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采用化学法组合的三种工艺系统,对含酚废水进行了工艺条件的研究。结果表明,对于浓度<30mg/l含酚废水,采用氧化凝聚处理是有效的;而对于30~80mg/l含酚废水,选用氧化凝聚和吸附组合的工艺系统处理,能使排放水中酚和COD达标。 相似文献
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Luka Traven Vladimir Mićović Darija Vukić Lušić Tvrtko Smital 《Environmental monitoring and assessment》2013,185(11):9009-9018
The present study investigates the response of three hepatic biomarkers in adult sea bass (Dicentrarchus labrax, Linnaeus 1758) caged at a wastewater outlet of an oil refinery with fish caged at a pristine site used as controls. The biomarkers that were investigated were the hepatosomatic index (HSI), 7-ethoxyresorufin-O-deethylase (EROD) activity and glutathione-S-transferase (GST) activity. In addition, we have measured the levels of polycyclic aromatic hydrocarbons (PAHs) and selected heavy metals (lead, cadmium, mercury, copper and zinc) in sediment samples at the polluted site. Although the polluted site had high environmental levels of PAHs and heavy metals, there was no difference in hepatic EROD activity and HSI between fish caged at the polluted site and controls. On the other hand, GST activity was significantly lower in fish caged at the polluted site compared to controls. Our results point out that the studied biomarkers have limited use in environmental risk assessment studies, at least when caged adult sea bass is used as the sentinel species and complex toxicant mixtures are involved. 相似文献
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Fengzu Zhang Sufang Fan Shaowen Liu Xuesheng Li Canping Pan 《Environmental monitoring and assessment》2013,185(11):9101-9109
A modified LC-MS method for the analysis of mepiquat residue in wheat, potato, and soil was developed and validated. A hydrophilic interaction liquid chromatographic column has been successfully used to retain and separate the mepiquat. Mepiquat residue dynamics and final residues in supervised field trials at Good Agricultural Practice (GAP) conditions in wheat, potato, and soil were studied. The limits of quantification for mepiquat in all samples were all 0.007 mg kg?1, which were lower than their maximum residue limits. At fortification levels of 0.04, 0.2, and 2 mg kg?1 in all samples, recoveries ranged from 77.5 to 116.4 % with relative standard deviations of 0.4–7.9 % (n?=?5). The dissipation half-lives (T 1/2) of mepiquat in soil (wheat), wheat plants, soil (potato), and potato plants were 4.5–6.3, 3.0–5.6, 2.2–4.6, and 2.4–3.2 days, respectively. The final residues of mepiquat were below 0.153 mg kg?1 in soil (wheat), 0.052–1.900 mg kg?1 in wheat, below 0.072 mg kg?1 in soil (potato), and below 1.173 mg kg?1 in potato at harvest time. Moreover, pesticide risk assessment for all the detected residues was conducted. A maximum 0.0012 % of acceptable daily intake (150 mg kg?1) for national estimated daily intake indicated low dietary risk of these products. 相似文献