Development and evaluation of a continuous coarse (PM10-PM2.5) particle monitor

In this paper, we describe the development and laboratory and field evaluation of a continuous coarse (2.5-10 microm) particle mass (PM) monitor that can provide reliable measurements of the coarse mass (CM) concentrations in time intervals as short as 5-10 min. The operating principle of the monitor is based on enriching CM concentrations by a factor of approximately 25 by means of a 2.5-microm cut point round nozzle virtual impactor while maintaining fine mass (FM)--that is, the mass of PM2.5 at ambient concentrations. The aerosol mixture is subsequently drawn through a standard tapered element oscillating microbalance (TEOM), the response of which is dominated by the contributions of the CM, due to concentration enrichment. Findings from the field study ascertain that a TEOM coupled with a PM10 inlet followed by a 2.5-microm cut point round nozzle virtual impactor can be used successfully for continuous CM concentration measurements. The average concentration-enriched CM concentrations measured by the TEOM were 26-27 times higher than those measured by the time-integrated PM10 samplers [the micro-orifice uniform deposit impactor (MOUDI) and the Partisol] and were highly correlated. CM concentrations measured by the concentration-enriched TEOM were independent of the ambient FM-to-CM concentration ratio, due to the decrease in ambient coarse particle mass median diameter with an increasing FM-to-CM concentration ratio. Finally, our results illustrate one of the main problems associated with the use of real impactors to sample particles at relative humidity (RH) values less than 40%. While PM10 concentrations obtained by means of the MOUDI and Partisol were in excellent agreement, CM concentrations measured by the MOUDI were low by 20%, and FM concentrations were high by a factor of 5, together suggesting particle bounce at low RH.     

Laboratory and field evaluation of measurement methods for one-hour exposures to O3, PM2.5, and CO.

While researchers have linked acute (less than 12-hr) ambient O3, PM2.5, and CO concentrations to a variety of adverse health effects, few studies have characterized short-term exposures to these air pollutants, in part due to the lack of sensitive, accurate, and precise sampling technologies. In this paper, we present results from the laboratory and field evaluation of several new (or modified) samplers used in the "roll-around" system (RAS), which was developed to measure 1-hr O3, PM2.5, and CO exposures simultaneously. All the field evaluation data were collected during two sampling seasons: the summer of 1998 and the winter of 1999. To measure 1-hr O3 exposures, a new active O3 sampler was developed that uses two nitrite-coated filters to measure O3 concentrations. Laboratory chamber tests found that the active O3 sampler performed extremely well, with a collection efficiency of 0.96 that did not vary with temperature or relative humidity (RH). In field collocation comparisons with a reference UV photometric monitor, the active O3 sampler had an effective collection efficiency ranging between 0.92 and 0.96 and a precision for 1-hr measurements ranging between 4 and 6 parts per billion (ppb). The limits of detection (LOD) of this method were 9 ppb-hr for the chamber tests and approximtely 16 ppb-hr for the field comparison tests. PM2.5 and CO concentrations were measured using modified continuous monitors--the DustTrak and the Langan, respectively. A size-selective inlet and a Nafion dryer were placed upstream of the DustTrak inlet to remove particles with aerodynamic diameters greater than 2.5 microm and to dry particles prior to the measurements, respectively. During the field validation tests, the DustTrak consistently reported higher PM2.5 concentrations than those obtained by the collocated 12-hr PM2.5 PEM samples, by approximately a factor of 2. After the DustTrak response was corrected (correction factor of 2.07 in the summer and 2.02 in the winter), measurements obtained using these methods agreed well with R2 values of 0.87 in the summer and 0.81 in the winter. The results showed that the DustTrak can be used along with integrated measurements to measure the temporal and spatial variation in PM2.5 exposures. Finally, during the field validation tests, CO concentrations measured using the Langan were strongly correlated with those obtained using the reference method when the CO levels were above the LOD of the instrument [approximately 1 part per million (ppm)].     

