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51.
The degree of chemical treatment in terms of removal of organic matter from different wastewaters has been investigated by employing potassium ferrate (K2FeO4) and ozone in various combinations. The study was performed in both the batch and the continuous flow systems. The treatment efficiency was determined through three different methods, i.e., chemical oxygen demand (COD), fluorescence and ultraviolet (UV) absorption. Fluorescence and UV absorption techniques were employed due to their specificity in measurement of humic substances, aromatic compounds and heterocyclic systems, whereas COD is a general parameter for the estimation of total organic matter. Fluorescence and UV absorbance values were correlated with respective COD values.Abdul Bari is with the Department of ChemistryShaukat Farooq is with the Department of Civil Engineering 相似文献
52.
Ultrasonic irradiation was found to accelerate the rate of hydrolysis of omethoate in aqueous solution over the pH range of 2—12. Process parameters studied include pH, steady-state temperature, concentration, and the type of gases, Greater than 96% hydrolysis was observed in 30 minutes through this process and the rate of destruction increased with the help of more soluble and low thermal inert gas. So with Krypton, omethoate was found to undergo rapid destruction as compared with Argon. In the presence of ultrasound, the observed first-order rate of hydrolysis of omethoate is found to be independent of pH. The formation of transient supercritical water(SCW) appears to be an important factor in the acceleration of chemical reactions in the presence of ultrasound. A detaiied chemical reaction mechanism for omethoatedestruction in water was formulated. Experimental results and theoretical kinetic mechanism demonstrated that the most of the omethoate undergo destruction inside the cavitating holes. A very less effect of temperature on the degradation of omethoate within a temperature range of 20——70℃ proves that a small quantity of omethoate undergoes secondary destruction in the bulk liquid. 相似文献
53.
Wenjing Lu Yawar Abbas Muhammad Farooq Mustafa Chao Pan Hongtao Wang 《Frontiers of Environmental Science & Engineering》2019,13(2):30
54.
Muhammad Nadeem Zafar Abdul Wahid Muhammad Afzal Ghauri Muhammad Zubair Muhammad Waseem Mumtaz Farooq Anwar 《毒物与环境化学》2013,95(3):422-433
This investigation describes the use of specially cultivated, nonliving biomass of Trichoderma harzianum as a biosorbent for the batch removal of Pb(II) from a stirred system under different experimental conditions. The metal removal depended upon pH, sorbent particle size, initial Pb(II) concentration, shaking speed, and sorption time. The optimal experimental conditions for the removal of Pb(II) by T. harzianum with an initial metal concentration of 100 mg L?1 were obtained at a particle size of 53 μm, a pH of 4.5, a shaking speed of 200 rpm, and a contact time of 720 min. The results were analyzed in terms of adsorption isotherms and kinetic models. The Freundlich isotherm model and pseudo second-order model fitted well in the data. T. harzianum proved to be a good biomaterial for accumulating Pb(II) from aqueous solutions (q = 460 mg g?1). 相似文献
55.
Li Lan Long Meijuan Islam Faisal Farooq Muhammad A. Wang Jian Mwamba Theodore M. Shou Jianyao Zhou Weijun 《Environmental science and pollution research international》2019,26(12):11827-11845
Environmental Science and Pollution Research - Nowadays, modern plant physiology focuses on complex behavior of metal co-contaminants in agrosystems. Keeping this in view, the current study was... 相似文献
56.
Gill Rafaqat A. Zhang Na Ali Basharat Farooq Muhammad A. Xu Jianxiang Gill Muhammad B. Mao Bizeng Zhou Weijun 《Environmental science and pollution research international》2016,23(20):20483-20496
57.
