CO2 storage capacity estimation: Methodology and gaps

Implementation of CO₂ capture and geological storage (CCGS) technology at the scale needed to achieve a significant and meaningful reduction in CO₂ emissions requires knowledge of the available CO₂ storage capacity. CO₂ storage capacity assessments may be conducted at various scales—in decreasing order of size and increasing order of resolution: country, basin, regional, local and site-specific. Estimation of the CO₂ storage capacity in depleted oil and gas reservoirs is straightforward and is based on recoverable reserves, reservoir properties and in situ CO₂ characteristics. In the case of CO₂-EOR, the CO₂ storage capacity can be roughly evaluated on the basis of worldwide field experience or more accurately through numerical simulations. Determination of the theoretical CO₂ storage capacity in coal beds is based on coal thickness and CO₂ adsorption isotherms, and recovery and completion factors. Evaluation of the CO₂ storage capacity in deep saline aquifers is very complex because four trapping mechanisms that act at different rates are involved and, at times, all mechanisms may be operating simultaneously. The level of detail and resolution required in the data make reliable and accurate estimation of CO₂ storage capacity in deep saline aquifers practical only at the local and site-specific scales. This paper follows a previous one on issues and development of standards for CO₂ storage capacity estimation, and provides a clear set of definitions and methodologies for the assessment of CO₂ storage capacity in geological media. Notwithstanding the defined methodologies suggested for estimating CO₂ storage capacity, major challenges lie ahead because of lack of data, particularly for coal beds and deep saline aquifers, lack of knowledge about the coefficients that reduce storage capacity from theoretical to effective and to practical, and lack of knowledge about the interplay between various trapping mechanisms at work in deep saline aquifers.     

WATER MANAGEMENT IN ONTARIO1

ABSTRACT: The Ontario Ministry of the Environment has based its water quality management approach on a set of guidelines published in 1970. In light of the changing societal and economic background, advancement in technology and scientific knowledge, and philosophical attitudes towards water management, the water management program was recently revised. Factors influencing the revised approach, including federal-provincial interrelationships and international commitments under the Canada-U.S. Agreement, are summarized. The revised program consists of a goal statement, policies to implement this goal, revised water quality objectives, and detailed implementation procedures for field staff use. Rather than promulgating regulations to impose arbitrary effluent or receiving water standards on a province-wide basis, the revised approach involves the imposition of legally enforceable effluent requirements on a case-by-case basis. Although the paper emphasizes the surface water quality program, it also outlines the Ministry's goals, policies, and procedures for the management of surface-water quantity, as well as ground water quality and quantity.     

Model simulations of dissolved oxygen characteristics of Minnesota lakes: Past and future

A deterministic, one-dimensional, unsteady numerical model has been developed, tested, and applied to simulate mean daily dissolved oxygen (DO) characteristics in 27 lake classes in the state of Minnesota. Reaeration and photosynthesis are the oxygen sources, while respiration, sedimentary, and biochemical water column oxygen demand are the sinks of oxygen in the model. The lake classes are differentiated by surface area (A _s), maximum depth (H _max), and trophic status expressed as Secchi depth (Z _s). Because lake stratification is most important to lake oxygen dynamics, simulated DO characteristics are plotted in terms of a stratification parameterA _s/H _max ^0.25 and Secchi depthZ _s. Simulations provide DO profiles on a daily time scale. Specific DO characteristics of ecological and environmental interest are epilimnetic DO, hypolimnetic DO, DO gradient from surface to bottom, and DO minima and maxima. Specific results are as follows: Simulated mean daily and weekly DO values in the epilimnion of all lakes for both past and future climate scenarios are near saturation over the summer season. Hypolimnetic DO values depend strongly on lake morphometry, trophic status, and time throughout the summer season. Future climate conditions are specified as the historical records from 1955 to 1979, adjusted (monthly) by the 2 × CO₂ GISS model output to account for doubling of atmospheric CO₂. With this climate change, weekly averaged epilimnetic DO is projected to drop by less than 2 mg/liter, and will remain above 7 mg/liter throughout the open water season. The hypolimnetic DO reductions after climate change are on the order of 2–8 mg/liter. Periods of anoxia are longer by as much as 80 days. Those changes would alter water quality dynamics in lakes and have a profound effect on lake ecosystems including indigenous fishes. The results presented are useful for evaluating environmental management options.     

ANALYSIS OF WIND- AND SHIP-INDUCED SEDIMENT RESUSPENSION IN DULUTH-SUPERIOR HARBOR1

ABSTRACT: Suspended solids and ammonium concentration profiles measured at five locations in Duluth-Superior Harbor during July-October 1985 were analyzed to quantify wind and ship effects on sediment resuspension and resulting harbor water quality. Wind components from the SE quadrant correlated strongly with depth-averaged suspended solids concentrations that were unaffected by ship passage or thermal stratification. Winds from that quadrant have the largest fetch in the harbor. The highest correlation (r²= 0.93) was with the 6-hour average of the ESE wind velocity component. Multiple linear regression analysis of data from post-ship passage concentration profiles yielded numerical estimates of settling velocities of 0.08 to 0.25 cm s^?1, typical of ship-resuspended sediments, and vertical eddy diffusivities of 4 to 13 cm² s¹. The results suggest that ambient vertical eddy diffusivities in the harbor are less than 4 cm² s^?1 in the absence of ship passages and with winds less than 5 m s^?1 (10 knots).     

