Diquat associated with copper sources for algae control: Efficacy and ecotoxicology

The aims of this research were to evaluate the efficacy of copper oxychloride (CuCl₂.3Cu(OH)₂), copper hydroxide (Cu(OH)₂) and diquat (1.1′-ethylene-2.2′-bipyridyldiylium dibromide), isolated and in association with 0.1% of both copper sources, in the control of the unicellular algae Ankistrodesmus gracilis and the filamentous algae Pithophora kewesis, and to determine the acute toxicity of the tested chemicals in Hyphressobrycon eques, Pomacea canaliculata, Lemna minor and Azolla caroliniana. The efficacy was estimated by the methods of chlorophyll a and pheophytin a readings, changed into growth inhibition percentage. Both algae were exposed to the following concentrations: 0.2; 0.4; 0.8; 1.2 mg L^?1 of diquat and its association with the copper sources; and 0.1; 0.3; 0.5; 0.7; 1.0 and 1.5 mg L^?1 in the isolated applications of copper hydroxide and copper oxychloride. An untreated control was kept. The acute toxicity was estimatedby 50% lethal concentration (LC50). The copper sources were effective for A. gracilis control, at rates as high as 0.1 mg L^?1 (>95% efficacy). Isolated diquat and its association with copper hydroxide were both effective at rates as high as 0.4 mg L^?1, with 95 and 88% control efficacy, respectively. The copper oxychloride was effective at 0.2 mg L^?1, with 93% efficacy. None of the tested chemicals and associations was effective on P. kewesis control. The most sensitive non target organism to the tested chemicals was L. minor; the less sensitive was H. eques.     

Carbon mineralization,microbial activity and metal dynamics in tailing ponds amended with pig slurry and marble waste

A field experiment was set up in Cartagena-La Unión Mining District, SE Spain, aimed at evaluating the short-term effects of pig slurry (PS) amendment alone and together with marble waste (MW) on organic matter mineralization, microbial activity and stabilization of heavy metals in two tailing ponds. These structures pose environmental risk owing to high metals contents, low organic matter and nutrients, and null vegetation. Carbon mineralization, exchangeable metals and microbiological properties were monitored during 67 d. The application of amendments led to a rapid decrease of exchangeable metals concentrations, except for Cu, with decreases up to 98%, 75% and 97% for Cd, Pb and Zn, respectively. The combined addition of MW + PS was the treatment with greater reduction in metals concentrations. The addition of PS caused a significant increase in respiration rates, although in MW + PS plots respiration was lower than in PS plots. The mineralized C from the pig slurry was low, approximately 25–30% and 4–12% for PS and MW + PS treatments, respectively. Soluble carbon (Csol), microbial biomass carbon (MBC) and β-galactosidase and β-glucosidase activities increased after the application of the organic amendment. However, after 3 d these parameters started a decreasing trend reaching similar values than control from approximately day 25 for Csol and MBC. The PS treatment promoted highest values in enzyme activities, which remained high upon time. Arylesterase activity increased in the MW + PS treatment. Thus, the remediation techniques used improved soil microbiological status and reduced metal availability. The combined application of PS + MW reduced the degradability of the organic compounds.     

Food contamination control in European new Member States and associated candidate countries: Data collected within the SAFEFOODNET project

This paper reports the results obtained from the data collected within the European Commission funded project SAFEFOODNET regarding the state of the art in the control of chemical food contaminants in twelve European New Member States and one Associated Candidate Country (Turkey). Information has been gathered on institutions involved in food chemical contamination control, types of contaminants and matrices analyzed, procedures for data quality assurance, purposes of the analyses and accessibility of data in the participant countries. The resulting picture points out the general availability of adequate capabilities for the analysis of food contaminants in the laboratories in charge of control and the performance of the analysis of a large variety of chemicals (persistent organic pollutants, polycyclic aromatic hydrocarbons, pesticides, mycotoxins, heavy metals, radionuclides) in almost each country with few exceptions (dioxins in Bulgaria, Turkey, Latvia, persistent organic pollutants in Lithuania and Malta, polycyclic aromatic hydrocarbons in Malta). The application of validated analytical methods and the process of laboratory accreditation are partially fulfilled within the investigated countries, but still forthcoming for some countries, as in Romania, Turkey and Malta. Information collected on food controls is only partially available online and the language used is prevalently local and English to a lesser extent.     