Developing, designing, and testing artificial set of lithologies for soil-aquifer treatment (SAT) systems without soil, using geosynthetic materials

Conventional soil-aquifer treatment (SAT) systems comprise of natural lithological sections up to the depth of zone of saturation or dried aquifers, which through geopurification process recharge the aquifers using domestic or industrial wastewaters. Such SAT systems have low infiltration capacity and frequently face the clogging problems, which causes environment hazards in the local areas. Under this study, three artificial set of lithologies (Lithology I, Lithology II, and Lithology III) were generated without using soil. Each one meter set of lithology was generated within a transparent cylindrical pipe of diameter 15 cm. Each lithology was equipped with nonwoven geotextile and geogrid material at different levels and comprises of coarse aggregate, fine aggregate, coarse sand, medium sand, and fine sand. Use of geotextile material within the artificial lithology shows approximately 8–10 times enhancement in the filtration capacity of the tested lithologies. Municipal wastewater (after primary treatment) was used to test the Lithologies I, II, and III. Between 100–200 l of wastewater was passed through each set of lithology everyday for seven days. Different water quality parameters such as pH, turbidity, electrical conductivity, fluoride, total suspended solids, biological oxygen demand, dissolve oxygen and carbon oxygen demand, chloride, and manganese were analyzed before and after passing through the lithologies everyday. One meter set of artificial lithologies have successfully reduced the concentration of measured water quality parameters between 60 and 93 %, without clogging. Lithology III equipped with superficial fine sand layer and two set of nonwoven geotextile has successfully removed 70–93 % concentration of wastewater. This study aims to demonstrate that a SAT system equipped with geotextile and without soil is more effective then the prevailing SAT systems. Study also proposed designs of SAT systems, which can be formed at unfavorable sites using abundant dry wells in which artificial set of lithologies can be used.     

A closure approach with multi-scale mixing length,and its application to wind and shear stress profiles within the atmospheric boundary layer

A method to determine flow specific first-order closure for the turbulent flux of momentum in the atmospheric boundary layer (ABL) is presented. This is based on the premise that eddy viscosity is a flow rather than a fluid property, and the physically more realistic assumption that the transfer of momentum and other scalar quantities in a turbulent flow takes place by a large, but finite number of length scales, than the often used single length scale, the ‘mixing length’. The resulting eddy viscosity is flow specific and when applied to the study of the ABL, yields the vertical profiles of shear stress and mean wind velocity in good agreement with observations. The method may be extended to other types of turbulent flows, however it should be recognized that each type of flow may yield a different eddy viscosity profile. Using the derived eddy viscosity the paper presents simple analytical solutions of the ABL equations to determine observationally consistent wind speed and shear stress profiles in the ABL for a variety of practical applications including air pollution modelling.     

A linear and nonlinear approach for interpretation of groundwater quality based on water quality index

In this study using linear and nonlinear approach, aggregate indices for various water quality parameters were analyzed. Using a linear and nonlinear interpolating surface, various water quality variables at grid points were investigated that is essential for mapping. The values help in constituting a key approach for determining the water quality index (WQI), which converts pollutant concentration data into subindex values and then combines them into a single score. One of the biggest advantages of WQI is its summary and intuitive communication capability which will be extremely helpful for demarcating safe aquifer zones of groundwater and in the selection of suitable method for remedial. The present study also describes pollution potential in ground water of Madhya Pradesh, India. The aggregate indices suggest intermediate to high pollution susceptibility in some region of Madhya Pradesh that may increase further if not managed. The overall interpretation of the study will be helpful in formulating suitable approach for water quality interpretation and sustainable planning of groundwater resources.     

Effect of different design aspects of pipe for earth air tunnel heat exchanger system: A state of art

Earth air tunnel heat exchanger (EATHE) is a promising passive technique to provide thermal comfort condition in buildings. EATHE system uses undisturbed temperature of the ground for heating/cooling of air. Despite the several advantages, this technique has not become much popular owing to its high capital cost (mainly pipe cost and trench excavation cost) and large land area requirements. The primary objective of this study is to present a comprehensive review of different EATHE pipe layouts, pipe properties and positioning of the pipe with their advantages and limitations. It is observed that the ring pipe layout is the most cost-effective pipe-layout for small size EATHE system because it saves excavation cost by using a trench of the existing foundation of the building. However, Grid pipe-layout is an ideal layout for a large size EATHE system. Multi-layer pipe layouts should be used to reduce the land area requirement significantly. Moreover, EATHE system can be installed beneath the building (under building foot-print) to eliminate extra land area requirement for the installation of EATHE system. This review article shows that the Initial capital cost and land area requirement for the EATHE system can be substantially reduced by using appropriate pipe layout. It can be concluded that if EATHE system is installed with proper design strategies, it will be a clean and cost-effective method for building heating/cooling with significant power savings.     

