Effects of metsulfuron-methyl on the microbial population and enzyme activities in wheat rhizosphere soil

The effects of metsulfuron-methyl, a sulfonylurea herbicide, on the wheat soil microorganisms were evaluated by the methods of microbial inoculation culture, and the activities of three enzymes were measured using the colorimetric method. The tolerant microorganisms that can resist 500 microg x g(-1) metsulfuron-methyl in the counting culture medium were studied specially. Metsulfuron-methyl distinctly inhibited the common aerobic heterotriphic bacteria, but the effects on common fungi and common actinomycete were not evident. In the meantime, the number of tolerant fungi increased greatly in the rhizosphere after the application of metsulfuron-methyl in contrast to the significant decrease of the amount of tolerant actinomycete. It indicates that fungi might turn into the dominant microbial type and actinomycete is the sensitive factor in the soil polluted by sulfonylurea residues. The population of aromatic compounds-decomposing bacteria, aerobic azotobacter, and nitrite bacteria all increased in the earlier period, but the aerobic azotobacter decreased rapidly in number 30 days later, and the amount of nitrite bacteria also showed a temporary decrease with time 15 days later. However, the denitrifying bacteria just began to increase significantly after the crops had grown for 50 days. The amount of sulfur-oxidizing bacteria gradually decreased with the growth of crops, and so were the sulfate-reducing bacteria after metsulfuron-methyl application. To all types of microorganisms, there were more microbes in rhizosphere samples than those in nonrhizosphere except aerobic azotobacter. It means the growth of wheat root system can stimulate the growth of most microorganisms. The activities of hydrogen peroxidase and polyphenol oxidase in soil samples after metsulfuron-methyl application were notably lower than those in the control, and the difference of the activities between the samples of rhizosphere and nonrhizosphere was evident. On the contrary, the activity of dehydrogenase was not inhibited by the application of metsulfuron-methyl, and the rhizosphere effect was not obvious either.     

Modeling human exposures to air pollution control (APC) residues released from landfills in England and Wales

Human exposures to air pollution control (APC) residues released from 6 landfills were modeled and assessed. Following a qualitative risk characterisation, direct and indirect exposures were quantified. Site-specific air dispersion modeling was conducted for PM(10), PCDDs/PCDFs, Pb, Cd, As and Cr(VI) concentrations at the closest residential points of exposure for 4 landfill sites accepting, in total, 75% w/w of the APC residues disposed of in 2000-2001 (UK). Inhalation risks, assessed by reference to air quality standards at residential exposure points, were assessed as insignificant. Preliminary modeling suggested that indirect exposures from PCDDs/PCDFs at the 95th percentile level for the site where APC deposition rates were highest could potentially exceed the tolerable daily soil intake (TDSI) but this warrants further study given the model limitations. These results offer an initial screen of the significance of potential risks from APC disposal, which is of value in addressing concerns about the uncertainty of potential risks to human health from bulk APC disposal at strategic locations.     

The study of ultrasound-assisted oxidative desulfurization process applied to the utilization of pyrolysis oil from waste tires

In recent years, the increasing world population and rapid industrial development has increased the consumption of fossil fuel-derived oils. In response to the resulting exhaustion of fossil fuel energy, many countries around the world are investigating methods of waste energy recovery and reuse, including oil recovery from the pyrolysis process of waste tires. This study investigates the efficiency of an ultrasound-assisted oxidative desulfurization (UAOD) process in sulfur reduction from diesel oil and the pyrolysis oil from waste tires treatment. The results indicate that the oxidation efficiency increases as the doses of transition metal catalyst are increased. Longer sonication time also enhances the oxidation process, apparently through the biphasic transfer of oxidants, which results in a high yield of organic sulfur oxidation products. The best desulfurization efficiency was 99.7% (2.67 ppm sulfur remaining) and 89% (800 ppm sulfur remaining) for diesel and pyrolysis oils, respectively, via a process executed by two UAOD units connected in series and combined with solid adsorption using 30 g of Al₂O₃ in 6 cm columns. These batch experiment results demonstrate clean waste energy recovery and utilization, while fulfilling the requirements of Taiwan EPA environmental regulations (sulfur concentrations less than 5000 ppm).     

Economic Analysis of CO2 Emission Trends in China

Climate change is one of hot spots all around the world. China, the second biggest CO₂ emitter, is facing increasingly severe pressure to reduce CO₂ emission. The article first describes Kaya Identity and its policy implications. Second, it uses the modified Kaya Identity and makes decomposition without residues on CO₂ emission during the period 1971-2005. Taking into account the changes of macroeconomic background, it conducts a detailed analysis in terms of CO₂ emission trend from 4^th Five Year Plan through 10^th Five Year Plan. The decomposition results indicate that economic development and increase in population are major driving forces, and that improvement in energy efficiency contributes to the reduction of CO₂ emission, and that decarbonization in primary energy structure is also an important strategic choice. Finally, the article stresses that in CO₂ order to realize the binding target of 20% reduction in GDP energy intensity during the 11^th Five Year Plan, China should speed up the readjustment of the industrial structure and energetically develop the energy-efficient technologies and clean fuel technology, which will effectively promote the country to reduce CO₂ emission and contribute to the mitigation of climate change.     

Synthesis of mesoporous magnesium oxide: Its application to CO2 chemisorption

Mesoporous magnesium oxide (MgO) was synthesized using mesoporous carbon CMK-3 obtained from mesoporous SBA-15 as exotemplate. P123 was used as the structure-directing template and rice husk ash (RHA) as the silica source for the synthesis of SBA-15, which was subsequently treated with sucrose and sulphuric acid to obtain mesoporous carbon (CMK-3). X-ray powder diffraction (XRD) results and the type-IV adsorption isotherm with H1 hysteresis obtained by N₂ adsorption/desorption study for SBA-15, CMK-3 and mesoporous MgO suggests its resemblance with materials synthesized using conventional silica sources. Mesoporous MgO was subjected for CO₂ adsorption study in TGA; adsorption was 8 and 10 wt% at 25 and 100 °C, respectively. Finally, mesoporous MgO is selective to CO₂ gas, thermally stable and regenerable. Thus, this study contributes a better route to enhance CO₂ gas adsorption and use ecological waste rice husk for the synthesis of such efficient mesoporous materials.     

日地环境对人类自发攻击性事件的影响

考察了日地空间物理环境扰动与人类自发攻击性群体性事件发生率之间相关性。统计分析发现，两者之间的相关程度很高，历元叠加后相关系数可达０．８４和０．７９、这表明日地空间物理环境对人类攻击性本能和情绪具有显著的调节作用，导致全球自发攻击性群体事件年发生率具有１１ａ准周期波动特征。其作用机制可能是地磁场活动和大气温度的影响。     

石油野外作业工人体力劳动强度分级调查

据ＧＢ３８６９—８３标准对江汉油田测量、地震、钻井、井下四类野外作业３４名工人、２４个工种进行了体力劳动强度分级调查，其结果：测量作业为Ⅰ～Ⅱ级；钻井作业Ⅱ级占５／８，Ⅲ级占１／４；井下作业Ⅲ级占２／３；地震作业Ⅲ、Ⅳ级各占４／９、２／９。说明前两类基本属中等强度劳动，后两类大部分属重强度劳动。     

从醇后气中回收淡甲醇

在甲醇分离器后设置淡甲醇回收装置回收醇后收醇后的中甲醇，其回收率达到８７．５％，同时大大降低了排放地沟的稀氨水中的甲醇含量，减轻了稀氨水对环境的污染，有较好的经济效益和环境效益。