全文获取类型
收费全文 | 9647篇 |
免费 | 0篇 |
专业分类
安全科学 | 10篇 |
废物处理 | 765篇 |
环保管理 | 1208篇 |
综合类 | 933篇 |
基础理论 | 3105篇 |
污染及防治 | 1728篇 |
评价与监测 | 1004篇 |
社会与环境 | 894篇 |
出版年
2019年 | 2篇 |
2018年 | 1474篇 |
2017年 | 1371篇 |
2016年 | 1194篇 |
2015年 | 123篇 |
2014年 | 13篇 |
2013年 | 9篇 |
2012年 | 459篇 |
2011年 | 1337篇 |
2010年 | 689篇 |
2009年 | 599篇 |
2008年 | 877篇 |
2007年 | 1231篇 |
2006年 | 1篇 |
2005年 | 19篇 |
2004年 | 33篇 |
2003年 | 61篇 |
2002年 | 97篇 |
2001年 | 15篇 |
2000年 | 10篇 |
1999年 | 2篇 |
1998年 | 9篇 |
1997年 | 1篇 |
1984年 | 11篇 |
1983年 | 8篇 |
1935年 | 2篇 |
排序方式: 共有9647条查询结果,搜索用时 15 毫秒
971.
The dynamic and residues of florasulam and flumetsulam in corn field ecosystem were investigated using quick, easy, cheap, effective, rugged, and safe (QuEChERS) procedure with high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). The limits of quantification (LOQs) of the proposed method ranged from 0.005 to 0.01 mg/kg. Mean recoveries and relative standard deviations (RSDs) of the two compounds in all samples at three spiking levels ranged 94–110 % and 2.0–9.2 %, respectively. Florasulam and flumetsulam degradation followed first-order kinetics with half-lives 1.7–2.9 and 3.3–8.7 days in soil and 1.3–1.8 and 0.9–1.7 days in plant, respectively. The residues in all the samples were found to be less than the LOQs at preharvest intervals of 53 and 78 days. The results suggest that the combined use of florasulam and flumetsulam on corn is considered to be safe under the recommended conditions and can be utilized for establishing the maximum residue limit (MRL) of florasulam in corn in China. 相似文献
972.
Maria P. Papadopoulou Emmanouil A. Varouchakis George P. Karatzas 《Environmental Modeling and Assessment》2010,15(5):319-328
Karst aquifers are characterized by spatial heterogeneity due to the presence of highly permeable channels and conduits in
low-permeable fractured rocks (matrix block). Recent studies have reported a close relationship between surface and subsurface
water in karstic regions due to the water flow through a complicated network of paths formed by fracture intersections. Subsurface
flow in karstified aquifers ranges between conduit flow, in large passages with relatively high flow velocities, and diffuse
flow, in the matrix block where Darcy’s law is still valid. In this paper, we present the simulation of a complex karstified
aquifer system in Crete, Greece, where the presence of main faults drastically affects the regional flow. A discrete fracture
approach in conjunction with an equivalent porous medium approach was adopted to simulate the mixed flow in the area of interest.
The simulation results have shown that the length and the orientation of the dominant faults, primarily during the rainy season,
affect the flow field. 相似文献
973.
Michael G. Hutchins Amelie Deflandre-Vlandas Paulette E. Posen Helen N. Davies Colin Neal 《Environmental Modeling and Assessment》2010,15(2):93-109
A combined semi-distributed hydrological model (CASCADE/QUESTOR) is used to evaluate the steady-state that may be achieved
after changes in land-use or management and to explore what additional factors need to be considered in representing catchment
processes. Two rural headwater catchments of the River Derwent (North Yorkshire, UK) were studied where significant change
in land-use occurred in the 1990s and the early 2000s. Much larger increases in mean nitrate concentration (55%) were observed
in the catchment with significant groundwater influence (Pickering Beck) compared with the surface water-dominated catchment
(13% increase). The increases in Pickering Beck were considerably greater than could be explained by the model in terms of
land-use change. Consequently, the study serves to focus attention on the long-term increases in nitrate concentration reported
in major UK aquifers and the ongoing and chronic impact this trend is likely to be having on surface water concentrations.
For river environments, where groundwater is a source, such trends will mask the impact of measures proposed to reduce the
risk of nitrate leaching from agricultural land. Model estimates of within-channel losses account for 15–40% of nitrate entering
rivers. 相似文献
974.
