钢铁企业工艺节水的技术途径研究

水资源短缺是中国钢铁企业发展的瓶颈,大力推广节水技术对促进企业的可持续发展具有积极意义。针对中国钢铁企业生产工艺与设备普遍落后、用水量大、水循环回用率低、水资源严重浪费的用水现状,从开发利用非常规水源、推广节水型工艺技术、强化串级用水和循环用水、废水处理技术等几方面探讨了钢铁企业工艺节水的技术途径,并对钢铁企业节水工作提出了几点建议。     

用粉末活性炭作前助凝剂提高PAC除藻效果的研究

采用烧杯搅拌实验研究了用粉末活性炭作前助凝剂提高聚合氯化铝(PAC)去除铜绿微囊藻的有效性。结果表明,单独使用粉末活性炭作前助凝剂的除藻效果并不好,而先投加20 mg/L高岭土,再将15 mg/L PAC与粉末活性炭同时投加,除浊除藻效果明显提高。考虑首先充分发挥粉末活性炭对有机物的去除能力,在除浊除藻率仍然较高的情况下,采用粉末活性炭先于高岭土2 min投加的方式,粉末活性炭的最佳助凝剂量为10mg/L。采用粉末活性炭、高岭土和FeCl3依次投加的完整助凝技术路线,除浊除藻效率最高。碱性水体比酸性水体有利于联用三种助凝剂除藻。扫描电镜(SEM)观察结果表明,采用助凝技术,藻细胞主要与高岭土无机颗粒发生凝聚,投加粉末活性炭有助于絮凝体体积增长,而在絮凝阶段投加FeCl3可使絮凝体的分维数达到1.947的最高值。联用粉末活性炭、高岭土和FeCl3是非常有效的助凝除藻新技术。     

辽河盘锦段与河口海域水体氮素分布特征及其与溶解氧的关系

选取辽河盘锦段至河口近岸海域区域进行研究水体中氨氮、硝酸盐氮和亚硝酸盐氮的分布特征及其与溶解氧的关系进行研究。结果表明水中氮素含量高于海水,且氨氮表现尤为突出,可能与水体中溶解氧含量和微生物环境、海水的稀释和迁移有很大关系;河水中氮素与溶解氧的呈显著负相关,而海水中氮素与溶解氧的关系不明显。这可能与海水的质化作用有关。     

Spatial heterogeneity of cyanobacterial communities and genetic variation of Microcystis populations within large, shallow eutrophic lakes (Lake Taihu and Lake Chaohu, China)

Cyanobacteria, specifically Microcystis, usually form massive blooms in eutrophic freshwater lakes. Cyanobacterial samples were collected from eight sites of both Lake Taihu and Lake Chaohu in late summer to determine the diversity and distribution pattern of cyanobacteria and Microcystis in large, shallow, entropic lakes with significant spatial heterogeneity and long-term Microcystis bloom. Molecular methods based on denaturing gradient gel electrophoresis and clone library analysis were used. A similar heterogeneous distribution pattern of cyanobacteria in both lakes was observed. Most parts of these two lakes with high trophic level were dominated by Microcystis. However, in the regions with low trophic levels as well as low concentrations of chlorophyll a, Synechococcus occupied a considerable percentage. Different morphospecies and genotypes dominated the bloom-forming Microcystis populations in these two lakes. Microcystis viridis and Microcystis novacekii were dominant in Lake Chaohu, whereas Microcystis flos-aquae was dominant in Lake Taihu. Only 2 of the13 Microcystis operational taxonomic units were shared between these two lakes. Analysis of molecular variance based on 16S to 23S internal transcribed spacer sequences indicated the significant genetic differentiation of Microcystis between these two lakes (F_st = 0.19, p < 0.001). However, only 19.46% of the genetic variability was explained by the population variation between lakes, whereas most (80.54%) of the genetic variability occurred within the lakes. Phylogenetic analysis revealed no phylogeographic structure of Microcystis population in these two lakes, as illustrated by their cosmopolitan nature. Our results revealed that spatial heterogeneity within lakes has more impact on the cyanobacterial diversity than geographical isolation in a local scale.     

