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111.
112.
Minhui XU Xiaogang GU Shuguang LU Zhouwei MIAO Xueke ZANG Xiaoliang WU Zhaofu QIU Qian SUI 《Frontiers of Environmental Science & Engineering》2016,10(3):438-446
The thermally activated persulfate (PS) degradation of carbon tetrachloride (CT) in the presence of formic acid (FA) was investigated. The results indicated that CT degradation followed a zero order kinetic model, and CO 2 – · was responsible for the degradation of CT confirmed by radical scavenger tests. CT degradation rate increased with increasing PS or FA dosage, and the initial CT had no effect on CT degradation rate. However, the initial solution pH had effect on the degradation of CT, and the best CT degradation occurred at initial pH 6. Cl– had a negative effect on CT degradation, and high concentration of Cl– displayed much strong inhibition. Ten mmol·L–1HCO 3 – promoted CT degradation, while 100 mmol·L–1NO 3 – inhibited the degradation of CT, but SO 4 2– promoted CT degradation in the presence of FA. The measured Cl–concentration released into solution along with CT degradation was 75.8% of the total theoretical dechlorination yield, but no chlorinated intermediates were detected. The split of C-Cl was proposed as the possible reaction pathways in CT degradation. In conclusion, this study strongly demonstrated that the thermally activated PS system in the presence of FA is a promising technique in in situ chemical oxidation (ISCO) remediation for CT contaminated site. 相似文献
113.
<正>2008年5月12日,是所有中国人永远铭记的日子。当四川汶川发生特大地震后,解放军、武警、消防、医护、专业救援队等各种救援人员迅速奔赴灾区开展各种营救工作。而从事救援工作的这些人员,每天面对灾难场面和危险的境地,许多人都会出现情绪和情感上的压力或心理创伤,如何积极适时地为灾后救援人员进行心理危机干预和心理疏导,是摆在我们面前的一个新课题。 相似文献
114.
Mitra PS Ghosh S Zang S Sonneborn D Hertz-Picciotto I Trnovec T Palkovicova L Sovcikova E Ghimbovschi S Hoffman EP Dutta SK 《Environment international》2012,39(1):188-199
The chemical composition of persistent organic pollutants (POPs) in the environment is not uniform throughout the world, and these contaminants contain many structurally different lipophilic compounds. In a well-defined study cohort in the Slovak Republic, the POP chemicals present in the peripheral blood of exposed children were chemically analyzed. The chemical analysis data revealed that the relative concentration and profile of structurally different organic pollutants, including polychlorinated biphenyls (PCBs), 2,2′-bis(4-chlorophenyl)-1,1-dichloroethylene (p,p′-DDE), 2,2′-bis(4-chlorophenyl)-1,1,1-trichloro-ethane (p,p′-DDT), hexachlorobenzene (HCB) and β-hexachlorocyclohexane (β-HCH), may vary from individual to individual, even within the same exposure area. These chemicals can be broadly classified into two groups. The first group, the PCB congeners, primarily originated from industrial compounds and their byproducts. The second group of compounds originated from or was commonly used in the agricultural sector (e.g., DDT, HCB). The objective of this study was to examine the effects of the two POP exposure profiles on gene expression. For the study population, we selected pre-pubertal girls (mean age of 46.2 ± 1.4 months) with high POP concentrations in their blood (> 75% tile of total POP) and classified them in the high ‘PCB’ group when the total PCB concentration was significantly higher than the total concentration of other POP components and in the ‘Other Than PCB’ (OTP) group, when the total PCB concentration was significantly lower than the concentration of the other major POP constituents. A matched control group of girls (< 25% tile of total POP) was selected for comparison purpose (n = 5 per group). Our aims were to determine whether there were any common effects of high POP exposure at a toxicogenomic level and to investigate how exposure may affect physiological functions of the children in two different exposure scenarios. Global gene expression analysis using a microarray (Affymetrix Gene Chip Human genome U133 Plus 2.0 Array) platform was conducted on the total RNA of peripheral blood mononuclear cells from the girls. The results were analyzed by Partek GS, Louis, MI, which identified twelve genes (ATAD2B, BIVM, CD96, CXorf39, CYTH1 ETNK1, FAM13A, HIRA, INO80B, ODG1, RAD23B, and TSGA14) and two unidentified probe sets, as regulated differentially in both the PCB and OTP groups against the control group. The qRT-PCR method was used to validate the microarray results. The Ingenuity Pathway Analysis (IPA) software package identified the possible molecular impairments and disease risks associated with each gene set. Connective tissue disorders, genetic disorders, skeletal muscular disorders and neurological diseases were associated with the 12 common genes. The data therefore identified the potential molecular effects of POP exposure on a genomic level. This report underscores the importance of further study to validate the results in a random population and to evaluate the use of the identified genes as biomarkers for POP exposure. 相似文献
115.
