N，N－二甲基甲酰胺在血液中代谢物S－（N－甲基氨基甲酰）谷胱甘肽的气质联用方法

根据先将ＳＭＧ转化为乙基、Ｎ－甲基氨基酸盐（ＥＭＣ），然后以气相色谱－质谱联用手段测定所产生的ＥＭＣ的原理，发展出一种定量检测大鼠血清中ＳＭＧ及其他Ｎ－甲基氨基甲酸硫酯类物质的分析方法．方法采用人工合成的ＳＭＧ和ＥＭＣ进行标定，每次测定需要样品量为０．５ｍＬ，方法的合理检出极限为ｃ（ＳＭＧ）＝１０μｍｏｌ／Ｌ．     

Influence of metal ion on sorption of p-nitrophenol onto sediment in the presence of cetylpyridinium chloride

Heavy metals and surfactants have a significant effect on the sorption of organic contaminants. In this study, batch equilibrium experiments were carried out to investigate the influence of Pb(NO(3))(2) on the sorption of p-nitrophenol (PNP) onto sediments in the presence of cationic surfactant cetylpyridinium chloride (CPC). Results indicated that in the complex system containing PNP, Pb(NO(3))(2) and CPC, the sorption of PNP decreased with increasing concentration of Pb(NO(3))(2) due primarily to competing for adsorption sites. Likewise, partitioning of PNP in adsorbed surfactant layers and micelles decreased with increasing level of Pb(NO(3))(2). Moreover, the influence of different metal ions (Pb(2+), Cd(2+), Zn(2+)) was examined and results indicated that the presence of heavy metals inhibited the sorption of PNP in the order: Pb(2+)>Cd(2+)>Zn(2+). The competitive effect of the heavy metals was in agreement with the hydration energy and hydrated radius. The results are believed to provide a useful insight into describing the transport and fate of PNP in natural environments.     

玻璃注射器对顶空气相色谱法分析苯系物的误差原因分析

按GB11890—89顶空气相色谱法分析苯系物时，发现重复性和分割水平样品平行性较差，经仔细分析，是由于使用普通玻璃注射器造成的。为避免此类误差，建议顶空气相色谱法分析时，使用带特氟龙顶端推杆的气密性注射器。     

Iron-doped Mn-Ce/TiO2 catalyst for low temperature selective catalytic reduction of NO with NH3

The catalysts of iron-doped Mn-Ce/TiO 2(Fe-Mn-Ce/TiO 2) prepared by sol-gel method were investigated for low temperature selective catalytic reduction(SCR) of NO with NH 3.It was found that the NO conversion over Fe-Mn-Ce/TiO 2 was obviously improved after iron doping compared with that over Mn-Ce/TiO 2.Fe-Mn-Ce/TiO 2 with the molar ratio of Fe/Ti = 0.1 exhibited the highest activity.The results showed that 96.8% NO conversion was obtained over Fe(0.1)-Mn-Ce/TiO 2 at 180°C at a space velocity of 50,000 hr 1.Fe-Mn-Ce/TiO 2 exhibited much higher resistance to H 2 O and SO 2 than that of Mn-Ce/TiO 2.The properties of the catalysts were characterized using X-ray diffraction(XRD),N 2 adsorption,temperature programmed desorption(NH 3-TPD and NOx-TPD),and Xray photoelectron spectroscopy(XPS) techniques.BET,NH3-TPD and NOx-TPD results showed that the specific surface area and NH3 and NOx adsorption capacity of the catalysts increased with iron doping.It was known from XPS analysis that iron valence state on the surface of the catalysts were in Fe3+ state.The doping of iron enhanced the dispersion and oxidation state of Mn and Ce on the surface of the catalysts.The oxygen concentrations on the surface of the catalysts were found to increase after iron doping.Fe-Mn-Ce/TiO2 represented a promising catalyst for low temperature SCR of NO with NH3 in the presence of H2 O and SO2.     

上海市城市扩展格局及土壤无机碳分布特征分析

土地利用方式变更引起的土壤碳库变化对全球温室效应、全球碳循环有重大影响。基于1：250000多目标地球化学调查数据,利用RS影像和GIS统计技术研究了上海城市扩展进程中的土壤无机碳空间分布与演化特征。根据上海地区1980、2000．2005年3期遥感影像分析,上海市城区扩张以原市区为中心向周边快速扩展,1980～2005年间,城区面积由193．08km^2增加到1570．52km^2,城市用地面积比例由3．05％迅速上升到24．77％。比较城区,郊区、乡村地区土壤无机碳分布,城区表层土壤无机碳密度为（1．12±0．64）kg／m^2,深层土壤无机碳密度为（1．24±0．40）kg／m^2,表层土壤无机碳积累明显,深层土壤呈现轻度积累,城区土壤无机碳空间分布变异系数降低。比较1980年前建城区、1980～2000年建城区．2000～2005年建城区与郊区土壤无机碳密度分布,城区土壤无机碳分布呈现富集。并且随建城区年限的延长,土壤无机碳积累渐趋显著,城市土壤无机碳分布的空间异质性降低。本项研究提供城市化进程中的土壤无机碳分布演变趋势信息,可为土壤固定碳潜力研究提供数据支持,也为推动中国城市生态系统碳循环研究提供参考。     

谈谈英语学习方式的转变

很多学生现在对英语学习感到无所适从，他们觉得自己无论如何尽力也没有办法提高英语成绩。本文对这种情况的出现做了简单的分析，并提出了一些建议。     

废旧电池掩埋处理方法初探

以分别种植小叶黄杨和八角金盘的2块试验土地与1块贫瘠裸露土地作为对照,试验植物吸收处理废旧电池的重金属污染的掩埋方法。文章介绍了将废旧电池内部的糊状物分别掩埋在小叶黄杨,八角金盘和贫瘠裸露土地3块试验土中,选用电池内部含量较多的 Zn 等重金属元素为跟踪元素,经一定时间后分析土壤中重金属元素的残留量。测定结果发现,小叶黄杨能很好地吸收掩埋入土的重金属元素,而八角金盘则对重金属没有明显的吸收作用。     

关于反吹扁袋除尘器悬臂装置的改进

论述了对锻烧白灰的竖窑除尘装置进行改造,取得了良好的效果     

Characterization of residues from dismantled imported wastes

Residues from the imported wastes dismantling process create a great burden on the ambient environment. To develop appropriate strategies for the disposal of such residues, their characteristics were studied through background value analysis and toxicity leaching tests. Our results showed that the heavy metals concentrations in residues were high, particularly those of Cu (7180 mg kg^?1), Zn (2783 mg kg^?1), and Pb (1954 mg kg^?1). Toxicity leaching tests revealed a high metal releasing risk of such residues if they are disposed of in a landfill. However, the residues of imported wastes were also found to have some intrinsic metal recycling value.     

堇青石负载Pd和过渡金属氧化物催化剂的表征及其对CO的催化氧化活性

以堇青石蜂窝陶瓷(CC)为载体,采用浸渍法制备了堇青石负载Pd和过渡金属混合氧化物催化剂,记作Pd-M-Mn(M=Cu,Co,Fe,Ni)/CC。实验结果表明:Pd-Co-Mn/CC催化剂的催化活性最高;随着Pd负载量的增加,CO转化率提高;当Pd负载量为1.00%时,反应温度为150℃时CO转化率达到98%,200℃时CO转化率达到100%;在反应温度150℃条件下,Pd-Co-Mn/CC催化剂(Pd负载量1.00%)的CO转化率在前30h内小幅度下降,随后稳定在90%以上,反应100h后,催化剂表面颜色由黑色变为棕褐色。