Climate policy support under political consensus: exploring the varying effect of partisanship and party cues

By creating attitudinal rifts among partisan voters, political polarization is expected to negatively affect chances of effectively mitigating climate change. While such expectations generally have found support, less attention has been paid to the opposite claim that political consensus should eliminate the partisan dimension in climate change politics. This study tests this claim by studying how party identification, and party cues specifically, affects public policy attitudes in a context defined by political consensus. Using data from a large online access panel in Sweden, party identification and party cues are shown to matter for policy attitudes even in a consensus context. This effect is not limited to certain issues but is found across a wide range of policies, and the effect of party cues, for a given issue, varies across parties. The implications of this study and areas for future work are discussed.     

Modeling the exposure of children and adults via diet to chemicals in the environment with crop-specific models

Exposure to chemicals via diet is a major uptake pathway for many compounds but is often estimated in a rather generic way. We use a new model framework (NMF) with crop-specific models to predict the dietary intake by 4-5-year-old children and 14-75-year-old women of three environmental compounds from their background concentrations in soil and air. Calculated daily intakes of benzo(a)pyrene and 2,3,7,8-TCDD are in good agreement with measured results from diet studies. The major source of both compounds in human diet is deposition from air. Inhalation of air and ingestion of soil play a minor role. Children take up more than twice the amount than adults per kg bodyweight, due to higher consumption per kg bodyweight. Contrary, the methods for indirect human exposure suggested in the Technical Guidance Document (TGD) for chemical risk assessment in the EU lead to overprediction, due to unrealistic consumption data and a false root model.     

Maßnahmen zur Dioxinminderung an Müllverbrennungsanlagen

The 17th BlmSchV fixed the emission limit of 0.1 ng TE/m_n ³ for PCDD/F’s produced as a result of waste- and special waste incinerators. This article introduces the different measures implemented to uphold this limit, and discusses their advantages and disadvantages. Methods of optimising the incineration conditions are among the primary measures. Different geometry’s for conventional oven incineration rooms were discussed, and an effective modernisation method was introduced (Temelli nozzles). The chemical and technical basis of an often discussed gasification method, as well as the characteristics of three specialised techniques (Coke Burn technique, Thermo-Select technique and Noell-DBI technique) are explained in this article. Alongside the secondary measures of hot-dust filtration and inhibition being added to the washers in an attempt to achieve PCDD/F adsorption. The most important tertiary measures, namely the SCR technique, along with a variety of coke adsorption techniques are introduced, with their advantages and disadvantages. New techniques such as DeDioxin and Medisorbon are also addressed.     

The Role of Organic Matter in Natural Aquatic Systems: Analytical Constraints

The dissolved organic matter in aquatic systems consists of a heterogeneous mixture of compounds with wide ranging chemical properties and diverse origins. the presence of organic matter (OM) in surface and ground waters has important implications with regard to the mobility and therefore fate of many potential organic and inorganic pollutants. the majority of the analytical approaches in current use require exhaustive pre-treatment steps which may lead to the formation of artefacts within the sample. an analytical technique based upon gel permeation chromatography is proposed as a more reliable procedure for the characterisation of naturally occurring dissolved organic matter.     

Nachhaltige Entwicklung von Managementstrategien: Multikriterielle Bewertungs- und Entscheidungshilfe-Instrumente im Umweltbereich

Zur Unterstützung von Bewertungs- und Entscheidungsprozessen über die Nachhaltigkeit von Managementstrategien, deren Auswirkungen durch unterschiedlich dimensionierte Indikatoren gemessen werden, gibt es verschiedene mathematische Methoden. In diesem Beitrag werden die Prinzipien dieser sog. multikriteriellen Bewertungs- und Entscheidungshilfeinstrumente beispielhaft anhand einer Auswahl von Strategien für ein Nachhaltiges Wassermanagement vorgestellt, sowie Vor- und Nachteile herausgearbeitet. Es wird gezeigt, dass sich die Verfahren insbesondere in Transparenz, Objektivit?t und durch den Grad an Partizipation durch Akteure z.T. erheblich unterscheiden. W?hrend die Hassediagrammtechnik sich an den naturwissenschaftlich begründbaren Datenmatrix orientiert und somit eine objektive und transparente Bewertung und Datenanalyse liefert, haben Konkordanzanalyse, Nutzwertanalyse, PROMETHEE und AHP ihre St?rken in der M?glichkeit, Akteure bzw. Stakeholder am Entscheidungsprozess partizipieren zu lassen. *** DIRECT SUPPORT *** A00OI029 00003     

Optimality of parental investment: The influence of nursing on reproductive success of mother and female young house mice

Summary The amount of parental milk investment determines not only the number of young the parent can produce, but also affects the offspring's fitness. The antagonism between quantity and quality of offspring was investigated in laboratory mice.In nursing first litters containing 2,4, ..., 14 pups, mothers invested increasing amounts of milk. This mainly extended the intervals between their first and second litters and slightly increased the size of their second litters, whilst third litters were not affected. In the female young, the decreasing amount each individual received as a result of increasing litter size led to delayed birth and reduced the size of their first litters. The intervals between their first and second litters and the size of the second litters were also affected, although to a lesser extent.Taking these results into consideration on a standard lifetime pattern of reproduction, the effects were calculated on net reproductive rates as an expression of fitness. Death rates were assumed that referred to population equilibrium or population growth. In both situations, the fitness curves of mothers and young showed that the actual level of milk investment and the level yielding optimal reproduction were in agreement. There was no significant deviation towards increased investment, as might result from parent-offspring conflict.