地倾斜观测是目前我国作为探索地震前兆的重要手段之一,实践证明地倾斜与地震存在着一定的对应关系.本文尝试利用淮北台FSQ型及JB型倾斜仪的观测结果,通过分析,获取与全球、全国强震有关的短临前兆信息以及总结其基本特征,得到了一些经验性认识. 相似文献
116.
117.
以pH作为SBR法硝化过程模糊控制参数的基础研究 总被引:13,自引:0,他引:13
为实现SBR法处理啤酒废水硝化时间的在线模糊控制,系统地研究了不同碱度类型和浓度对SBR法硝化过程中pH变化规律的影响,同时考察了DO和ORP的变化规律。结果表明,硝化过程中pH的变化可以分为下降型和上升型,下降型有ρ(HCO3^-)适量和不足两种情况,ρ(HCO3^-)适量时,pH在硝化结束时由下降转为上升;ρ(HCO3^-)不足时,pH在硝化结束时下降速率变小;根据pH这些变化特征控制硝化终点;下降型是最普遍的情形,上升型是ρ(HCO3^-)过分充足的情况,在硝化过程和硝化结束之间,pH一直呈现上升趋势,不能根据pH的变化来控制硝化时间,若ψ(曝气量)适宜,可以通过DO来判断硝化终点;上升型在实际中很少出现,pH以上变化规律不仅可以判断硝化时间,还可以判断硝化反应过程中ρ(HCO3^-)充足与否,在此基础上,建立了SBR法硝化时间的模糊控制规则。图7表1参16。 相似文献
118.
Xuguang TANG Shuying WANG Yongzhen PENG 《Frontiers of Environmental Science & Engineering》2010,4(4):475-481
The characteristic of phosphorus removal and appropriate change of the traditional operation modes were investigated in UniFed sequencing batch reactor (SBR) laboratory-scale apparatus (40 L), treating actual domestic wastewater with low ratios of C/N (2.57) and C/P (30.18), providing theoretical basis for actual application of wastewater treatment plant. UniFed SBR system with its unique operation mode had the distinct superiority of phosphorus removal. On this occasion, the effect of volumetric exchange ratio (VER) and the method of influent introduction for phosphorus removal were studied. When the carbon source became the limiting factor to phosphorus release, the higher the VER, the lower the phosphorus concentration in the effluent. Three different influent patterns, including one-time filling, four-time filling, and continuous filling with the same quantity of wastewater could increase the release rate of anaerobic phosphorus from 0.082 to 0.143 mg·P·(L·min)-1. Appropriate change of the traditional operation modes could optimize the efficiency of phosphorus removal. When the feed/ decant time was extended from 2 h to 4 h, the phosphorous removal efficiency increased from 59.93% to 88.45% without any external carbon source. In the mode of alternation of anoxic-aerobic (A/O) condition, phosphorous removal efficiency increased from 55.07% to 72.27% clearly. The carbon source in the influent can be used adequately, and denitrifying phosphorus removal was carried out in anoxic stage 2 (A2). This mode was optimal for the treatment of actual domestic wastewater with low C/N and C/P ratios. 相似文献
119.
Daizhou Zhang Guangyu Shi Yasunobu Iwasaka Min Hu Jiaye Zang 《Water, Air, & Soil Pollution: Focus》2005,5(3-6):261-276
Analysis of individual particles collected at Beijing in northern China revealed that particles abundant in calcium (Ca) always
constituted a large fraction of mineral particles in the urban atmosphere. The particles were characterized by cubic morphologies.
The major mineral element in the particles was Ca and few or no other mineral elements were detected. A large number of the
particles were in the range of diameter <1 μm, where common natural mineral particles were rarely detected. The contribution
of the Ca particles to the volume of total mineral particles greatly exceeded that of other mineral particles during non-dust-storm
periods and was comparable to that during dust-storm periods. Reagent film tests showed that particulate sulfate and nitrate
formation on the Ca particles was similar to that on common mineral particles. These results indicate that a large portion
of Ca in the atmospheric particulate matter in Beijing was from anthropogenic sources rather than from natural sources, and
the anthropogenic Ca particles acted as a significant medium for the formation of sulfate and nitrate. Similar particles were
also detected at Qingdao, a coastal city in northern China. Data of a dust storm event showed that Ca-abundant particles from
East China arrived there and moved out of the continent, similarly to Asian dust storm particles, suggesting possible contributions
of anthropogenic Ca even in Asian dust storm samples in the downstream areas. Therefore, Ca may not be a good indicator of
Asian dust from natural sources. However, the Ca particles, due to their unique shapes and elemental compositions, may provide
an indicator for the atmospheric dispersion of anthropogenic particulate matters in East Asia. 相似文献
120.