大宝山矿区水体和沉积物中重金属的污染评价

分别于丰水期和枯水期对广东省大宝山矿区铁龙拦泥坝至凉桥河段水体中溶解态的重金属进行了调查,应用EPA推荐的健康风险评价模型发现,水体中非致癌物通过饮水途径所导致平均个人年风险排列顺序是Cu〉Pb〉Zn,最大值的平均个人年风险在丰水期和枯水期的平均值分别是2.14×10-7 a-1和4.13×10-7 a-1,小于国际防辐射委员会（ICRP）推荐的最大可接受平均个人年风险5.0×10-5a-1。致癌物Cd的平均个人年风险在丰水期和枯水期的平均值分别是3.52×10-4 a-1和4.53×10-4 a-1,大于ICRP推荐的最大可接受值,同时也大于非致癌物3～4个数量级。另外,通过对枯水期沉积物的重金属总量分析,发现凉桥槽对坑支流受水体pH的影响,导致其沉积物重金属的浓度最高。根据Long和Macdonald利用生物效应数据库法建立的沉积物质量基准,发现除冷水泾外,其他采样点的平均效应中值指数（mERMQ）值都大于1.5,可见沉积物中的重金属会对当地底栖生物产生毒害作用。     

铁炭微电解法预处理超高盐榨菜腌制废水

超高盐榨菜腌制废水是高盐、高氮磷及高有机物废水,目前常采用生物方法进行处理,但因高污染物浓度及高盐度影响,处理效果不够理想;因此,选用铁炭微电解法对超高盐榨菜腌制废水进行预处理。通过静态烧杯实验,研究了反应时间、初始pH、铁炭体积比和铁水体积比对COD和氨氮去除率的影响。单因素实验的最佳处理条件：原水pH4～4．5,反应时间为30min,铁炭体积比为1：1,铁水体积比为2：1,出水COD和氨氮的去除率分别为57．29％和53．11％,盐度由原水的6．62％下降为3．63％,去除率达45．17％,pH由原水4．01升高为6．38。正交实验结果表明,影响COD和氨氮去除率的因素从大到小的顺序为：铁水体积比、初始pH、反应时间、铁炭体积比。实验表明,采用铁炭微电解法能够对超高盐榨菜腌制废水中的COD和氨氮进行有效去除,出水的pH升高和盐度下降,能满足后续生物处理的预处理要求。     

Emergy analysis of the recycling options for construction and demolition waste

Construction and demolition (C&D) waste is becoming a major contributor to environmental pollution. In Shanghai, China, the quantity of C&D waste is 2.11E+07 t/yr, which accounts for 45% of the total quantity of solid waste. There has been a growing promotion of recycling C&D waste as an effective way to solve this waste problem. However, the evaluation of the efficiency of recycling C&D waste as a potential source of resources is largely based on traditional economic analysis. The economic analysis emphasizes money instead of the harmony between economic benefit and environmental effects. There is a need for a new strategic approach to investigate the efficiency of recycling C&D waste to achieve the integration between economic, social and environmental effects. Emergy theory can be employed to analyze different recycling options for C&D waste. With reference to the Chinese construction industry, this paper demonstrates that the close-loop recycling option is better than the open-loop recycling option for C&D waste in terms of the integration of social, environmental and sustainable aspects. To evaluate different technology solutions for C&D waste recycling, the emergy theory and method is not limited to a cost-benefit balance but can include economic, social, environmental and sustainable effects.     

Effect of liquid-to-solid ratio on semi-solid Fenton process in hazardous solid waste detoxication

The liquid-to-solid ratio (L/S) of semi-solid Fenton process (SSFP) designated for hazardous solid waste detoxication was investigated. The removal and minimization effects of o-nitroaniline (ONA) in simulate solid waste residue (SSWR) from organic arsenic industry was evaluated by total organic carbon (TOC) and ONA removal efficiency, respectively. Initially, Box-Behnken design (BBD) and response surface methodology (RSM) were used to optimize the key factors of SSFP. Results showed that the removal rates of TOC and ONA decreased as L/S increased. Subsequently, four target initial ONA concentrations including 100 mg kg⁻¹, 1 g kg⁻¹, 10 g kg⁻¹, and 100 g kg⁻¹ on a dry basis were evaluated for the effect of L/S. A significant cubic empirical model between the initial ONA concentration and L/S was successfully developed to predict the optimal L/S for given initial ONA concentration for SSFP. Moreover, an optimized operation strategy of multi-SSFP for different cases was determined based on the residual target pollutant concentration and the corresponding environmental conditions. It showed that the total L/S of multi-SSFP in all tested scenarios was no greater than 3.8, which is lower than the conventional slurry systems (L/S ? 5). The multi-SSFP is environment-friendly when it used for detoxication of hazardous solid waste contaminated by ONA and provides a potential method for the detoxication of hazardous solid waste contaminated by organics.     

