首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1512篇
  免费   404篇
  国内免费   145篇
安全科学   85篇
废物处理   87篇
环保管理   92篇
综合类   799篇
基础理论   281篇
污染及防治   538篇
评价与监测   67篇
社会与环境   54篇
灾害及防治   58篇
  2025年   2篇
  2024年   6篇
  2023年   34篇
  2022年   77篇
  2021年   56篇
  2020年   46篇
  2019年   46篇
  2018年   54篇
  2017年   58篇
  2016年   80篇
  2015年   84篇
  2014年   101篇
  2013年   122篇
  2012年   118篇
  2011年   118篇
  2010年   92篇
  2009年   70篇
  2008年   63篇
  2007年   67篇
  2006年   76篇
  2005年   60篇
  2004年   57篇
  2003年   55篇
  2002年   42篇
  2001年   52篇
  2000年   61篇
  1999年   50篇
  1998年   54篇
  1997年   39篇
  1996年   45篇
  1995年   41篇
  1994年   24篇
  1993年   22篇
  1992年   19篇
  1991年   7篇
  1990年   12篇
  1989年   7篇
  1988年   7篇
  1987年   9篇
  1986年   6篇
  1985年   2篇
  1984年   4篇
  1983年   7篇
  1982年   4篇
  1981年   2篇
  1980年   1篇
  1978年   2篇
排序方式: 共有2061条查询结果,搜索用时 15 毫秒
131.
高温固硫反应中锶化合物的促进作用   总被引:18,自引:0,他引:18  
肖佩林  沈迪新 《环境化学》1994,13(5):389-394
本文论述了锶化合物在高温燃烧条件下固硫反应的促进作用,通过X-射线粉晶衍射及扫描电镜的研究,证明形成含硫酸钙的复合盐的生成是提高固硫率的关键,用该方法制成的工业型煤,在实际锅炉中试烧其固硫率可达70%,是烟气排烟脱硫的有效方法之一,对净化大气,减少污染有现实意义。  相似文献   
132.
含染料废水处理方法的现状与进展   总被引:50,自引:0,他引:50  
综述了含染料废水处理方法的现状和进展,尤其是在物理法,化学法,徨化法以及物理化学法中的新技术,其中包括膜及液膜方法,磁分离系统、超声波辐射法,非平衡等离子体法、超临界水氧化法、深度化学氧化法、光催化氧化法、等方法的研究现状,新的方法,材料,工艺的应用,对提高该类废水处理效率和效果具有重要的意义。  相似文献   
133.
Field experiments were done in two sites, Yixing and Changshu, Jiangsu province, China, to study P movement and leaching in flooded paddy soils. P movement in soil was investigated by using the KH2 32PO4 tracker method, and the amount of P leached from the soil layer in different depths was estimated by measuring P concentrations in the soil solution and saturated hydraulic conductivities in field. Determination was done about one month after P application. There was 46% and 42% of total 32P retained in the 0–5cm layer of soil in the Yixing site and in the Changshu site respectively. The 32P retained in the 25–30 cm layer was only about 1–2% of the total 32P added. Furthermore, 8.01% of 32P in the soil of Yixing site and 16.8% of 32P in the soil of Changshu site was lost from the layer 0–30cm soil. The seasonal amounts of P leached from the top soil layer and from bottom layer are about 4.5–5.8% and 1.6–2.1% of the total P application, respectively. Changes of total P concentrations in soil solutions during rice growth showed that the fertilizer P applied before flooding of the paddy fields suffered a flash leaching loss and a slow leaching loss. We concluded that the fertilizer P could quickly move in the flooded paddy rice field and parts of it can enter into surface water and ground water. Unless the P application is well managed the risk of P loss and consequently environmental pollution exist.  相似文献   
134.
    
Successive sediment suspensions often happen in estuary, yet little research has probed into the difference in the release behaviors of organic compounds among different suspensions. This study took polycyclic aromatic hydrocarbons (PAHs) as typical organic contaminants and investigated the release behaviors between two successive suspensions with a particle entrainment simulator (PES). Results showed that successive sediment suspensions lowered the concentration of dissolved PAHs in the overlying water via facilitating the re-adsorption of dissolved PAHs onto the suspended particles. Fast-release and slow-release periods of PAHs were successively observed in the both suspensions. The concentration changes of dissolved PAHs in the second suspension were generally similar with but hysteretic to those in the first suspension. More vigorous desorption and re-absorption of PAHs were induced in the second suspension. Successive sediment suspensions obviously decreased the concentrations of mineral composition and organic matters in the overlying water, which significantly affects multiphase distribution of PAHs.  相似文献   
135.
Concentrations of eight trace metals (TMs) in road dust (RD) (particles?<?25 μm) from urban areas of Xinxiang, China, were determined by inductively coupled plasma mass spectrometry. The geometric mean concentrations of Zn, Mn, Pb, As, Cu, Cr, Ni and Cd were 489, 350, 114, 101, 60.0, 39.7, 31.6, and 5.1 mg kg?1, respectively. When compared with TM levels in background soil, the samples generally display elevated TM concentrations, except for Cr and Mn, and for Cd the enrichment value was 69.6. Spatial variations indicated TMs in RD from park path would have similar sources with main roads, collector streets and bypasses. Average daily exposure doses of the studied TMs were about three orders of magnitude higher for hand-to-mouth ingestion than dermal contact, and the exposure doses for children were 9.33 times higher than that for adults. The decreasing trend of calculated hazard indexes (HI) for the eight elements was As?>?Pb?>?Cr?>?Mn?>?Cd?>?Zn?>?Ni?>?Cu for both children and adults.  相似文献   
136.
热电厂冲灰水除氟的研究   总被引:1,自引:0,他引:1       下载免费PDF全文
本文采用了多种方法对热电厂冲灰水的除氟进行了研究。结果表明,用石灰调节冲灰水的pH,以铝矾做除氟剂并配以絮凝剂的混凝除氟法效果最佳,氟的去除率达95%以上,冲灰水的氟含量降到1mg/l以下。这种混凝除氟法,简单易行,便于操做,不产生二次污染。  相似文献   
137.
    
