Polylactide (PLA)—Halloysite Nanocomposites: Production, Morphology and Key-Properties

To evaluate the potential of halloysite nanotubes (HNT) as nanofiller for polylactide (PLA), various nanocomposites have been successfully produced by melt-blending the polyester matrix with HNT (HNT(QM)). HNT were also surface treated by silanization reaction with 3-(Trimethoxysilyl) propyl methacrylate (TMSPM). The morphology, thermal, tensile and impact strength properties of the nanocomposites containing 3?C12?% HNT were evaluated and compared to those of pristine (unfilled) PLA. The nanocomposites were characterized by higher rigidity (with Young??s modulus increasing with HNT loading), higher tensile strength (about 70?MPa at 6?% HNT(QM)), whereas the elongation at break and impact strength did not decrease. As demonstrated under dynamic solicitation (DMA), melt-blending PLA with HNT led to enhancement of storage modulus (E??) and offers the possibility to use PLA in applications requiring higher temperatures of utilization. However, with few exceptions, TGA and DSC measurements did not reveal important changes of thermal parameters. The surface silanization treatment proved to improve the quality of the nanofiller dispersion even at higher loading. As a result, good thermal stability associated to high tensile strength, and noticeable increases in impact properties were recorded. Furthermore, enhanced nucleating ability and crystallization kinetics of the PLA matrix were revealed as specific characteristics.     

Morphology, chemistry and distribution of neoformed spherulites in agricultural land affected by metallurgical point-source pollution

Metal distribution patterns in superficial soil horizons of agricultural land affected by metallurgical point-source pollution were studied using optical and electron microscopy, synchrotron radiation and spectroscopy analyses. The site is located in northern France, at the center of a former entry lane to a bunker of World War II, temporarily paved with coarse industrial waste fragments and removed at the end of the war. Thin sections made from undisturbed soil samples from A and B horizons were studied. Optical microscopy revealed the occurrence of yellow micrometer-sized (Ap horizon) and red decamicrometer-sized spherulites (AB, B(1)g horizons) as well as distinct distribution patterns. The chemical composition of the spherulites was dominated by Fe, Mn, Zn, Pb, Ca, and P. Comparison of calculated Zn stocks, both in the groundmass and in spherulites, showed a quasi-exclusive Zn accumulation in these neoformed features. Their formation was related to several factors: (i) liberation of metal elements due to weathering of waste products, (ii) Ca and P supply from fertilizing practices, (iii) co-precipitation of metal elements and Ca and P in a porous soil environment, after slow exudation of a supersaturated soil solution in more confined mineral media.     

Down syndrome maternal serum marker screening after 18 weeks' gestation

Women having access to prenatal care late in pregnancy may still wish to benefit from maternal serum screening for Down syndrome. Therefore, we established reference values for α-feto protein (AFP) and free β-human chorionic gonadotrophin (β-hCG), and assessed the diagnostic value of maternal serum marker screening at 18–35 weeks' gestation based upon a series of 4072 sera from unaffected pregnancies and 118 sera from pregnant women with fetuses affected by Down syndrome. Using a 1/250 risk cut-off, a detection rate of 72.9% (95% CI = 71.5–74.3%) was achieved with a false-positive rate of 7.51% (95% CI = 6.71–8.3%). This was not significantly different from the percentages observed in our 14–17 weeks routine screening (50 596 patients): 71.9% (95% CI = 71.5–72.3%) and 6.48% (95% CI = 6.28–6.68%), respectively. Detection and screen-positive rates were, respectively, 51.3% (95% CI = 35.6–67.0%) and 5.95% (95% CI = 5.12–6.68%) in women aunder 35 years of age, and 84.8% (95% CI = 76.9–92.7%) and 24% (95% CI = 20.7–27.3%) in women aged 35 years and over. In conclusion, maternal serum marker screening is feasible at 18 weeks' gestation and later, which may be of interest in selected cases. Copyright © 2002 John Wiley & Sons, Ltd.     

Costs and benefits of preventing workplace accidents: The case of participatory ergonomics

This paper provides a cost-benefit analysis of a participatory ergonomics program conducted at the beginning of the 1990s to reduce back-related disorders among packers at a warehouse of the Société des Alcools du Québec in Quebec City. After evaluating the costs of the program, we present a rigorous econometric analysis to assess how many accidents have been prevented by the program so as to compute the direct and indirect costs avoided as a result of such accident reduction. We show that the program has indeed been profitable for the firm.     

Land change in the southern Yucatán and Calakmul biosphere reserve: effects on habitat and biodiversity.

The southern Yucatán contains the largest expanse of seasonal tropical forests remaining in Mexico, forming an ecocline between the drier north of the peninsula and the humid Petén, Guatemala. The Calakmul Biosphere Reserve resides in the center of this region as part of the Mesoamerican Biological Corridor. The reserve's functions are examined in regard to land changes throughout the region, generated over the last 40 years by increasing settlement and the expansion and intensification of agriculture. These changes are documented from 1987/1988 to 2000, and their implications regarding the capacity of the reserve to protect the ecocline, forest habitats, and butterfly diversity are addressed. The results indicate that the current landscape matrix serves the biotic diversity of the reserve, with several looming caveats involving the loss of humid forests and the interruption of biota flow across the ecocline, and the amount and proximity of older forest patches beyond the reserve. The highly dynamic land cover changes underway in this economic frontier warrant an adaptive management approach that monitors the major changes underway in mature forest types, while the paucity of systematic ecological and environment-development studies is rectified in order to inform policy and practice.     

Egg survival,embryonic development,and larval characteristics of northern shrimp (<Emphasis Type="Italic">Pandalus borealis</Emphasis>) females subject to different temperature and feeding conditions

Laboratory experiments on ovigerous females of northern shrimp (Pandalus borealis) were used to assess the effects of temperature and food ration on female condition during incubation and examine how combined effects of temperature and female condition influenced egg survival, embryonic development, and larval characteristics. Ovigerous females were maintained at 2°C, 5°C, and 8°C and fed on a low (three times/week; 2–2.7% W/W) or high ration (five times/week at satiation). The increase in temperature accelerated the developmental time of the eggs but their survival at 8°C was reduced. Conversion efficiency of yolk reserves in developing embryos was significantly reduced at elevated temperatures and larvae hatching at 2°C and 5°C were significantly larger and heavier than those hatching at 8°C. The experimental design did not result in any effect of food ration on the energetic condition of females or on egg characteristics and their biochemical composition. However, lower energy reserves were observed for females held at 8°C.