Bioavailability of copper,cadmium, zinc,and lead in tropical savanna soils assessed by diffusive gradient in thin films (DGT) and ion exchange resin membranes

The technique of diffusion gradient in thin films (DGT) for assessing bioavailable metals has not been tested under field conditions. We assessed the relationships of DGT- and cation exchange resin-membrane-measured concentrations of Cd, Cu, Pb, and Zn with plant uptake of the metals under greenhouse and field conditions. In the greenhouse, the effective concentrations of Cu, Pb, and Zn by DGT correlated significantly with uptake by sorghum (Sorghum bicolor), but cation exchange resin-membrane-measured concentrations of Cd, Pb, and Zn did not correlate with sorghum uptake. In the field, the DGT-measured concentrations of Cd, Pb, and Zn were not linearly related to uptake Cd, Pb, and Zn by lettuce (Lactuca sativa) except for Cu uptake (r = 0.87, p < 0.05). Similarly, it was only the resin-membrane-extractable Pb that correlated with Pb uptake by lettuce (r = 0.77; p < 0.05). However, fitting non-linear regression models improved the plant metal uptake predictions by DGT-measured bioavailable Cd, Cu, Pb, and Zn under field conditions. In conclusion, the DGT technique was fairly predictive of bioavailability in the greenhouse, but not in the field.     

Evaluation of sediment quality guidelines derived using the screening-level concentration approach for application at uranium operations in Saskatchewan,Canada

Sediment quality guidelines (SQGs) can be derived using different approaches and are commonly used in environmental management, reclamation, and risk assessment. The screening-level concentration (SLC) approach has been used in Ontario, Canada, to derive lowest effect levels (LELs) and severe effect levels for use as SQGs. This approach was adopted by the Canadian Nuclear Safety Commission (CNSC) to set guidelines for metals (As, Cr, Cu, Pb, Mo, Ni, Se, U, and V) and radionuclides (Ra-226, Pb-210, and Po-210) in sediment at northern Saskatchewan uranium mining and milling operations. The SLC approach is based on total metal and radionuclide concentrations in sediment, and corresponding benthic community composition data for a specific sampling site. In this study, sediment chemistry (total metals and radionuclides) and benthic community data from northern Saskatchewan uranium operations were compiled and examined. Results indicate that the CNSC-derived SQGs had limited relationships to observed effects, or lack thereof, on benthic invertebrate communities near uranium operations in Saskatchewan. The LELs were found to correctly align with effects at 95% of the sites that had effects, on a general basis, but on an element-specific basis many of the elements had concentrations at effect sites below their LELs. Furthermore, concentrations of the evaluated elements exceeded at least one LEL at 60% of the no-effect sites. The high number of exceedences of LELs at reference and no-effect sites (false-positives) calls to question the appropriateness of the CNSC-derived SQGs. It is suggested that alternatives to the SLC approach be explored.     

Heavy metal pattern and solute concentration in soils along the oldest highway of the world – the AVUS Autobahn

Highways and main roads are a potential source of contamination for the surrounding environment. High traffic rates result in elevated heavy metal concentrations in road runoff, soil and water seepage, which has attracted much attention in the recent past. Nonetheless, investigations of pollutants in roadside soils are still a subject of major interest due to the rapid development of traffic systems and increasing traffic all over the world. The accumulation of the heavy metals Pb, Cd, Cu and Zn in soils along the oldest federal highway of the world has been studied by sampling a roadside transect of 125 by 10?m. In addition, heavy metal concentrations of Pb, Cd, Zn, Cu, Ni and Cr in soil solutions from different distances (2.5, 5 and 10?m) from the hard shoulder of the highway and from three soil depths (10, 30, and 50?cm) were investigated. The results show that heavy metal concentrations are up to 20 times increased compared to the geochemical background levels and a reference site of 800-m distance from the roadside. Soil matrix concentrations in the topsoil (0-10?cm) mostly exceeded the precautionary values of the German Federal Soil Protection and Contamination Ordinance (BBodSchV). The concentrations of Cd, Pb and Zn in the soil matrix tended to decrease with distance from the roadside edge, whereas the concentrations in the soil solution increased at a distance of 10?m onwards due to a lower soil pH. Because of both high pH values and a high sorption capacity of the soils, soil solution concentrations seldom exceeded the trigger values of the German Federal Soil Protection and Contamination Ordinance (BBodSchV) for transferring soil solution to groundwater.     

