Determination of PAHs by On-Line Polarization Synchronous Fluorescence with HPLC

A novel analytical method has been established for on-line simultaneous determination of fluorene and acenaphthene,chrysene and benzo[a]anthracene (B[a]A) by polarization synchronous fluoromet.y (PSF) coupled to high performance liquid chromatography (HPLC). The detection limits were: 0.039, 0.046, 0.016 and 0.042 mgL-1 for fluorene, acenaphthene, chrysene and B[a]A, respectively. The proposed method has been successfisily applied to simultaneous determination of these PAHs in environmental air and marine sediment samples.     

连续采样与五日法采样效果及费用的对比分析

通过对连续采样与五日法采样五种方法监测结果及所需费用的比较，得出连续采样方法监测结果更具有代表性，合理性，一次性投资大，但运行费用并不高的结论。     

Development of an ombrotrophic peat bog (low ash) reference material for the determination of elemental concentrations

Given the increasing interest in using peat bogs as archives of atmospheric metal deposition, the lack of validated sample preparation methods and suitable certified reference materials has hindered not only the quality assurance of the generated analytical data but also the interpretation and comparison of peat core metal profiles from different laboratories in the international community. Reference materials play an important role in the evaluation of the accuracy of analytical results and are essential parts of good laboratory practice. An ombrotrophic peat bog reference material has been developed by 14 laboratories from nine countries in an inter-laboratory comparison between February and October 2002. The material has been characterised for both acid-extractable and total concentrations of a range of elements, including Al, As, Ca, Cd, Cr, Cu, Fe, Hg, Mg, Mn, Na, Ni, P, Pb, Ti, V and Zn. The steps involved in the production of the reference material (i.e. collection and preparation, homogeneity and stability studies, and certification) are described in detail.     

乌鲁木齐市餐饮业油烟污染的调查及防治初探

通过对乌鲁木齐市20家餐饮业油烟污染的调查分析，结果表明，乌鲁木齐市餐饮业油烟污染严重，并提出了防治措施。     

离子交换树脂光度法测定微量铁的研究

研究了以阳离子交换树脂为显色载体，利用直接吸附在树脂上有色络合物－Fe(II)邻二氮菲的吸光度，借以检测水和火腿肠中铁的新方法，本法具有比原子吸收法更高的灵敏度，稳定性和选择性，并对成络及树脂吸附条件作了较详细研究。     

Determination of Trace Organochlorinated Pesticides and Polychlorinated Biphenyls in Water

A modified steam distillation liquid-liquid extraction (SDE) device is developed for the enrichment of trace organochlorinated pesticides (OCPs) and polychlorinated biphenyls (PCBs) in up to one litre of water samples. One ml of n-hexane is sufficient to extract the analytes. The extract can be analysed directly by a capillary gas chromatography-electron capture detector. The recoveries range from 84.6 to 102.3% for OCPs and 80.5 to 106.2% for PCBs, respectively. Matrice materials such as lipids and humic substances were removed by the SDE method from the extract and no further cleanup and concentration steps were needed.     

哈密地区环境中^220Rn子体α潜能浓度所致居民剂量估算

用ＳｔｒａｎｄｅｎＥ．推荐的测量方法对哈密地区环境空气中２２０Ｒｎ子体α潜能浓度测量结果表明，室内、外平均值分别为５６．１和１０．２（×１０－７Ｊ·ｍ－３）。室内外２２０Ｒｎ／２２２Ｒｎ子体α潜能浓度比值分别为０．８４和０３２。２２０Ｒｎ子体所致居民有效剂量当量为２２８μＳｖ·ａ－１（集体有效剂量当量为０．９×０２ｍａｎ·Ｓｖ）。     

Preliminary studies of a fast screening method for polycyclic aromatic hydrocarbons in soil by using solvent microextraction-gas chromatography

Solvent microextraction (SME) was applied to the extraction of polycyclic aromatic hydrocarbons (PAHs) from spiked and real environmental soil samples with different matrices. Soil sample was mixed with 7 mL of acetone and 14 mL of water to allow partitioning of the PAHs from the soil to the liquid phase. A 2 microL octane drop suspended from a microsyringe needle tip was then immersed into the stirred solution-soil mixture for extraction. After an 11 min extraction, the octane drop was withdrawn into the syringe and injected directly into the GC for identification and quantification. The whole analysis procedure took 27 min, with an extraction time of 11 min, and a GC separation time of 16 min. A second extraction could be undertaken whilst the GC is running, hence the GC run time currently limits the sample throughput. In this method, a small amount of organic solvent was used for the extraction process, which produced little waste. The limits of detection for lower molecular weight (< 230) PAHs range from 0.13 to 0.36 mg kg-1, and for higher molecular weight (> 250) PAHs are estimated to be between 0.5 and 1.0 mg kg-1, with RSD values generally under 20%. Due to the small volumes of organic solvent used, the consumable cost per extraction is only US$ 0.12. This is the first report of the application of SME to solid samples, and the first report of the use of SME for the analysis of PAHs.     

乌鲁木齐市汽车尾气污染状况调查

对乌鲁木齐市主要街道受汽车尾气污染的调查和综合分析得到CO、NOx、HC的污染规律,主要街道路中心空气中CO、NOx日均值已超出国家大气环境质量二级标准,市区主要街道的人行道空气中NOx含量已超出二级标准,Ⅱ、Ⅲ类道路人行道空气中CO含量已超标;在三类街道中,Ⅰ类街道车流量最大,Ⅱ类次之,Ⅲ类最少,而汽车排放尾气对街道空气污染状况为Ⅲ类最重、Ⅱ类次之、Ⅰ类最轻。     

某铀矿工人头发中总α,总β,铀,钍放射性水平的调查

本文对某铀矿职业工人和非职业工人头发中的总β、总α放射性水平和铀、钍含量进行了分析测定.结果表明,该矿工人体内铀和钍的蓄积量均在正常放射性本底水平范围内,从头发中检验未观察到工人体内铀、钍放射性水平有明显的升高.