废物水泥窑共处置产品中重金属的释放特性

选用欧盟固体中无机组分有效量测试方法(EA NEN7371)和块状材料中无机组分的扩散实验方法(EA NEN7375),研究了模拟混凝土样品中重金属(Cr、Ni、As、Cd和Pb)的释放特性.结果表明,混凝土中重金属的有效释放量低于总量;不同重金属的有效释放量与总量比值差异较大.扩散控制是混凝土中Cr、Ni和Cd释放的主要机理,释放曲线与斜率为0.5的直线拟合较佳,且不同区间浸出量曲线的斜率均在0.35~0.65范围内;As在释放前期有延滞现象,但中后期仍以扩散控制为主;Pb的释放为溶解控制,受浸取液的pH值影响较大.重金属扩散系数负对数值按Pb相似文献   

多米诺事故情景下的区域环境风险评价

将多米诺效应纳入化工区环境风险评价中,采用扩展概率模型和蒙特卡洛模拟的方法计算多米诺事故的概率,运用大气和水扩散模型模拟污染事故的后果,进而利用地理信息系统分析在多米诺事故情景下的区域环境风险水平.结果表明,研究区域67.5%的风险源能引发二次事故,平均每个初始事故引发9.58次二次事故、17.21次三次事故.二次事故情景和三次事故情景下的区域环境风险值分别是一次事故的6.40倍和12.33倍,多米诺效应明显放大了区域环境风险值,应成为今后风险防范的重点.     

多级强化地下水修复技术对NH_4~+-N的去除机制

为解决地下水污染修复技术中PT(抽出处理)和PRB(渗透性反应墙)存在的一些不足,搭建了MET(多级强化地下水修复技术)小试装置,以NH4+-N为目标污染物,研究MET对地下水中NH4+-N的去除效果及机制.结果表明,在进水水力负荷为14.68 m3/(m2·d)、ρ(NH4+-N)为25.0 mg/L的条件下,装置连续运行45 d,NH4+-N去除率呈先降后升、平稳后再下降的趋势,平均值达90%以上.出水ρ(NH4+-N)平均值为2.0 mg/L,其中,硝化作用和微生物同化作用使ρ(NH4+-N)平均下降13.9和5.2mg/L,分别占进水ρ(NH4+-N)的54%和20%;植物作用、基质永久吸附作用和挥发作用分别使ρ(NH4+-N)下降2.9、0.7和0.7mg/L,占进水ρ(NH4+-N)的12%、3%和3%.综上,MET对地下水中NH4+-N的去除率可达90%,实现了高效去除NH4+-N的目标.     

道路交通噪声预测声源简化研究

为了分析《环境影响评价技术导则声环境》(HJ 2.4—2009)中将道路声源简化为1条位于道路中心线处的线声源与按照车道数简化为多条线声源之间的误差,针对不同宽度的道路,推导了多条线声源与1条线声源在接收点噪声影响的误差计算公式,并基于Predictor-lima预测软件预测和现场噪声衰减规律实测进行了验证。研究结果表明,对于接收点到道路边缘的距离大于道路宽度的情况,可简化为1条线声源;对于接收点到道路边缘的距离小于道路宽度的情况,应按照车道数简化为多条线声源。     

Performance of different macrophytes in the decontamination of and electricity generation from swine wastewater via an integrated constructed wetland-microbial fuel cell process

Plants constitute a major element of constructed wetlands(CWs).In this study,a coupled system comprising an integrated vertical flow CW(IVCW) and a microbial fuel cell(MFC) for swine wastewater tre atment was developed to research the effects of macrophytes commonly employed in CWs,Canna indica,Acorus calamus,and Ipomoea aquatica,on decontamination and electricity production in the system.Because of the different root types and amounts of oxygen released by the roots,the rates of chemical oxygen demand(COD) and ammonium nitrogen(NH_4~+-N) removal from the swine wastewater differed as well.In the unplanted,Canna indica,Acorus calamus,and Ipomoea aquatica systems,the COD removal rates were 80.20%,88.07%,84.70%,and 82.20%,respectively,and the NH_4~+-N removal rates were 49.96%,75.02%,70.25%,and 68.47%,respectively.The decontamination capability of the Canna indica system was better than those of the other systems.The average output voltages were 520±42,715±20,660±27,and 752±26 mV for the unplanted,Canna indica,Acorus calamus,and Ipomoea aquatica systems,respectively,and the maximum power densities were 0.2230,0.4136,0.3614,and0.4964 W/m~3,respectively.Ipomoea aquatica had the largest effect on bioelectricity generation promotion.In addition,electrochemically active bacteria,Geobacter and Desulfuromonas,were detected in the anodic biofilm by high-throughput sequencing analysis,and Comamonas(Proteobacteria),which is widely found in MFCs,was also detected in the anodic biofilm.These results confirmed the important role of plants in IVCW-MFCs.     