Ans M. Mouton Andy P. Dedecker Sovan Lek Peter L. M. Goethals 《Environmental Modeling and Assessment》2010,15(1):65-79
This study aimed to compare different methods to analyse the contribution of individual river characteristics to predict the
abundance of Asellus (Crustacea, Isopoda). Six methods which provide the relative contribution and/or the contribution profile of the input variables
of artificial neural network models were therefore compared: (1) the ‘partial derivatives’ method; (2) the ‘weights’ method;
(3) the ‘perturb’ method; (4) the ‘profile’ method; (5) the ‘classical stepwise’ method; (6) the ‘improved stepwise’ method.
Consequently, the key variables which affect the habitat preferences of Asellus could be identified. To evaluate the performance of the artificial neural network model, the model predictions were compared
with the results of a multiple linear regression analysis. The dataset consisted of 179 samples, collected over a 3-year period
in the Zwalm catchment in Flanders, Belgium. Twenty-four environmental variables as well as the log-transformed abundance
of Asellus were used in this study. The different contribution methods seemed to give similar results concerning the order of importance
of the input variables. Nevertheless, their diverse computation led to differences in sensitivity and stability of the methods
and the derived outcomes on the habitat preferences. From an ecological point of view, the environmental variables describing
the stream type (width, depth, stream order and distance to mouth) were the most significant variables for Asellus in the Zwalm catchment during the period 2000–2002 for all applied methods. Indirectly, one can conclude that the water quality
is not the limiting factor for the survival of Asellus in the Zwalm catchment. 相似文献
975.
A Spatially Explicit Model for Estimating Annual Average Loads of Nonpoint Source Nutrient at the Watershed Scale 总被引:1,自引:0,他引:1
Tao Zhang 《Environmental Modeling and Assessment》2010,15(6):569-581
The overloaded nonpoint source (NPS) nutrients in upper streams always result in the nutrient enrichment at lakes and estuaries
downstream. As NPS pollution has become a serious environmental concern in watershed management, the information about nutrient
output distribution across a watershed has been critical in the designing of regional development policies. But existing watershed
evaluation models often encounter difficulties in application because of their complicated structures and strict requirements
for the input data. In this paper, a spatially explicit and process-based model, Integrated Grid’s Exporting and Delivery
model, was introduced to estimate annual in-stream nutrient levels. Each grid cell in this model was regarded as having potentials
of both exporting new nutrients and trapping nutrients passing by. The combined nutrient dynamics of a grid is mainly determined
by the grid’s features in land use/land cover, soil drainage, and geomorphology. This simple-concept model was tested at some
basins in north Georgia in the USA. Stations in one basin were used to calibrate the model. Then an external validation was
employed by applying the calibrated model to stations in the other neighbor basins. Model evaluation statistics implied the
model’s validity and good performance in estimating the annual NPS nutrients’ fluxes at the watershed scale. This study also
provides a promising prospect that in-stream annual nutrient loads can be accurately estimated from a few public available
datasets. 相似文献
976.
A framework for dissolved oxygen (DO) modeling of the Ravi River has been developed based on a combination of laboratory measurements
and field and monitoring data. Both the classical Streeter-Phelps (CSP) and the modified Streeter-Phelps (MSP) models are
used for DO simulations. The MSP model considers the carbonaceous biochemical oxygen demand (CBOD) and nitrogenous biochemical
oxygen demand (NBOD) separately, whereas the CSP model is evaluated considering only the CBOD and NBOD is incorporated in
the overall BOD utilization rate. CBOD, NBOD and BOD rates have been determined through long-term BOD analysis of five main
wastewater outfalls and two surface drains discharging into the Ravi River over a 98 km stretch. Analysis by Thomas Method
manifests strong coefficient of determination “R2” between 0.72 and 0.98 for all the three types of BOD rates. Sensitivity analyses have also been carried out to find out
a suitable reaeration rate formula for highly variable flows in the Ravi River. The CSP model results based on classical approach
of considering only CBOD show significant difference between the model predictions and field measurements suggesting that
NBOD needs to be incorporated for the model development. The dissolved oxygen values calculated using the MSP model and the
CSP model based on overall BOD rate are in close agreement with field measurements and are thus suitable to model DO levels
in the Ravi River. 相似文献
977.
Marian Leimbach Nico Bauer Lavinia Baumstark Ottmar Edenhofer 《Environmental Modeling and Assessment》2010,15(3):155-173
Within this paper, we present the novel hybrid model REMIND-R and its application in a climate policy context based on the
EU target to avoid a warming of the Earth’s atmosphere by more than 2°C compared to the pre-industrial level. This paper aims
to identify necessary long-term changes in the energy system and the magnitude of costs to attain such a climate protection
target under different designs of the post-2012 climate policy regime. The regional specification of mitigation costs is analyzed
in the context of globalization where regions are linked by global markets for emission permits, goods, and several resources.
