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61.
62.
Silvana Povolo Maria Giovanna Romanelli Federico Fontana Marina Basaglia Sergio Casella 《Journal of Polymers and the Environment》2012,20(4):944-949
The production of polyesters from triglyceride containing substrates was investigated. A first filter step based on lipase activity was followed and those bacteria potentially able to degrade oils or animal fats were further tested for their polymer accumulation properties, selected and kept for further studies. In a second step, bacteria were directly grown on animal fats and/or vegetable oils, and polyhydroxyalkanoates (PHAs) accumulation was verified under appropriate incubation conditions. Each substrate, whether of animal or vegetable derivation, supported the growth of a number of the newly isolated strains and among those, some strains were also found to produce reasonably high amounts of PHA. The repeat-unit composition of the polyesters was determined by gas chromatography (GC) analysis of the ?-hydroxyalkanoate methyl esters from the hydrolyzed polymer and some class of co-polymers were also detected. These properties, coupled with the ability of some of the selected isolates to grow and produce lipases on a minimal medium, could be considered as promising in view of possible industrial applications. The overall results indicate that PHAs could be produced from waste containing considerable amounts of fat, oil and grease (FOG), that generally need to be treated for their disposal. 相似文献
63.
Griselda V. Garaffo Silvana L. Dans Susana N. Pedraza Enrique A. Crespo Mariana Degrati 《Marine Biology》2007,152(1):165-177
Off Patagonian coasts, Argentina, the dusky dolphin is one of the most common small cetaceans. This species is the aim of
newly developed watching activities during summer in Golfo Nuevo. However, the real occurrence and movement pattern are unknown.
The objectives of this work were to investigate the predictability of dusky dolphin distribution, group structure and behaviour
in the western portion of Golfo Nuevo, with respect to environmental features (bottom depth, bottom slope, distance from shore
and substrate). Random transects in the bay were searched by small boat during the summer and autumn of 2001–2004. When a
group of dolphins was sighted, estimates of group size, composition (mothers with calves, adults and juveniles only, and mixed
groups) and the predominant activity (feeding, travelling, socialising, resting and milling) were recorded and thereafter at 2 min intervals. A grid of 1.5 × 1.5 km was constructed and each cell was characterised
by environmental features, Area Use Index (percent of total annual search effort) and Activity Index (predominant behaviour
of groups observed in that cell). Mothers with calves and smaller groups and resting behaviour occurred in shallowest waters supporting the idea/hypothesis that movement to shallower water is related to increased
safety for individuals. Travelling occurred in the deepest areas with other behaviours observed in intermediate depths. Dolphin distribution within the bay
differed significantly between years, but this was not related to any of the factors analysed in this study. Although there
was considerable variation between years, in general, dolphins were found in deeper waters further from shore (except for
mother–calf groups) and over areas with steeper seafloor gradient. The high variability in the distribution of the animals
does not allow for the generation of a simple, area-specific management plan. 相似文献
64.
In this work, the treatment of landfill leachates by a photoelectrochemical procedure is reported. When applied to untreated leachates the photochemical system was significantly hindered on account of the characteristic dark coloration of the samples. At this condition the degradation process was essentially electrochemical permitting typical color and COD removal of about 50% and 20%, respectively. When a previous chemical precipitation process was applied aiming the elimination of colored species (mainly humic substances) the decolorization and COD removal was extended to 90% and 60%, respectively. Considering the extremely complex character of the leachates and its usual resistance to conventional degradation processes the result reported here attest the high potentiality of photoelectrochemical processes to remediation of recalcitrant residues. 相似文献
65.