The effects of low frequency noise on mental performance and annoyance

Low frequency noise (LFN) as background noise in urban and work environments is emitted from many artificial sources such as road vehicles, aircraft, and air movement machinery including wind turbines, compressors, and ventilation or air conditioning units. In addition to objective effects, LFN could also cause noise annoyance and influence mental performance; however, there are no homogenous findings regarding this issue. The purpose of this research was to study the effects of LFN on mental performance and annoyance, as well as to consider the role of extraversion and neuroticism on the issue. This study was conducted on 90 students of Iran University of Medical Sciences (54 males and 36 females). The mean age of the students was 23.46 years (SD?=?1.97). Personality traits and noise annoyance were measured by using Eysenck Personality Inventory and a 12-scale self-reported questionnaire, respectively. Stroop and Cognitrone computerized tests measured mental performance of participants each exposed to 50 and 70 dBA of LFN and silence. LFNs were produced by Cool Edit Pro 2.1 software. There was no significant difference between mental performance parameters under 50 and 70 dBA of LFN, whereas there were significant differences between most mental performance parameters in quiet and under LFN (50 and 70 dBA). This research showed that LFN, compared to silence, increased the accuracy and the test performance speed (p?<?0.01). There was no association between LFN and noise annoyance (p?>?0.01). Introverts conducted the tests faster than extraverts (p?<?0.05). This research showed that neuroticism does not influence mental performance. It seems that LFN has increased arousal level of participants, and extraversion has a considerable impact on mental performance.     

Assessment of heavy metal enrichment in the offshore fine-grained sediments of the Caspian Sea

Sampling of the offshore seabed sediments of southwestern part of the Caspian Sea was carried out by gravity corer in order to study heavy metal concentration and the physicochemical factors controlling their distribution in the fine-grained fraction. The grain size distribution, amount, and type of clay minerals, total organic carbon (TOC) content, and Eh–pH of the sediments were determined. The average concentrations of the heavy metals in ppm are Mn (563), Cu (207.5), Sr (187), Zn (94), Pb (26.3), Ni (14.5), Co (11.5), Cd (2.56), and Ag (1.04) in their order of abundances. Co and Zn mostly indicate increase in silt-size fraction of the sediments suggesting their probable detrital provenance but the Mn, Ni, Cu, Sr, Pb, Cd, and Ag concentrations show a similar trend to distribution of the clay-size fraction. The concentrations of Mn, Co, and Cd increase with increase in the TOC content but the Cu, Pb, Ni, Ag, and Sr concentrations decrease with increase of the TOC content. The amounts of Zn, Cu, Sr, Pb, Cd, and Ag increase with increase in the CaCO₃ content. The calculated enrichment factor indicates that the sediments are very strong to extremely enriched in Ag, significantly enriched in Cu and Cd, and depleted to mineral for Pb, Sr, Co, Ni, and Zn. Variations of the Cu, Sr, Cd, Ag, and Pb concentrations are similar to the clay and CaCO₃ distributions.     

The use of sensory perception indicators for improving the characterization and modelling of total petroleum hydrocarbon (TPH) grade in soils

This paper proposes a multistep approach for creating a 3D stochastic model of total petroleum hydrocarbon (TPH) grade in potentially polluted soils of a deactivated oil storage site by using chemical analysis results as primary or hard data and classes of sensory perception variables as secondary or soft data. First, the statistical relationship between the sensory perception variables (e.g. colour, odour and oil–water reaction) and TPH grade is analysed, after which the sensory perception variable exhibiting the highest correlation is selected (oil–water reaction in this case study). The probabilities of cells belonging to classes of oil–water reaction are then estimated for the entire soil volume using indicator kriging. Next, local histograms of TPH grade for each grid cell are computed, combining the probabilities of belonging to a specific sensory perception indicator class and conditional to the simulated values of TPH grade. Finally, simulated images of TPH grade are generated by using the P-field simulation algorithm, utilising the local histograms of TPH grade for each grid cell. The set of simulated TPH values allows several calculations to be performed, such as average values, local uncertainties and the probability of the TPH grade of the soil exceeding a specific threshold value.     

