Baseline mercury and zinc concentrations in terrestrial and coastal organisms of Admiralty Bay, Antarctica

This paper provides the first quantitative information on mercury in soil, coastal sediment, and in characteristic organisms of terrestrial and shallow coastal marine ecosystems from Admiralty Bay (King George Island, Antarctica). As expected for a remote area, mercury content is low in abiotic components of the ecosystem, and probably similar to natural levels. Mercury also occurs in very low concentrations in the vegetation, invertebrates and fish. These low mercury levels may be due to sulphide formation in reducing sediments of this environment. Higher concentrations of mercury occurred in bird feathers and mammal hair, indicating biomagnification. This was not found for Zinc. These results may be useful as a reference background to detect future inputs of trace elements in this remote area of the earth. Terrestrial vegetation and bird feathers are suggested as target regional biomonitors.     

Investigation of the ultraviolet photolysis method for the determination of organic nitrogen in aerosol samples

The research objective was to adapt the ultraviolet (UV)-photolysis method to determine dissolved organic nitrogen (DON) in aqueous extracts of aerosol samples. DON was assumed to be the difference in total concentration of inorganic nitrogen forms before and after sample irradiation. Using a 2(2) factorial design the authors found that the optimal conversion of urea, amino acids (alanine, aspartic acid, glycine, and serine), and methylamine for a reactor temperature of 44 degrees C occurred at pH 2.0 with a 24-hr irradiance period at concentrations <33 microM of organic nitrogen. Different decomposition mechanisms were evident: the photolysis of amino acids and methylamine released mainly ammonium (NH4+), but urea released a near equimolar ratio of NH4+ and nitrate (NO3-). The method was applied to measure DON in the extracts of aerosol samples from Tampa, FL, over a 32-day sampling period. Average dissolved inorganic (DIN) and DON concentrations in the particulate matter fraction PM10 were 78.1 +/- 29.2 nmol-Nm(-3) and 8.3 +/- 4.9 nmol-Nm(-3), respectively. The ratio between DON and total dissolved nitrogen ([TDN] = DIN + DON) was 10.1 +/- 5.7%, and the majority of the DON (79.1 +/- 18.2%) was found in the fine particulate matter (PM2.5) fraction. The average concentrations of DIN and DON in the PM2.5 fraction were 54.4 +/- 25.6 nmol-Nm(-3) and 6.5 +/- 4.4 nmol-Nm(-3), respectively.     

Rockfall Hazard and Risk Assessment Along a Transportation Corridor in the Nera Valley,Central Italy

Rockfalls are a common type of fast-moving slope failures, and in many countries they represent the primary cause of landslide fatalities. We present a methodology to ascertain rockfall hazard and to determine the associated risk along transportation networks. The proposed methodology is based on the combined analysis of the recurrence of rockfall events, determined from historical information, the frequency-volume statistics of rockfalls, obtained from inventories of recent rockfall triggering events, and the results of a physically based, spatially distributed rockfall simulation model used to determine rockfall hazard. The available information on rockfall hazard is combined in a Geographic Information System with a map of the transportation network to identify the road sections potentially subject to rockfalls. Information on the location and type of rockfall defensive measures, including revetment nets, elastic fences, concrete walls, and artificial tunnels, is used to estimate the efficacy of the defensive structures and to determine the level of the residual rockfall risk along the roads. To illustrate the methodology, we discuss an application in a 48-km² area in the Nera River valley, in the Umbria Region of central Italy, where rockfalls are abundant, and where considerable investments were recently made to mitigate rockfall risk. Note: This version was published online in June 2005 with the cover date of August 2004.     

EFFECT OF WATERSHED SUBDIVISION ON SWAT FLOW,SEDIMENT, AND NUTRIENT PREDICTIONS1

ABSTRACT: The size, scale, and number of subwatersheds can affect a watershed modeling process and subsequent results. The objective of this study was to determine the appropriate level of subwatershed division for simulating flow, sediment, and nutrients over 30 years for four Iowa watersheds ranging in size from 2,000 to 18,000 km² with the Soil and Water Assessment Tool (SWAT) model. The results of the analysis indicated that variation in the total number of subwatersheds had very little effect on streamflow. However, the opposite result was found for sediment, nitrate, and inorganic P; the optimal threshold subwatershed sizes, relative to the total drainage area for each watershed, required to adequately predict these three indicators were found to be around 3, 2, and 5 percent, respectively. Decreasing the size of the subwatersheds below these threshold levels does not significantly affect the predicted levels of these environmental indicators. These threshold subwatershed sizes can be used to optimize input data preparation requirements for SWAT analyses of other watersheds, especially those within a similar size range. The fact that different thresholds emerged for the different indicators also indicates the need for SWAT users to assess which indicators should have the highest priority in their analyses.     

