Suspended Particulate Matter Distribution in Rural-Industrial Satna and in Urban-Industrial South Delhi

An air quality sampling program was designed and implemented to collect the baseline concentrations of respirable suspended particulates (RSP = PM₁₀), non-respirable suspended particulates (NRSP) and fine suspended particulates (FSP = PM_2.5). Over a three-week period, a 24-h average concentrations were calculated from the samples collected at an industrial site in Southern Delhi and compared to datasets collected in Satna by Envirotech Limited, Okhla, Delhi in order to establish the characteristic difference in emission patterns. PM_2.5, PM₁₀, and total suspended particulates (TSP) concentrations at Satna were 20.5 ± 6.0, 102.1 ± 41.1, and 387.6 ± 222.4 μg m⁻³ and at Delhi were 126.7 ± 28.6, 268.6 ± 39.1, and 687.7 ± 117.4 μg m⁻³. Values at Delhi were well above the standard limit for 24-h PM_2.5 United States National Ambient Air Quality Standards (USNAAQS; 65 μg m⁻³), while values at Satna were under the standard limit. Results were compared with various worldwide studies. These comparisons suggest an immediate need for the promulgation of new PM_2.5 standards. The position of PM₁₀ in Delhi is drastic and needs an immediate attention. PM₁₀ levels at Delhi were also well above the standard limit for 24-h PM₁₀ National Ambient Air Quality Standards (NAAQS; 150 μg m⁻³), while levels at Satna remained under the standard limit. PM_2.5/PM₁₀ values were also calculated to determine PM_2.5 contribution. At Satna, PM_2.5 contribution to PM₁₀ was only 20% compared to 47% in Delhi. TSP values at Delhi were well above, while TSP values at Satna were under, the standard limit for 24-h TSP NAAQS (500 μg m⁻³). At Satna, the PM₁₀ contribution to TSP was only 26% compared to 39% in Delhi. The correlation between PM₁₀, PM_2.5, and TSP were also calculated in order to gain an insight to their sources. Both in Satna and in Delhi, none of the sources was dominant a varied pattern of emissions was obtained, showing the presence of heterogeneous emission density and that nonrespirable suspended particulate (NRSP) formed the greatest part of the particulate load.     

Determination of Impact of Urbanization on Agricultural Land and Wetland Land Use in Balçovas’ Delta by Remote Sensing and GIS Technique

Because of their intense vegetation and the fact that they include areas of coastline, deltas situated in the vicinity of big cities are areas of greet attraction for people who wish to get away from in a crowded city. However, deltas, with their fertile soil and unique flora and fauna, need to be protected. In order for the use of such areas to be planned in a sustainable way by local authorities, there is a need for detailed data about these regions. In this study, the changes in land use of the Balçova Delta, which is to the immediate west of Turkey’s third largest city Izmir, from 1957 up to the present day, were investigated. In the study, using aerial photographs taken in 1957, 1976 and 1995 and an IKONOS satellite image from the year 2005, the natural and cultural characteristics of the region and changes in the coastline were determined spatially. Through this study, which aimed to reveal the characteristics of the areas of land already lost as well as the types of land use in the Balçova delta and to determine geographically the remaining areas in need of protection, local authorities were provided with the required data support. Balçova consists of flat and fertile wetland with mainly citrus-fruit orchards and flower-producing green houses. The marsh and lagoon system situated in the coastal areas of the delta provides a habitat for wild life, in particular birds. In the Balçova Delta, which provides feeding and resting for migratory birds, freshwater sources are of vital importance for fauna and flora. The settlement area, which in 1957 was 182 ha, increased 11-fold up to the year 2005 when it reached 2,141 ha. On the other hand, great losses were determined in farming land, olive groves, forest and in the marsh and lagoon system. This unsystematic and rapid urbanization occurring in the study region is not only causing the loss of important agricultural land and wetland, but also lasting water and soil pollution.     

Heavy Metal Contents of the Karasu Creek Sediments, Nigde, Turkey

Heavy metal contamination in sediments of the Karasu spring was investigated in the presented study. In this respect, sediment samples were collected from contaminant sites along the spring starting from the spring water manifestation site, base of the Akkaya dam to the dam exit site. Heavy metal concentrations were determined by X-ray Fluorescence Spectrometer. Cobalt, copper, arsenic, tin, nickel, zinc, cadmium, lead, aluminum, iron, titan, chromium and manganese contents of the Karasu creek sediments are found as 18.30–69.00, 12.40–595.0 5.50–345.3, 5.80–15.1, 10.9–64.1, 28.90–103,300, 4.1–356.2, 7.70–37,840, 13,460–109,400, 11,740–62,900, 22.18–59.04, 41.70–369 and 12.09–3,480 mg/kg, respectively. Results indicate the presence of a contamination in the Karasu creek. All the metal concentrations were found to be exceeding their acceptable limit values. Eutrophication is developed in the Karasu creek and the Akkaya dam. It is thought that heavy metal accumulation in the creek is originated from discharge from mine quarries, industrial and domestic wastes. Protection zones should be defined and all necessary measures must be taken along the Karasu creek.     