谈地磁观测中的温度效应

地磁场各要素的绝对数值是通过基线值来确定的,而基线值又与温度相关,是一条大致随温度变化的曲线。本文选取通海、贵阳、邵阳、天水等地磁台的基线值资料,计算各分量基线值与记录室温度的相关系数,判定基线值与温度之间的相关关系,掌握在不同记录室温度条件下,温度变化对地磁基线值以及地磁观测仪器的影响程度。以供其他地磁台站新建、改造观测记录室时借鉴。     

基于主成分分析法研究内蒙古环境质量的统计分析

生态环境问题一直以来制约着西部地区的经济发展,内蒙古作为以资源型开发为主要工业结构的自治区在这方面表现尤为突出。为了使内蒙古自治区借助实施西部大开发战略和开展生态环境建设的机会推进环境保护工作的进程,从环境污染和生态破坏角度运用主成分分析法评价内蒙古自治区2005年到2009年间环境质量。通过综合得分分析得出内蒙古环境质量逐年好转,而且环境质量整体优化速率逐年加快,通过主成分分析得到大气污染和工业污染是在不同领域影响自治区环境质量的主导因素,主要归因于内蒙古自治区工业结构以资源能源型为主、沙尘天气频繁出现以及追求经济快速增长所致的环境问题。     

滨海化工区废水预处理去毒技术耦合工艺研究

化工产业是天津滨海新区重要的支柱产业,该行业废水是滨海污染物控制的主要威胁。针对常规单一方法存在的问题,试验选取滨海某化工区实际废水从内电解-Fenton、内电解-混凝、内电解-超声及微波强化氧化-光催化4种耦合去毒预处理工艺进行了研究。试验表明,与传统方法相比,内电解-Fenton法中H2O2的加入增加了污染物的降解途径,提高了对污染物的去除效率;内电解-混凝法对于制药废水的生物毒性有比较好的去除作用,不加PAM或Ca(OH)2的效果更佳;内电解-超声法对制药废水的生物毒性去除率可达92%,其可生化性提高45%;微波强化氧化-光催化法对大多数难降解物质有效,而对酚类物质降解效果不佳。     

酸雨对广西典型碳酸盐岩地区碳源效应研究

选取广西两个典型碳酸盐岩地区桂林(代表灰岩地区)与柳州(代表白云岩地区)作为研究区域,研究酸雨与岩石表面反应,并计算出由酸雨对碳酸盐岩的化学风化过程中形成CO2成为碳源的量。利用溶蚀试片溶蚀速率以及GIS技术得到研究区由酸雨产生的CO2源为41.066×108 g/a,其中桂林市区速率为33.349×108 g/a,柳州市区速率为7.717×108 g/a。单位面积源桂林与柳州分别为66.967×105 g/a.km2和42.777×105 g/a.km2,虽然低于两地的单位面积汇分别为273.891×105 g/a.km2与43.660×105 g/a.km2,但已不容忽略。柳州市区CO2源的释放速率比桂林市区慢的原因主要有二:桂林市区碳酸盐岩的代表面积为柳州市区2.77倍;由于柳州酸雨总体强度比桂林低,导致碳酸盐岩的溶蚀速率较低。     

水污染防治领域的技术预见

针对水污染防治领域开展了技术预见研究。通过德尔菲调查法所获数据及其结果分析,确定出排名最高的10项技术课题,作为未来水污染防治领域的关键技术课题,其中共涉及6个领域:城镇污水处理与回用,饮用水净化与安全,工业废水处理与回用,农村、农业污水处理与回用,地下水体污染控制以及微量有毒物质的防控。分析表明,10项关键技术课题的预期实现时间集中在2014年-2018年;领先国家或地区主要是美国、日本和欧盟;发展路径选择最多的是集成创新的方式;技术本身可行性、市场需求、政策支持是最主要的3个制约其发展的因素;目前所处的阶段主要是实际应用阶段。     

Risk Assessment of Carbon Sequestration for Terrestrial Ecosystems in China

Abstract

Climate change will alter the capacity of carbon sequestration, and the risk assessment of carbon sequestration for terrestrial ecosystems will be helpful to the decision-making for climate change countermeasures and international climate negotiations. Based on the net ecosystem productivity of terrestrial ecosystems simulated by Atmosphere Vegetation Integrated Model, each grid of the risk criterion was set by time series trend analysis. Then the risks of carbon sequestration of terrestrial ecosystems were investigated. The results show that, in the IPCCSRES-B2 climate scenario, climate change will bring risks of carbon sequestration, and the high-risk level will dominate terrestrial ecosystems. The risk would expand with the increase of warming degree. By the end of the long-term of this century, about 60% of the whole country will face the risk; Northwest China, mountainous areas in Northeast China, middle and lower reaches plain of Yangtze River areas, Southwest China and Southeast China tend to be extremely vulnerable. Risk levels in most regions are likely to grow with the increase of warming degree, and this increase will mainly occur during the near-term to mid-term. Northwest China will become an area of high risks, and deciduous coniferous forests, temperate mixed forests and desert grassland tend to be extremely vulnerable.