Modeling of Cr contamination in the agricultural lands of three villages near the leather industry in Kasur,Pakistan, using statistical and GIS techniques

Kasur is one of the hubs of leather industry in the Punjab, Pakistan, where chrome tanning method of leather processing is extensively being used. Chromium (Cr) accumulation levels in the irrigation water, soil, and seasonal vegetables were studied in three villages located in the vicinity of wastewater treatment plant and solid waste dumping site operated by the Kasur Tanneries Waste Management Agency (KTWMA). The data was interpreted using analysis of variance (ANOVA), clustering analysis (CA), and principal component analysis (PCA). Interpolated surface maps for Cr were generated using the actual data obtained for the 30 sampling sites in each of the three villages for irrigation water, soil, and seasonal vegetables. The level of contamination in the three villages was directly proportional to their distance from KTWMA wastewater treatment plant and the direction of water runoff. The highest level of Cr contamination in soil (mg kg^?1) was observed at Faqeeria Wala (37.67), intermediate at Dollay Wala (30.33), and the least in Maan (25.16). A gradational variation in Cr accumulation was observed in the three villages from contaminated wastewater having the least contamination level (2.02–4.40 mg L^?1), to soil (25.16–37.67 mg kg^?1), and ultimately in the seasonal vegetable crops (156.67–248.33 mg kg^?1) cultivated in the region, having the highest level of Cr contamination above the permissible limit. The model used not only predicted the current situation of Cr contamination in the three villages but also indicated the trend of magnification of Cr contamination from irrigation water to soil and to the base of the food chain. Among the multiple causes of Cr contamination of vegetables, soil irrigation with contaminated groundwater was observed to be the dominant one.     

Depth-related shift in life history strategies of a brooding and broadcasting deep-sea asteroid

Combining field and laboratory work, this study investigated the reproductive cycle, aggregative behavior, spawning periodicity, development and early growth of the sea star Henricia lisa living at bathyal depths off eastern Canada. Marked differences were found between individuals from ~1,300 and ~600 m deep. The former had a male biased sex ratio and an aperiodic reproductive cycle, whereas the latter displayed an equal sex ratio and a biannual breeding pattern. Furthermore, the maximum size was larger and female fecundity roughly five times higher in shallower compared to deeper populations. In the tanks, aggregative behavior was recorded twice a year during the summer and winter breeding periods. The onset of aggregations and spawning coincided with a temperature of 3–4°C. Males spawned first and females typically responded inside 30–60 min. Between 12 and 20 eggs were retained to be brooded under the arched arms of the female, whereas the remainder were broadcasted and developed without parental care. The fertilized eggs underwent a first cleavage after 12 h, reached the brachiolaria stage in 1 month, became juveniles within 3–4 months and reached ~ 4 mm in diameter after 14–17 months of growth. The embryos and juveniles developed at the same rate whether brooded or not, and development of winter cohorts was typically slower due to lower prevailing temperatures. This study of H. lisa provides the first evidence of lecithotrophy in a seasonally breeding deep-sea echinoderm and of brooding in a deep-sea asteroid.     

Noise disturbance caused by outdoor activities�� a simulated-environment study for Ali Sami Yen Stadium, ?stanbul

Negative effects of noise on individuals, the inevitable result of urbanization, have become a significant urban problem in our day. Introduction of an approach to the noise problem on an urban-planning scale lightens the burden of measures required to be taken against noise at the stages of regional and developmental planning. Stadiums, which should be also evaluated from the point of noise problem when planning decisions are made on the urban planning scale, may cause very serious problems differing depending on the region they are located in. In this article, various dimensions of the noise problem caused by stadiums have been exemplified by making an assessment on Ali Sami Yen football stadium located in Mecidiyeköy district which is among important residential and commercial centres of ?stanbul or Turkey. When the simulation results obtained for ordinary days and match days are evaluated, it has been found out that the people living in the area are exposed to noise levels substantially exceeding the acceptable values. Results of the survey conducted in the area have clearly revealed the existence of noise problem, too.