６．５％和１０８．３％．施肥可提高土壤养分，促进林木生长．造林５年后的调查结果，穴垦施肥林地的土壤有机质、速效Ｎ分别为１５．４４７ｇ／ｋｇ和４９．２３０ｍｇ／ｋｇ，林木年均树高生长为１．２５ｍ；不施肥处理的有机质、速效Ｎ分别为１０．３８８ｇ／ｋｇ和３５．７１５ｍｇ／ｋｇ，林木年平均生长量为０．３５ｍ；林木材积施肥处理的为不施肥的９．８倍．整地施肥还可提高林木叶片的养分含量．     

Capacity and degree of iodine absorbed and enriched by vegetable from soil

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