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非固定化和固定化啤酒酵母对Cd2+和Cu2+的吸附特性研究 总被引:2,自引:1,他引:1
对比了不同吸附剂对重金属的吸附效果,同时研究了啤酒酵母的固定化方法、菌体用量对吸附效果的影响、非固定化和固定化啤酒酵母吸附热力学特性。研究结果表明,非固定化死啤酒酵母对Cd2+的单位菌体吸附量是常用吸附剂活性炭的3倍;由1∶3的海藻酸钠与碱处理啤酒酵母(w/w)制得的固定化颗粒吸附效果最好;菌体用量的增加会降低单位菌体对重金属的吸附量;啤酒酵母对重金属的吸附位点有限,Cd2+的实际最大吸附量为13.95 mg/g,Cu2+为7.67 mg/ 相似文献
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研究了水解酸化与生物接触氧化组合循环工艺处理猪养殖场废水厌氧发酵液的脱氮特性,重点考察了组合工艺的最佳运行工况和参数,同时讨论了组合工艺低温运行的性能。结果表明,水力停留时间24 h和污水循环比1∶3为最佳运行工况,此时出水氨氮浓度为2.16~8.20 mg/L。溶解氧(DO)浓度2~3 mg/L和有机负荷3 g/L以下为最佳运行参数,出水氨氮浓度稳定在10 mg/L以下。在春季低温条件下(8~12℃),组合工艺也能较好运行,水解酸化池内小分子有机酸产生总量为114.50~244.22 mg/L。组合工艺连续运行3个月以上,污染物去除效果稳定。 相似文献
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雨水中新污染物(ECs)识别逐渐受到广泛关注,掌握其在降水过程赋存及迁变特性成为雨水资源化利用的关键. 选取典型屋面,研究了2023年春季3~5月期间6场降雨事件不同集汇过程中雨水水质状况及ECs赋存差异,采用主成分分析(PCA)和相关性分析,探明了屋面雨水集汇过程中ECs归趋特性. 结果表明,54种目标ECs在净湿沉降、干湿沉降和屋面径流过程中共检出44种,总浓度范围为63.0~432.4 ng·L-1(平均值为166.8 ng·L-1). 其中,双酚A(BPA)浓度水平最高,其范围为14.7~265.6 ng·L-1(平均值为62.5 ng·L-1),其次为氧氟沙星(OFX)和甲氧基肉桂酸乙基己酯(EHMC);溶解性有机质(DOM)、氮污染物和颗粒物是影响ECs赋存特性的重要因子,Mantel相关系数最高可达0.98(P<0.01);初期雨水集汇过程中净湿沉降的ECs浓度最高,而后期干湿沉降和屋面径流的ECs浓度较高,干、湿沉降对屋面径流的ECs平均贡献率分别为21.48%和78.52%,药品与个人护理品(PPCPs)、内分泌干扰物(EDCs)和农药等在集汇过程中超30%沉积在屋面. 研究结果可为城市屋面径流中的ECs识别和控制以及雨水安全利用提供科学理论依据. 相似文献
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Determination of butyltin compounds in sedimentsby gas chromatography with flamephotometric detector
DeterminationofbutyltincompoundsinsedimentsbygaschromatographywithflamephotometricdetectorXuFuzheng;ZanJun;JiangGuibin;HanHen... 相似文献
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A 60-year sedimentary record of natural and anthropogenic impacts on Lake Chenghai, China 总被引:1,自引:0,他引:1
Fengyu Zan Shouliang Huo Beidou Xi Jingtian Zhang Haiqing Liao Yue Wang Kevin M. Yeager 《环境科学学报(英文版)》2012,24(4):602-609
Recent sediments from Lake Chenghai, China, were investigated at high temporal resolution to trace both natural and anthropogenic effects on the lake using total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP), organic phosphorus (Po), inorganic phosphorus (Pi) and organic carbon and nitrogen stable isotopes (δ13Corg and δ15N) in a 137Cs-dated sediment core. The results indicated that the sedimentary record covers the last 60 years, during which the lake had undergone apparent changes in nutrient sources and productivity in response to nutrient loading. Prior to the late 1980s, the nutrient contents in sediments mainly originated from algae and lake productivity was relatively stable. Since the late 1980s, increasing TOC, TN and TP concentrations together with the change of δ13Corg and δ15N suggested anthropogenic perturbations in nutrient loading and lake productivity. Endogenic nutrients derived from algae and anthropogenic inputs were two important sources of sedimentary nutrients. The anthropogenic nutrients mainly originated from the discharge of industrial wastewater and artificial cultivation of Spirulina after the middle 1980s, and domestic wastewater discharged from Yongsheng County since 1993. 相似文献
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Zhiguang Zhou Yue Ren Jiazhi Chu Nan Li Sen Zhen Hu Zhao Shuang Fan Hui Zhang Pengjun Xu Li Qi Shuting Liang Bin Zhao 《环境科学学报(英文版)》2016,28(6):244-251
To assess the influence of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans(PCDD/Fs) on the environment in the vicinity of municipal solid waste incinerators(MSWIs), we determined the levels of PCDD/Fs in air and soil samples collected around a MSWI, which is the largest in China. The International Toxicity Equivalency Quantity(I-TEQ) concentrations of PCDD/Fs in air samples were from 0.0300 to 1.03 pg I-TEQ/m~3(0.445–13.6 pg/m~3), with an average of 0.237 pg I-TEQ/m~3, while in soil samples they ranged from 0.520 to 3.40 pg I-TEQ/g(2.41–88.7 pg/g) with an average of1.49 pg I-TEQ/g. The concentrations of PCDD/Fs in air and soil samples were comparable to other areas, and Pe CDFs were the dominant contributors, which was different from stack gas homologue patterns. Multivariate statistical analysis showed that PCDD/Fs emission from the MSWI did not directly affect the profiles of PCDD/Fs in air and soils, so that vehicles and unidentified emission sources should be considered. The daily inhalation levels of PCDD/Fs for children(0.0110 to 0.392 pg I-TEQ/(kg·day) and adults(0.00600 to 0.221 pg I-TEQ/(kg·day) near the MSWI were lower than the tolerable daily intake of 1.00 to 4.00 pg WHO-TEQ/(kg·day), but in winter the values were higher than in summer. These results can be used as basic data for assessing the risk of PCDD/Fs exposure in residents living around this MSWI, and more monitoring programs and studies should be carried out around MSWIs. 相似文献