Directions of Change in Land Cover and Landscape Patterns from 1957 to 2000 in Agricultural Landscapes in NW Spain

The aim of this work is the analysis of the dynamics in cultural landscapes, focused on the spatial distribution of changes in land cover and landscape patterns, and their possible linkages. These dynamics have been analyzed for the years 1957 and 2000 in a sector of the north of Galicia (NW Spain) characterized with diverse landscapes. Afforestation processes linked to agriculture abandonment and forestry specialization were the main processes observed in the study area, with the exception of the southern mountainous sector that was dominated by ploughing of scrubland for conversion into grassland, reflecting a specialization in livestock production. The structural changes that have taken place in most of the study area were related to the heterogeneity aspects, although the mountainous sectors were characterized by changes in heterogeneity and fragmentation. According to the tests performed, the comparison of the spatial distribution of both dynamics showed a certain statistical significance, reflecting the interrelationship between patterns and processes. This approach could be useful for the identification of areas with similar characteristics in terms of spatial dynamics so as to define more effective and targeted landscape planning and management strategies.     

Analysing demand for environmental quality: a willingness to pay/accept study in the province of Siena (Italy)

The province of Siena, Italy, enacted a new garbage plan (NGP) with the objective of increasing separate waste collection (SWC), shutting down six landfills and increasing incineration. The aim of the paper is to evaluate costs and benefits of the NGP. The hypothesis is that willingness to pay (WTP) should reflect the value to the community of having better environmental quality, according to the Contingent Valuation literature. The paper reports the results of a contingent valuation (CV). The sample was divided into two subsets: firms and households. Through the information gathered via a detailed questionnaire, parametric and non-parametric estimates were elaborated to analyse the WTP of the population for the benefits flowing from increased SWC, increased incineration and shutting down of landfills. These values were expressed as a share of the tax actually paid. Although a small subset of firms and households valued increasing incineration less positively, requesting compensation, on the whole interviewees (with large differences between firms and households) had a net positive WTP for the provisions included in NGP. Parametric estimation procedures enabled us to analyse the economic as well as social and demographic factors affecting these results. These elements are useful for computing a value for the waste charge that also reflects external effects. Finally, we estimated household income elasticity of WTP for the increase in SWC and found less than one: environmental quality is not a luxury good.     

Design and performance evaluation of a photocatalytic reactor for indoor air disinfection

Environmental Science and Pollution Research - Since COVID-19 pandemic, indoor air quality control has become a priority, and the development of air purification devices effective for disinfecting...     

Toxicity evaluation of vinasse and biosolid samples in diplopod midgut: heat shock protein in situ localization

Environmental Science and Pollution Research - Large amounts of residues generated by agricultural, urban and industrial activities are dumped daily on the soil. This practice deserves special...     

Urban regeneration and democratization of information access: CitiStat experience in Baltimore

This article explores the potential of a GIS-based approach to city management - Baltimore's CitiStat e-government program - for meeting the goals of sustainable urban regeneration. The argument advocated here builds on the widely held recognition that the application of ICTs in general can lead to both new forms of inclusion and exclusion of citizens. Therefore attending to the 'digital divide' is a relevant issue because cities are complex environments where outcomes of interventions are uncertain and widening participative arenas to different actors can increase the possibilities to regenerate declining urban areas in a more democratic way.     

Work ability of workers in different age groups in a public health institution in Brazil.

OBJECTIVES: The aim of this study was to determine the associations between demographics, work, lifestyle, housework, and the work ability of workers. METHODS: Employees between the ages of 20 and 69 (N = 651), employed at a Brazilian public institution, responded to a questionnaire on demographics, work, lifestyle characteristics, and work ability. RESULTS: Work ability decreased significantly with age among the women. The younger group had higher scores on the work ability index than the older age groups, except for mental resources. The logistic regression analysis showed that higher age, lower education, and long work history at the institution were significantly associated with reduced work ability. CONCLUSIONS: The progressive aging, the low level of education, and the long duration work in the studied institution were related to a reduction in work ability, which increases the risk of work disability or early retirement.     

Under-Reporting of Accidents Involving Biological Material by Nursing Professionals at a Brazilian Emergency Hospital

Background. Pathogens can be transmitted to health professionals after contact with biological material. The exact number of infections deriving from these events is still unknown, due to the lack of systematic surveillance data and under-reporting. Methods. A cross-sectional study was carried out, involving 451 nursing professionals from a Brazilian tertiary emergency hospital between April and July 2009. Through an active search, cases of under-reporting of occupational accidents with biological material by the nursing team were identified by means of individual interviews. The Institutional Review Board approved the research project. Results. Over half of the professionals (237) had been victims of one or more accidents (425 in total) involving biological material, and 23.76% of the accidents had not been officially reported using an occupational accident report. Among the under-reported accidents, 53.47% were percutaneous and 67.33% were bloodborne. The main reason for nonreporting was that the accident had been considered low risk. Conclusions. The under-reporting rate (23.76%) was low in comparison with other studies, but most cases of exposure were high risk.