Novel CeO2@TiO2 core–shell nanostructure catalyst for selective catalytic reduction of NOx with NH3

The CeO₂@TiO₂ core–shell nanostructure catalyst prepared by a two-step hydrothermal method was used for selective catalytic reduction (SCR) of NOx with NH₃ in this study. The catalyst presented the obvious core–shell structure, and the shell was amorphous TiO₂ which could protect the active center from the SO₂ erosion. The catalyst showed high activity and stability, excellent N₂ selectivity and superior SO₂ resistance and H₂O tolerance. Characterizations such as TEM, HR-TEM, XRD, BET, XPS, NH₃-TPD, and H₂-TPR were carried out. The results indicated that the catalyst had large surface area and the active sites were well dispersed on the surface. The NH₃-TPD, H₂-TPR and XPS results implied that its increased SCR activity might be due to the enhancement of NH₃ chemisorption and the increase of active oxygen species, both of which were conductive to NH₃ activation. The excellent catalytic performance suggests that it is a promising candidate for SCR catalyst.     

SCR装置对焦炉煤气燃烧废气中PCDD/Fs、PCBs和PCNs的协同脱除

研究了某大型焦化厂的选择性催化还原(SCR)装置对焦炉煤气燃烧废气中典型非故意产生持久性有机污染物(UPPOPs)的脱除效果,对SCR装置入口和出口废气和SCR装置降尘中二英(PCDD/Fs)、多氯联苯(PCBs)和多氯萘(PCNs)的全部异构体进行了分析.结果表明,SCR装置对总PCDD/Fs的脱除效率最高,为94.6%,对总PCBs和总PCNs的脱除率分别为74.7%和78.4%.SCR装置入口和出口废气中UP-POPs同系物的分布模式明显不同,入口处以高氯取代为主,出口处以低氯取代为主.SCR装置对高氯取代UP-POPs有更好的脱除效果.催化还原和催化氧化降解同时发生是SCR装置脱除废气中UP-POPs的重要机制.     

分解炉分级燃烧降氮脱硝技术的研究与应用

低NOx高温燃烧技术与大容积分解炉系统有机结合，具有热效率高、分解炉温度分布均匀、降氮脱硝、NOx排放浓度低等特点。文章介绍了高温分级燃烧技术在水泥窑中的应用，重点分析了分级燃烧、降氮脱硝在分解炉系统中的应用原理，以及推广的价值。     

两种空气自动监测系统的比较

国产长光程空气自动监测系统是中国自行研制的更为先进、更具自动化的系统，24h点式仪器是老式空气检测仪器，对这两种新、老仪器的比较可以看出在运行过程中的利弊。     

关于构建中国石化劳动防护用品管理信息系统的设想

探讨了中国石化劳动防护用品管理信息系统的建设目标以及技术方案选择,提出了系统功能设想。     

由硫酸亚铁（绿矾）制取还原铁粉的工艺研究

提出了一种新的绿矾综合利用的途径,即绿矾经碳酸盐转化,然后采用无烟煤作还原剂,CaCO3为添加剂,进行高温还原焙烧制取还原铁粉.先将绿矾用水溶解,用理论量1.2倍的（NH4）2CO3将FeSO4转化为FeCO3,FeCO3焙烧的最佳条件是FeCO3∶无烟煤∶CaCO3为100∶60∶8,焙烧温度为1000℃,焙烧时间为4.5 h.粗还原铁粉化学成分除C含量较高外,符合国家有关标准,900℃左右经氢气精还原1 h所得精还原铁粉化学成分的各项指标,均达到或优于国家有关标准的要求.     

商品粮流通系统中的人为灾害影响分析

我国每年在收获、储运、加工和消费等环节的粮食损失和浪费高达1300亿kg,大大超过建国以来任何一次灾害带来的损失,直接影响国民经济的发展。目前,人为灾害对我国成品粮的影响未引起人们的足够重视。本文对此进行了系统分析,并提出相应之对策。     

论安全文化在安全监督中的应用

本文从铁路行业的特点出发，探讨和分析了我国安全生产管理体制中的群众监督的现状，研究了安全文化在安全生产群众监督（筒称安全监督）中的作用及其显著效果，指出了在铁路行业推行安全文化的深远意义和作用。     

压力驱动膜的污染与防治

介绍了各种压力驱动膜的适用范围,讨论了膜污染的机理,并从膜的性质、操作条件、料液的预处理和膜的清洗4个方面阐述了如何防治膜的污染。     

A new method for evaluating the sewage sludge pyrolysis kinetics

A new method to simplify calculation the kinetics model is applied to sewage sludge pyrolysis based on the assumption that volatile run out as soon as it formed and during temperature arising process in this study. Difference method widely used to solve math problems is conducted to calculate kinetics parameters. Pyrolysis experiments are carried out at heating rates of 10, 15, 20, and 50 °C/min. All the TG curves are divided into three parts which are beginning decomposition temperature range, main decomposition temperature range, and final decomposition temperature range. The second one is employed to determine the parameters for more than 70% of the total mass loss occurs in this range. According to the developed method, the react order, reaction energy and pre-exponential factor are obtained, which are in the range of 3.9–4.1, 82.3–109.2 kJ/mol and 7.7 × 10⁶–2.8 × 10⁹/min, respectively, which are in the range of that reported previously. As a comparison experimental data with calculated data, the well fitting results indicate that this method is appropriate for simulating sludge pyrolysis kinetics.