Hemin dialkylphosphate compounds

The Science of Nature -     

Predicting particle deposition on HVAC heat exchangers

Particles in indoor environments may deposit on the surfaces of heat exchangers that are used in heating, ventilation and air conditioning (HVAC) systems. Such deposits can lead to performance degradation and indoor air quality problems. We present a model of fin-and-tube heat-exchanger fouling that deterministically simulates particle impaction, gravitational settling, and Brownian diffusion and uses a Monte Carlo simulation to account for impaction due to air turbulence. The model predicts that <2% of submicron particles will deposit on heat exchangers with air flows and fin spacings that are typical of HVAC systems. For supermicron particles, deposition increases with particle size. The dominant deposition mechanism for 1–10 μm particles is impaction on fin edges. Gravitational settling, impaction, and air turbulence contribute to deposition for particles larger than 10 μm. Gravitational settling is the dominant deposition mechanism for lower air velocities, and impaction on refrigerant tubes is dominant for higher velocities. We measured deposition fractions for 1–16 μm particles at three characteristic air velocities. On average, the measured results show more deposition than the model predicts for an air speed of 1.5 m s⁻¹. The amount that the model underpredicts the measured data increases at higher velocities and especially for larger particles, although the model shows good qualitative agreement with the measured deposition fractions. Discontinuities in the heat-exchanger fins are hypothesized to be responsible for the increase in measured deposition. The model and experiments reported here are for isothermal conditions and do not address the potentially important effects of heat transfer and water phase change on deposition.     

Currents connecting communities: nearshore community similarity and ocean circulation

Understanding the mechanisms that create spatial heterogeneity in species distributions is fundamental to ecology. For nearshore marine systems, most species have a pelagic larval stage where dispersal is strongly influenced by patterns of ocean circulation. Concomitantly, nearshore habitats and the local environment are also influenced by ocean circulation. Because of the shared dependence on the seascape, distinguishing the relative importance of the local environment from regional patterns of dispersal for community structure remains a challenge. Here, we quantify the "oceanographic distance" and "oceanographic asymmetry" between nearshore sites using ocean circulation modeling results. These novel metrics quantify spatial separation based on realistic patterns of ocean circulation, and we explore their explanatory power for intertidal and subtidal community similarity in the Southern California Bight. We find that these metrics show significant correspondence with patterns of community similarity and that their combined explanatory power exceeds that of the thermal structure of the domain. Our approach identifies the unique influence of ocean circulation on community structure and provides evidence for oceanographically mediated dispersal limitation in nearshore marine communities.     

Antarctic krill aggregation characteristics from acoustic observations in the Southwest Atlantic Ocean

The distributional features and physical characteristics of 4830 krill (Euphausia superba Dana) aggregations detected acoustically in the Southwest Atlantic between 26 January and 21 February 1981 are described. Results are compared with aggregations detected in the Indian Ocean. Aggregations in the Atlantic were larger, closer to the surface and to each other than in the Indian Ocean. Similar patterns in the distribution of aggregation spacing along survey transects were found in the two areas, although the pattern of spacings in the Atlantic indicates differences in the scale of aggregation. Serial interdependence of aggregation variables was minimal in the Atlantic, with aggregation thickness, length and spacing showing weak inter-relationships. Weak functional association, between water depth and aggregation thickness was evident. Investigation of variability in aggregation structure in relation to prevailing environmental conditions gave equivocal results and no clear association between any aggregation variable and prevailing hydrography was observed. The implications of these results for future studies on krill aggregation are discussed in relation to a conceptual framework which was developed from the present results and aimed at linking krill aggregation characteristics to environmental features.     

Social influences on body size and developmental time in the bumblebee Bombus terrestris

In many social insects, including bumblebees, the division of labor between workers relates to body size, but little is known about the factors influencing larval development and final size. We confirmed and extend the evidence that in the bumblebee Bombus terrestris the adult bee body size is positively correlated with colony age. We next performed cross-fostering experiments in which eggs were switched between incipient (before worker emergence) and later stage colonies with workers. The introduced eggs developed into adults similar in size to their unrelated nestmates and not to their same-age full sisters developing in their mother colony. Detailed observations revealed that brood tending by the queen decreases, but does not cease, in young colonies with workers. We next showed that both worker number and the queen presence influenced the final size of the developing brood, but only the queen influence was mediated by shortening developmental time. In colonies separated by a queen excluder, brood developmental time was shorter in the queenright compartment. These findings suggest that differences in body size are regulated by the brood interactions with the queen and workers, and not by factors inside the eggs that could vary along with colony development. Finally, we developed a model showing that the typical increase in worker number and the decrease in brood contact with the queen can account for the typical increase in body size. Similar self-organized social regulation of brood development may contribute to the optimization of growth and reproduction in additional social insects.     

Evaluating cumulative effects of disturbance on the hydrologic function of bogs,fens, and mires

Few quantitative studies have been done on the hydrology of fens, bogs, and mires. Consequently predicting the cumulative impacts of disturbances on their hydrologic functions is extremely difficult. For example, few data are available on the role of bogs and fens with respect to flood desynchronization and shoreline anchoring. However, recent studies suggest that very small amounts of groundwater discharge are sufficient to radically modify mire surface-water chemistry, and consequently, vegetation communities and their associated surface-water hydrology. Bogs and fens are, in a sense, hydrobiologic systems, and any evaluation of cumulative impacts will have to (1) consider the complicated and little understood interactions among wetland hydrology, water chemistry, and biota, and (2) place the effect of individual wetland impacts within the context of the cumulative impacts contributed to the watershed from other geomorphic areas and land uses.It is difficult to evaluate the potential cumulative impacts on wetland hydrology because geologic settings of wetlands are often complex and the methods used to measure wetland streamflow, groundwater flow, and evapotranspiration are inexact (Winter 1988). This is especially so for bogs, fens, and mires underlain by thick organic soils. These wetlands, found in the circumboreal areas of North America, Europe, and Asia, are major physiographic features in eastern North America, northern Europe, and Siberia (Kivenen and Pakarinen 1981, Gore 1983, Glaser and Janssens 1986). Their very scale makes it difficult to quantify the hydrologic function accurately. The hydrology of small bogs and fens found elsewhere is just as poorly understood because of conflicting conceptual models of pertinent hydrologic processes.This article (1) reviews our current understanding of the hydrologic function of bogs, fens, and mires at different scales and in different physiographic settings and (2) presents hypotheses on potential cumulative impacts on the hydrologic function that might occur with multiple disturbances.     

SIMULATION OF REGIONAL GROUND WATER FLOW IN BEDROCK,SOUTHWESTERN NEW YORK-NORTHWESTERN PENNSYLVANIA1

ABSTRACT: This paper presents the results of steady-state three-dimensional computer simulations to determine the hydrogeologic setting of formation water in the hydrocarbon producing formations of southwestern New York and northwestern Pennsylvania. Recharge areas for the regional ground water flow systems in the study area are the Valley Heads Moraine and Allegheny uplands; discharge areas are Lakes Erie and Ontario to the north and the northern margin of the Appalachian basin to the south. Simulated ground water flow in all model layers moves north from the ground water divide on the Valley Heads Moraine towards Lake Erie at a rate from 10^?-⁶ to 10^?-³ ft/day. South of the divide intermediate-scale and local-scale flow systems occur in the upper 4000 feet of the stratigraphic section and the directions of ground water flow diverge towards major rivers and other topographically low areas.