Relationship between neuropsychological tests and driver's license renewal tests in Parkinson's disease

Objective: To determine whether the standard Spanish driving test (ASDE test) was able to identify patients with Parkinson's disease (PD) at risk of unsafe driving and to examine the relationship between the ASDE test and the Useful Field of View (UFOV) as well as with a battery of neuropsychological tests in drivers with PD.

Methods: Thirty-seven patients with PD and 33 controls matched by age and education level were included in an observational study. All participants were active drivers and patients with PD underwent study procedures after taking the medication in the “on” period. Subjects with a Mini-Mental State Examination (MMSE) score ≤ 24 were excluded. Neuropsychological tests (Repeatable Battery for Neuropsychological Status [RBANS], Trail Making Test [TMT-A and -B], and Block Design test), driving performance tests (ASDE Driver Test and UFOV), and daytime sleepiness (Epworth Sleepiness Scale) were assessed.

Results: The PD group performed significantly worse than healthy controls in the ASDE Motor Coordination tests. No significant differences were observed in anticipation speed, multiple reaction time, concentrated attention, and resistance to monotony. All participants successfully completed the UFOV tests. Statistically significant differences between patients with PD and controls were found in processing speed (UFOV1; P =.03) and more patients with PD were found in the categories of higher driving risk levels (P =.03). In addition, patients with PD showed worse scores than healthy controls in visuospatial capacities (Line Orientation), psychomotor speed (Coding and TMT-A), memory (List Recognition, Story Recall), and executive function (TMT-B). The driving tests (ASDE and UFOV) showed a low sensitivity and a high specificity but a higher percentage of patients in the PD group failed in multiple reaction time, concentrated attention, and resistance to monotony. In addition, 18.9% of patients with PD showed a cutoff of 4 for UFOV risk. In the discriminant analysis, Line Orientation (visuospatial/constructive domain) and Figure Recall (delayed memory) were found to be statistically significant with a rate of correct classification of unsafe drivers with PD of 78.2%. In addition, normal results on the Line Orientation item were associated with a 1.5 times higher probability of non-risky driving in the multivariate analysis.

Conclusions: At early stages of the disease, about 19% of patients with PD showed difficulties that may affect their driving capabilities. Line Orientation and Figure Recall are useful to alert clinicians to the risk of unsafe driving. For this reason, patients with PD should be evaluated for driving abilities more regularly to determine the extent of deficits that may influence driving performance.     

Greenhouse gases emissions from a closed old landfill cultivated with biomass crops

Closed landfills need after-closure rehabilitation. The chosen option should ensure greenhouse gases release, from the landfill, is not promoted once settled. The objective of this study was to estimate and confront, during different seasons, CH₄, CO₂ and N₂O emissions under three vegetation covers in a closed landfill in Buenos Aires, Argentina. CH₄ (methane), CO₂ (carbon dioxide) and N₂O (nitrous oxide) emissions from landfill’s technosol under spontaneous vegetation (control), Pennisetum purpureum and Miscanthus giganteus (biomass crops), were quantified with non-steady-state non-flow-through chambers, in July 2014 and from February to July 2015. A linear regression analysis was performed to relate the variables “flux of a gas” and “concentration of that gas” from the 3 treatments and 6 dates, separating the 5 sampling times. A high correlation between concentrations and fluxes of CO₂ and N₂O was found, but no correlation was established for CH₄. Mean emissions (2014–2015) varied from: ?2.3 to 639.41 mgCH₄ m^?2 day^?1, 3884 to 46,365 mgCO₂ m^?2 day^?1 and 0.40 to 14.59 mgN₂O m^?2 day^?1. Vegetation covers had no significant effect on CH₄ and N₂O concentration in time, but they had on CO₂ concentration. Season of the year had a significant effect on concentration of the three gases. This is the first study on CH₄, CO₂ and N₂O emissions from a landfill closed 27 years ago covered with biomass crops.     

Are children playgrounds safe play areas? Inorganic analysis and lead isotope ratios for contamination assessment in recreational (Brazilian) parks

Environmental Science and Pollution Research - In city playgrounds, there is a potential risk of harming children’s health by contamination coming from anthropogenic activities. With the aim...     

Photocatalytic soot degradation under UV and visible light

Environmental Science and Pollution Research - Particulate matter is one of the most persistent global air pollutants that is causing health problems, climate disturbance and building...