Kinetics of carbon mineralization of biochars compared with wheat straw in three soils 总被引:2,自引:0,他引:2
Qayyum MF Steffens D Reisenauer HP Schubert S 《Journal of environmental quality》2012,41(4):1210-1220
Application of biochars to soils may stabilize soil organic matter and sequester carbon (C). The objectives of our research were to study in vitro C mineralization kinetics of various biochars in comparison with wheat straw in three soils and to study their contribution to C stabilization. Three soils (Oxisol, Alfisol topsoil, and Alfisol subsoil) were incubated at 25°C with wheat straw, charcoal, hydrothermal carbonization coal (HTC), low-temperature conversion coal (LTC), and a control (natural organic matter). Carbon mineralization was analyzed by alkali absorption of CO released at regular intervals over 365 d. Soil samples taken after 5 and 365 d of incubation were analyzed for soluble organic C and inorganic N. Chemical characterization of biochars and straw for C and N bonds was performed with Fourier transformation spectroscopy and with the N fractionation method, respectively. The LTC treatment contained more N in the heterocyclic-bound N fraction as compared with the biochars and straw. Charcoal was highly carbonized when compared with the HTC and LTC. The results show higher C mineralization and a lower half-life of straw-C compared with biochars. Among biochars, HTC showed some C mineralization when compared with charcoal and LTC over 365 d. Carbon mineralization rates were different in the three soils. The half-life of charcoal-C was higher in the Oxisol than in the Alfisol topsoil and subsoil, possibly due to high Fe-oxides in the Oxisol. The LTC-C had a higher half-life, possibly due to N unavailability. We conclude that biochar stabilization can be influenced by soil type. 相似文献
58.
Aziz Khan Daniel Kean Yuen Tan Fazal Munsif Muhammad Zahir Afridi Farooq Shah Fan Wei Shah Fahad Ruiyang Zhou 《Environmental science and pollution research international》2017,24(30):23471-23487
Cotton (Gossypium hirustum L.) is grown globally as a major source of natural fiber. Nitrogen (N) management is cumbersome in cotton production systems; it has more impacts on yield, maturity, and lint quality of a cotton crop than other primary plant nutrient. Application and production of N fertilizers consume large amounts of energy, and excess application can cause environmental concerns, i.e., nitrate in ground water, and the production of nitrous oxide a highly potent greenhouse gas (GHG) to the atmosphere, which is a global concern. Therefore, improving nitrogen use efficiency (NUE) of cotton plant is critical in this context. Slow-release fertilizers (e.g., polymer-coated urea) have the potential to increase cotton yield and reduce environmental pollution due to more efficient use of nutrients. Limited literature is available on the mitigation of GHG emissions for cotton production. Therefore, this review focuses on the role of N fertilization, in cotton growth and GHG emission management strategies, and will assess, justify, and organize the researchable priorities. Nitrate and ammonium nitrogen are essential nutrients for successful crop production. Ammonia (NH3) is a central intermediate in plant N metabolism. NH3 is assimilated in cotton by the mediation of glutamine synthetase, glutamine (z-) oxoglutarate amino-transferase enzyme systems in two steps: the first step requires adenosine triphosphate (ATP) to add NH3 to glutamate to form glutamine (Gln), and the second step transfers the NH3 from glutamine (Gln) to α-ketoglutarate to form two glutamates. Once NH3 has been incorporated into glutamate, it can be transferred to other carbon skeletons by various transaminases to form additional amino acids. The glutamate and glutamine formed can rapidly be used for the synthesis of low-molecular-weight organic N compounds (LMWONCs) such as amides, amino acids, ureides, amines, and peptides that are further synthesized into high-molecular-weight organic N compounds (HMWONCs) such as proteins and nucleic acids. 相似文献
59.
60.
Farooq S Hashmi I Qazi IA Qaiser S Rasheed S 《Environmental monitoring and assessment》2008,140(1-3):339-347
The present study was undertaken to examine the drinking water quality of Rawal Treatment Plant, Rawalpindi and its distribution
network by collecting samples from eight different locations. The aim was to determine potential relationship between the
presence of microorganisms and chlorine residual in the distribution network. Quantification of chlorine residual, turbidity,
standard plate count (SPC), fecal and total coliforms by Most Probable Number (MPN) was performed. Three different forms of chlorine were measured at each sampling station such
as free chlorine, residual chlorine, chloramines and total chlorine residual. A critical evaluation of data presented indicated
that pH generally ranged from 7.02–7.30; turbidity varied from 0.34–2.79 NTU; conductivity fluctuated from 359–374 μS/cm;
and TDS values were found to be ranging between 180–187 mg/l. Station # 7 was found to be most contaminated. The value of total chlorine was found to be 0.86 to1.7 mg/l at Station # 3 and 6, respectively. Highest standard plate count was 62 CFU/ml at Station # 7. Total
coliforms were less than 1.1 MPN/100 ml at almost most of the stations except at Station # 3 where it was found to be greater than 23.0 MPN /100 ml. Overall aim of this study is to create awareness about contamination
of drinking water in the water distribution networks and to make recommendations to provincial agencies such as EPA, CDA and
WASA that regular monitoring should be carried out to ensure that the chlorine residual is available at consumer end. 相似文献