From simulation experiments with REMIND-R, it turns out that quite different strategies of restructuring the energy system
are pursued by the regions. Furthermore, it is demonstrated that the variance of mitigation costs is higher across regions
than across policy regimes. First-order impacts, in particular, reduced rents from trade in fossil resources, prevail regardless
of the design of the policy regime. 相似文献
978.
When agricultural lands are no longer used for agriculture and allowed to recover its natural vegetation, soil organic carbon
can accumulate in the soil. Measurements of soil organic carbon and aggregate stability changes under various forms of land
use are needed for the development of sustainable systems. Therefore, comparison of soil samples taken from both agricultural
and nearby area close to land-mined fields where no agricultural practices have been done since 1956 can be a good approach
to evaluate the effects of tillage and agriculture on soil quality. The objective of this study was to compare tillage, cropping
and no tillage effects on some soil-quality parameters. Four different locations along the Turkey–Syria border were selected
to determine effects of tillage and cropping on soil quality. Each location was evaluated separately because of different
soil type and treatments. Comparisons were made between non-tilled and non-cropped fallow since 1956 and adjacent restricted
lands that were tilled about every 2 years but not planted (T) or adjacent lands tilled and planted with wheat and lentil
(P). Three samples were taken from the depths of 0–20 and 20–40 cm each site. Soil organic carbon (SOC), pH ,electrical conductivity,
water soluble Ca++, Mg++, CO3-2{\rm CO}_{3}^{-2} and HCO3-{\rm HCO}_{3}^{-}, extractable potassium (K+) and sodium (Na+), soil texture, ammonium (NH4+{\rm NH}_{4}^{+}–N) and nitrate (NO3–N), extractable phosphorous and soil aggregate stability were determined. While the SOC contents of continuous tillage without
cropping and continuous tillage and cropping were 2.2 and 11.6 g kg−1, respectively, it was 30 g kg−1 in non-tilled and non-planted site. Tillage of soil without the input of any plant material resulted in loss of carbon from
the soil in all sites. Soil extractable NO3−N contents of non-tilled and non-cropped sites were greatest among all treatments. Agricultural practices increased phosphorus
and potassium contents in the soil profile. P2O5 contents of planted soils were approximately 20 to 39 times greater than those of non-tilled and non-cropped soils at different
sites. FTIR spectra showed that never tilled sites had greater phenol, carboxylic acid, amide, aromatic compounds, polysaccharide
and carbohydrates than other treatments. 相似文献
979.
Monavari SM Omrani GA Karbassi A Raof FF 《Environmental monitoring and assessment》2012,184(4):1841-1846
Environment problems associated with the generation of waste are part of societal changes where households play an important
role. These societal changes influence the size, structure and characteristic of given households. For the effective planning
of solid-waste handling infrastructure, it is essential to know the quantity of waste generation and its composition. This
paper presents the findings of a study carried out in an urban municipal area in Iran to determine the household solid-waste
generation rate and waste composition based on field surveys and to determine the related socioeconomic parameters. The dependent
variables were waste generation and composition, and independent variables were family size, family employment, age, number
of room and education. Over 400 sample households were selected for the study using a stratified random sampling methodology
and from five different socioeconomic groups. Waste collected from all groups of households were segregated and weighted.
Waste generation rate was 5.4 kg/household/day. Household solid waste comprised of ten categories of wastes and with the largest
component (76.9%). The generation and composition of household solid waste were correlated with family size, education level
and households income. This paper adequately suggests new insights concerning the role of socioeconomic parameters in affecting
the generation of household waste. 相似文献
980.
Bai S Srikantaswamy S Krishnanandan V Naik OP 《Environmental monitoring and assessment》2012,184(1):239-249
Urban wastewater treatment leads to the generation of large quantities of biosolids. Accumulation of biosolids is a problem
of environmental relevance due to the existence of heavy metals in the biosolids. Determination of total metal in biosolid
provides information relating pollution levels. Determination of their mobilization capacity and behaviour in the environment
is an important task. An experimental approach commonly used for studying the mobility, transport and bioavailability of metal
in biosolids is the use of selective sequential extraction procedure. In the present study an attempt has been made to study
the heavy metal properties in biosolid samples collected from urban wastewater treatment plants located at Mysore, Karnataka.
Few heavy metals selected for the present study are cadmium, chromium, copper, iron, nickel and zinc. The concentration of
these metals in biosolids and their partition in different fractions are studied. The speciation of metals based on the sequential
extraction scheme was carried out. The concentration of heavy metals is lower than that established by European legislation.
The residual fraction has the maximum percentage of heavy metals whereas, only a small fraction of heavy metals (Fe, Zn and
Cd) are extracted in the most soluble fractions, exchangeable and carbonate fractions. 相似文献