H_2O_2致大鼠RTE细胞系氧化应激作用及GSH保护作用的体外研究

许多具有氧化作用的空气污染物,均能使细胞产生氧化损伤,使胸腺基质淋巴生成素(thymic stromal lymphopoietin,TSLP)含量上升。而TSLP是一种启动过敏性炎症的重要因子,会导致哮喘等疾病发生率的上升。在本研究中用过氧化氢(H_2O_2)模拟具有氧化作用的空气污染物进行染毒,研究细胞氧化应激水平的变化,并讨论还原型谷胱甘肽(GSH)对细胞受氧化损伤的保护作用。将大鼠支气管上皮细胞(RTE)分组培养,每组设置6个平行实验,分别用低、中、高剂量H_2O_2染毒3 h;高剂量设置1个重复,作为保护组,在染毒前用GSH保护2 h。结果显示,高剂量组H_2O_2(3.2 mmol·L~(~(-1)))染毒的细胞,其细胞活力下降(P0.01),丙二醛(MDA)水平上升(P0.01),TSLP水平上升(P0.05),与之相比,用GSH保护后的同剂量染毒组,上述指标得到全面缓解(P0.01)。这表明高浓度的H_2O_2会损伤细胞活力,并使MDA及TSLP水平上升,而GSH对TSLP及MDA的升高有极显著的抑制作用,即对细胞有一定的保护作用。     

珊瑚碎屑颗粒内孔隙特性微观试验研究∗

珊瑚碎屑是一种特殊的岩土材料,其显著特征是存在大量的内孔隙。为了深入揭示珊瑚碎屑内孔隙特性,通过电镜扫描(SEM)和压汞试验(MIP),分别定性和定量化地分析了珊瑚碎屑颗粒表面及内部孔隙形态特征和分布规律。结果表明:珊瑚碎屑存在由珊瑚虫生长和微生物共生形成的两类大小、形态及分布不同的内孔隙;珊瑚碎屑的整体孔隙度为9%～25%,由珊瑚虫生长而形成的孔隙等效直径为10～200μm;由微生物形成的孔隙面孔隙度低,孔隙直径多为4μm以下,且等轴或不等轴孔隙占绝大部分。     

基于数据挖掘的施工危险识别注意投入与分配研究*

为分析施工情境中危险识别注意资源动态投入分配规律,基于动态时间规整算法,挖掘危险识别注视轨迹序列,以表征注意资源投入分配变化,并采用k-means聚类、注视熵、Needleman-Wunsch全局序列对齐算法和统计等方法,深入挖掘注意资源在危险目标中投入和分配等时空变化规律。研究结果表明:当事人危险识别各阶段注意资源呈现从显著目标到高危目标的投入变化趋势,危险识别注意资源分配随情境复杂因素呈现零散、均匀的空间特征,分配无序程度提高。     

兴隆山油松树轮宽度与太阳年辐射总量的关系分析

利用采自兰州市榆中县兴隆山自然保护区的油松树轮资料,建立了研究区域的树轮STD年表。并利用1960?—?2016年该区域的太阳年辐射总量资料,将油松树轮宽度与太阳年辐射总量的年际变化趋势相比较,利用Pearson分析初步探究其相关性。采用滑动相关分析等方法,探讨了研究区域油松树轮宽度与太阳年辐射总量的关系随时间的变化。结果表明：树轮宽度与太阳年辐射总量在年际上存在较为一致的变化趋势,且该树轮宽度标准化年表对研究区域太阳年辐射总量具有一定的指示意义。在此基础上设计转换方程,利用多元回归技术重建了研究区1640?—?2015年的太阳年辐射总量变化历史,重建序列的方差解释量为36.9%（F?=?15.206,p?相似文献   

Insights into reactive oxygen species formation induced by water-soluble organic compounds and transition metals using spectroscopic method

Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future.