Modeling the impact of mitigation options on methane abatement from rice fields

The enhanced concentration of methane (CH₄) in the atmosphere is significantly responsible for the ominous threat of global warming. Rice (Oryza) paddies are one of the largest anthropogenic sources of atmospheric CH₄. Abatement strategies for mitigating CH₄ emissions from rice fields offer an avenue to reduce the global atmospheric burden of methane and hence the associated menace of climate change. Projections on population growth suggest that world rice production must increase to meet the population’s food energy demand. In this scenario, those mitigation options are advocated which address both the objectives of methane mitigation and increased production of rice simultaneously. In this paper, we have formulated a nonlinear mathematical model to investigate the effectiveness and limitations of such options in reducing and stabilizing the atmospheric concentration of CH₄ while increasing rice yield. In modeling process, it is assumed that implementation rate of mitigation options is proportional to the enhanced concentration of atmospheric CH₄ due to rice fields. Model analysis reveals that implementation of mitigation options not always provides “win-win” outcome. Conditions under which these options reduce and stabilize CH₄ emission from rice fields have been derived. These conditions are useful in devising strategies for effective abatement of CH₄ emission from rice fields along with sustainable increase in rice yield. The analysis also shows that CH₄ abatement highly depends on efficiencies of mitigation options to mitigate CH₄ emission and improve rice production as well as on the implementation rate of mitigation options. Numerical simulation is carried out to verify theoretical findings.     

Assessing the effects of transboundary ozone pollution between Ontario,Canada and New York,USA

We investigated the effects of transboundary pollution between Ontario and New York using both observations and modeling results. Analysis of the spatial scales associated with ozone pollution revealed the regional and international character of this pollutant. A back-trajectory-clustering methodology was used to evaluate the potential for transboundary pollution trading and to identify potential pollution source regions for two sites: CN tower in Toronto and the World Trade Center in New York City. Transboundary pollution transport was evident at both locations. The major pollution source areas for the period examined were the Ohio River Valley and Midwest. Finally, we examined the transboundary impact of emission reductions through photochemical models. We found that emissions from both New York and Ontario were transported across the border and that reductions in predicted O3 levels can be substantial when emissions on both sides of the border are reduced.     

Niche separation in two species of hare. Metabolic costs of plant phenolics

Summary The distributions of mountain hare (Lepus timidus) and European hare (L. europaeus) overlap in central Sweden, but they occupy separate food niches in winter. In Scandinavia, the European hare is mainly a grazer while mountain hare is a predominant browser. Browse contain high amounts of secondary metabolites, such as phenols, compared to grass. This raises the question if the two hare species differ in their metabolic tolerance of plant phenols and that these differences influence their food choice.Phenolic excretion in urine increased significantly with phenolic intake in both species. Excretion of glucuronic acid conjugates, one of the major pathways of elimination of phenols in both hare species, is positively correlated to phenolic intake and excretion. However, the extent of excretion of phenolics by this route was different in the two species of hare. European hares excreted substantially more glucuronic acid per amount of phenolics than mountain hare. The phenols were metabolized to a larger extent in the mountain hare, indicating a higher detoxification capacity. From these results it is likely that European hare have a higher cost for the detoxification of plant phenols compared to mountain hare. This cost and negative effect on sodium balance when feeding on browse may prevent exploitation of forest habitats by European hares, whereas mountain hare are better able to do so.     

The effect of paper industry effluent on growth, pigments, carbohydrates and proteins of rice seedlings

The effect of paper industry effluent on the growth and content of certain macromolecules of seedlings of rice (Oryza sativa L. cv. Kesari-82K) has been examined. The effects were investigated in relation to both concentration of effluent and time of exposure to the effluent. Percentage of germination, water imbibing capacity, growth, pigment, carbohydrate and protein content showed a decreasing trend with increase in effluent concentration and time. Protein content was the most sensitive macromolecule affected by effluent. Measurement of protein and protein enzymes might therefore provide a useful criterion for the evaluation of the phytotoxicity of effluent released from the pulp and paper industries.