• New method of mineralizing PFCs was proposed. • Activated carbon was regenerated while mineralizing PFCs. • Molten NaOH has good mineralization effect on PFOS and PFBS. Current study proposes a green regeneration method of activated carbon (AC) laden with Perfluorochemicals (PFCs) from the perspective of environmental safety and resource regeneration. The defluorination efficiencies of AC adsorbed perfluorooctanesulfonate (PFOS), perfluorooctanoic acid (PFOA) and perfluorobutanesulfonate (PFBS) using three molten sodium salts and one molten alkali were compared. Results showed that defluorination efficiencies of molten NaOH for the three PFCs were higher than the other three molten sodium salts at lower temperature. At 700°C, the defluorination efficiencies of PFOS and PFBS using molten NaOH reached to 84.2% and 79.2%, respectively, while the defluorination efficiency of PFOA was 35.3%. In addition, the temperature of molten salt, the holding time and the ratio of salt to carbon were directly proportional to the defluorination efficiency. The low defluorination efficiency of PFOA was due to the low thermal stability of PFOA, which made it difficult to be captured by molten salt.The weight loss range of PFOA was 75°C–125°C, which was much lower than PFOS and PFBS (400°C–500°C). From the perspective of gas production, fluorine-containing gases produced from molten NaOH-treated AC were significantly reduced, which means that environmental risks were significantly reduced. After molten NaOH treatment, the regenerated AC had higher adsorption capacity than that of pre-treated AC.  相似文献   
138.
湿法烟道气脱硫脱硝反应动力学   总被引:1,自引:0,他引:1       下载免费PDF全文
近年来,发展的同时脱硫脱硝方法,是借助于氧化不容易溶解的NO到容易溶解的NO_2,或者利用水溶性亚铁螯合物作为一种催化剂加速NO的吸收,也就是亚铁螯合物能够与NO形成一个络合物而促进NO的吸收。或者应用水溶液中NO_x被溶解的SO_2还原形成N_2,N_2O或还原到氮化物如NOH(SO_3~(2-)_2、 NH_2SO_3~-和NH_4~+而除去,而SO_2被氧化生成硫酸盐。本文综述了湿法烟道气脱硫脱硝反应动力学和机理以及一些中间化合物形成与消失的过程。  相似文献   
139.
农业非点源污染环境影响及防治   总被引:10,自引:0,他引:10  
非点源污染也称面源污染,因其污染的时空范围广,不确定性大,污染严重,对其治理及管理的难度也较大.由于化肥和农药的大量使用,农业非点源已成为中国水环境的主要污染源.文章中对农业非点源污染的特点、来源和危害进行了系统论述,并提出防治农业非点源污染的具体措施建议.  相似文献   
140.
    
This work investigates the effects of lubricant sulfur contents on the morphology, nanostructure, size distribution and elemental composition of diesel exhaust particle on a light-duty diesel engine. Three kinds of lubricant (LS-oil, MS-oil and HS-oil, all of which have different sulfur contents: 0.182%, 0.583% and 1.06%, respectively) were used in this study. The morphologies and nanostructures of exhaust particles were analyzed using high-resolution transmission electron microscopy (TEM). Size distributions of primary particles were determined through advanced image-processing software. Elemental compositions of exhaust particles were obtained through X-ray energy dispersive spectroscopy (EDS). Results show that as lubricant sulfur contents increase, the macroscopic structure of diesel exhaust particles turn from chain-like to a more complex agglomerate. The inner cores of the core-shell structure belonging to these primary particles change little; the shell thickness decreases, and the spacing of carbon layer gradually descends, and amorphous materials that attached onto outer carbon layer of primary particles increase. Size distributions of primary particles present a unimodal and normal distribution, and higher sulfur contents lead to larger size primary particles. The sulfur content in lubricants directly affects the chemical composition in the particles. The content of C (carbon) decreases as sulfur increases in the lubricants, while the contents of O (oxygen), S (sulfur) and trace elements (including S, Si (silicon), Fe (ferrum), P (phosphorus), Ca (calcium), Zn (zinc), Mg (magnesium), Cl (chlorine) and Ni (nickel)) all increase in particles.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号