Quantifying air pollution attenuation within urban parks: an experimental approach in Shanghai, China

Parks with various types of vegetations played an important role in ameliorating air quality in urban areas. However, the attenuation effect of urban vegetation on levels of air pollution was rarely been experimentally estimated. This study, using seasonal monitoring data of total suspended particles (TSP), sulfur dioxide (SO(2)) and nitrogen dioxide (NO(2)) from six parks in Pudong District, Shanghai, China, demonstrated vegetations in parks can remove large amount of airborne pollutants. In addition, crown volume coverage (CVC) was introduced to characterize vegetation conditions in parks and a mixed-effects model indicated that CVC and the pollution diffusion distance were key predictors influencing pollutants removal rate. Therefore, it could be estimated by regression analysis that in summer, urban vegetations in Pudong District could contribute to 9.1% of TSP removal, 5.3% of SO(2) and 2.6% of NO(2). The results could be considered for a better park planning and improving air quality.     

Response of denitrification genes <Emphasis Type="Italic">nirS</Emphasis>, <Emphasis Type="Italic">nirK</Emphasis>, and <Emphasis Type="Italic">nosZ</Emphasis> to irrigation water quality in a Chinese agricultural soil

Purpose  

Denitrification is an important biochemical process in global nitrogen cycle, with a potent greenhouse gas product N₂O. Wastewater irrigation can result in the changes of soil properties and microbial communities of agricultural soils. The purpose of this study was to examine how the soil denitrification genes responded to different irrigation regimes.     

Combined inverse modeling approach and load duration curve method for variable nitrogen total maximum daily load development in an agricultural watershed

Purpose  

Nonpoint sources (NPS) pollution has been an important cause for water quality impairment worldwide. To take the temporal variations of both NPS pollution and in-stream attenuation into consideration, an inverse modeling approach and the load duration curve (LDC) method were combined for variable nutrient total maximum daily load (TMDL) development.     

Ce-Sn-W-O_x催化剂的配伍优化及脱硝影响因素

采用共混热解法制备系列Ce-Sn-W-Ox复合氧化物,用于NH3选择性催化还原NO。通过正交实验优化CeSn-W-Ox配方,采用环境扫描电镜(ESEM)、X-射线衍射仪(XRD)等表征分析催化剂的微观形貌和固相结构,确立Ce-Sn-WOx最佳配比及结构形貌。结果表明,以粒度为5~8 mm的堇青石瓷片担载分散Ce-Sn-W-Ox,进行NH3-SCR脱除NO,当Ce/Sn/W元素摩尔比为1∶0.8∶0.6时,Ce Sn0.8W0.6Ox/堇青石NH3-SCR脱除NO效果最好。当空速为7 200 h-1,催化剂在252~426℃内脱除NO效率均大于94%。重点考察了反应空速(GHSV)、水蒸气(H2O)、SO2等对Ce Sn0.8W0.6Ox/堇青石NH3-SCR脱除NO活性的影响。研究表明,空速低于10 000 h-1时,催化剂脱硝活性受空速影响小;单独通入5%H2O对催化剂脱硝活性基本没有影响;单独通入429 mg/m3SO2导致催化剂活性略有降低;同时通入429 mg/m3SO2和5%H2O,催化剂脱硝活性下降至85.33%,除去SO2和H2O后,催化剂活性又能明显回升。     

Comprehensive Assessment and Promotion Policy of Producer Services’ Competitiveness in Beijing City:A Comparative Analysis among Beijing,Tianjin,Shanghai,Guangzhou and Shenzhen

The five central cities-Beijing,Tianjin,Shanghai,Guangzhou and Shenzhen-of the three most important strategic regions in China,namely Beijing-Tianjin-Hebei metropolitan region,the Yangtze River Delta and the Pearl River Delta,are taken as a comparative analysis on urban producer services’ competitiveness,especially focusing on the comparative advantages and disadvantages of producer services in Beijing.Firstly,based on an integrated indicator system including one objective hierarchy,four standard hierarchies and 35 indicator hierarchies,the study applies factor analysis model and analytic hierarchy process model reformed by entropy technology to measure the comprehensive competitiveness of producer services in the above five cities.Secondly,Beijing has comparative advantages of capital resource,industrial base,scientific research resource and market scale,since it takes the first place of the five cities in the comprehensive competitiveness of producer services,the competitiveness of industrial development,business environment and living environment,only inferior to Shanghai in the competitiveness of talent capital.Thirdly,Beijing has comparative disadvantages in the level of producer services development,urban innovation capability and living environment.Finally,five proposals are put forth to enhance the competitiveness of producer services in Beijing,namely perfecting the system of laws and statutes,supporting the development of industry association,implementing scientific development planning,introducing preferential fiscal and taxation policies and strengthening human capital reserve.     

A statistic comparison of multi-element analysis of low atmospheric fine particles (PM2.5) using different spectroscopy techniques

Over the past few decades, the metal elements(MEs) in atmospheric particles have aroused great attention. Some well-established techniques have been used to measure particlebound MEs. However, each method has its own advantages and disadvantages in terms of complexity, accuracy, and specific elements of interest. In this study, the performances of inductively coupled plasma–optical emission spectrometry(ICP-OES) and total reflection X-ray fluorescence spectroscopy(TXRF) were evaluated for qualit...