Flox C Cabot PL Centellas F Garrido JA Rodríguez RM Arias C Brillas E 《Chemosphere》2006,64(6):892-902
The anodic oxidation of 1.8l of solutions with mecoprop (2-(4-chloro-2-methylphenoxy)-propionic acid or MCPP) up to 0.64 g l(-1) in Na2SO4 as background electrolyte within the pH range 2.0-12.0 has been studied using a flow plant containing a one-compartment filter-press electrolytic reactor with a boron-doped diamond (BDD) anode and a stainless steel cathode, both of 20-cm2 area. Electrolyses carried out in batch under steady conditions and operating at constant current density between 50 and 150 mA cm(-2) always yield complete mineralization due to the great concentration of hydroxyl radical generated at the BDD anode. The degradation rate is practically independent of pH and Na2SO4 concentration, but it becomes faster with increasing MCPP concentration, current density, temperature and liquid flow rate. The effect of these parameters on current efficiency and energy cost has also been investigated. Generated weak oxidants such as H2O2 and peroxodisulfate ion have little influence on the mineralization process. The kinetics for the herbicide decay follows a pseudo first-order reaction with a higher rate constant when current density increases. Aromatic products such as 4-chloro-o-cresol, 2-methylhydroquinone and 2-methyl-p-benzoquinone, and generated carboxylic acids such as maleic, fumaric, lactic, pyruvic, tartronic, acetic and oxalic, have been identified as intermediates by chromatographic techniques. The initial chlorine is completely released in the form of chloride ion, which is slowly oxidized to Cl2 at the BDD anode. A reaction pathway for MCPP mineralization involving all products detected is proposed. 相似文献
66.
Nabil Ben Omar Manuel Entrena MaTeresa González‐Muñoz José Maria Arias Francisco Huertas Manuel Rodriguez‐Gallego 《毒物与环境化学》2013,95(1-4):209-217
We studied the morphological diversity of struvite crystals produced by Myxococcus coralloides and Myxococcus xanthus in different culture conditions. We discussed the similarities of these crystals with the struvite morphology studied previously following the theory of the periodic bond chains. 相似文献
67.
68.
Evaluation of aquatic plants for removing polar microcontaminants: a microcosm experiment 总被引:2,自引:0,他引:2
Microcosm wetland systems (5 L containers) planted with Salvinia molesta, Lemna minor, Ceratophyllum demersum, and Elodea canadensis were investigated for the removal of diclofenac, triclosan, naproxen, ibuprofen, caffeine, clofibric acid and MCPA. After 38 days of incubation, 40-99% of triclosan, diclofenac, and naproxen were removed from the planted and unplanted reactors. In covered control reactors no removal was observed. Caffeine and ibuprofen were removed from 40% to 80% in planted reactors whereas removals in control reactors were much lower (2-30%). Removal of clofibric acid and MCPA were negligible in both planted and unplanted reactors. The findings suggested that triclosan, diclofenac, and naproxen were removed predominantly by photodegradation, whereas caffeine and naproxen were removed by biodegradation and/or plant uptake. Pseudo-first-order removal rate constants estimated from nonlinear regressions of time series concentration data were used to describe the contaminant removals. Removal rate constants ranged from 0.003 to 0.299 d(-1), with half-lives from 2 to 248 days. The formation of two major degradation products from ibuprofen, carboxy-ibuprofen and hydroxy-ibuprofen, and a photodegradation product from diclofenac, 1-(8-Chlorocarbazolyl)acetic acid, were followed as a function of time. This study emphasizes that plants contribute to the elimination capacity of microcontaminants in wetlands systems through biodegradation and uptake processes. 相似文献
69.
Wium-Andersen T Nielsen AH Hvitved-Jacobsen T Kristensen NK Brix H Arias C Vollertsen J 《Water environment research》2012,84(7):605-616
Five sorption materials were studied with a focus on polishing pretreated stormwater: crushed limestone, shell-sand, zeolite, and two granulates of olivine. These materials are commercially available at comparatively low cost and have been subjected to a minimum of modification from their natural states. The sorbents were tested for phosphorus, arsenic, cadmium, chromium, copper, nickel, lead, and zinc at concentration and conditions relevant for typical stormwater. The materials were tested for sorption capacity and kinetics. Desorption was tested under neutral and alkaline conditions and in the presence of chloride. For most sorbent/sorbate combinations, significant sorption occurred within the first minutes of contact between sorbent and sorbate. Treatment to the low microgram per liter range could be achieved by contact times of less than 1 hour. The study indicated that sorption filters can be designed for long life expectancy at comparatively low cost by applying the materials tested. 相似文献
70.