A Comparison Between Two Moss Species Used as Transplants for Airborne Trace Element Biomonitoring in NE Italy

Transplants of the mosses Hypnum cupressiforme and Pseudoscleropodium purum used as active biomonitors of airborne trace elements were compared in a survey carried out at Trieste (NE Italy). Twelve elements were considered: Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, Ti, V, Zn. Water-washed materials of H. cupressiforme and P. purum, collected in a remote area to prepare transplants, showed comparable content of all elements, excluding Pb. Transplants of P. purum showed a significantly higher accumulation of Al, Fe, Pb and Ti; higher levels of Cu and V were accumulated in H. cupressiforme. Losses of some elements occurred in some samples of both species; the most consistent losses regarded Cr and Mn. Accumulation data of Al, As, Cd, Hg, Zn found in the two transplanted sets were not correlated. Differences in element uptake in the two mosses are likely to depend mainly on morphology, and probably on the different forms of emission and deposition types of the elements. The two mosses showed an overall accordance in discriminating sites highly and scarcely affected by trace element depositions, although they accumulated some elements, in particular Hg and Zn, in different ways. P. purum proved to be a better accumulator than H. cupressiforme, showing similar or higher accumulation and lower loss of almost all elements, especially those related to particulate, dry depositions; H. cupressiforme could be effective in detecting large-scale patterns, related to wet depositions. These results indicate that these mosses cannot be used interchangeably for monitoring particular elements, and are able to provide complementary information on different, local and long-range deposition patterns.     

Performance of an electrochemical COD (chemical oxygen demand) sensor with an electrode-surface grinding unit

An electrochemical COD (chemical oxygen demand) sensor using an electrode-surface grinding unit was investigated. The electrolyzing (oxidizing) action of copper on an organic species was used as the basis of the COD measuring sensor. Using a simple three-electrode cell and a surface grinding unit, the organic species is activated by the catalytic action of copper and oxidized at a working electrode, poised at a positive potential. When synthetic wastewater was fed into the system, the measured Coulombic yields were found to be dependent on the COD of the synthetic wastewater. A linear correlation between the Coulombic yields and the COD of the synthetic wastewater was established (10-1000 mg L(-1)) when the electrode-surface grinding procedure was activated briefly at 8 h intervals. When various kinds of wastewater samples obtained from various sewage treatment plants were measured, linear correlations (r(2)> or = 0.92) between the measured EOD (electrochemical oxygen demand) value and COD of the samples were observed. At a practical wastewater treatment plant, the measurement system was successfully operated with high accuracy and good stability over 3 months. These experimental results show that the application of the measurement system would be a rapid and practical method for the determination of COD in water industries.     

Real-time PCR for detection of the Aspergillus genus

Aspergillus is a genus of mold that has strong indoor sources, including several species capable of acting as opportunistic pathogens. Previous studies suggest that Aspergillus could serve as an indicator for abnormal mold growth or moisture, making it an important genus for environmental monitoring. Here, a quantitative polymerase chain reaction (qPCR, or real-time PCR) assay is presented for Aspergillus. The assay shows good specificity for the genus, detecting all Aspergillus species tested, although a few non-Aspergillus species are also amplified. Sensitivity testing demonstrates that DNA representing one conidium can be detected. A validation study compared qPCR results against direct microscopy counts using A. fumigatus conidia aerosolized into a laboratory chamber. The assay was then used to quantify Aspergillus in indoor air samples, demonstrating its utility for environmental monitoring. Analysis of a small number of clinical sputum samples showed complete agreement with culturing results.     

Validation of a European standard for the determination of hexavalent chromium in solid material

A European standard for the determination of Cr(vi) in solid material has been elaborated in the framework of an international co-operation and finally validated in the course of an interlaboratory comparison. The procedure is based on the alkaline digestion prescribed by EPA method 3060A followed by ion chromatography and determines an operationally defined content of Cr(vi), including water-soluble and insoluble chromates. A preliminary robustness study was carried out in order to compare different extraction methodologies and to study the equivalency of different analytical methods for the determination of Cr(vi) in alkaline extracts of soil and waste materials. During an interlaboratory validation trial with 19 European laboratories a set of 4 samples (2 soil and 2 waste samples) was analysed to determine performance characteristics for different combinations of digestion and detection methods. With the procedures prescribed by the new European standard (EN 15192) acceptable results were obtained for both soil samples and one of the waste samples (sludge). However, for the second waste sample (fly ash) a large deviation in analytical results was observed. This indicates that particularly for waste materials a possible occurrence of strong matrix effects has to be considered and supplementary quality control data are needed in order to assess the validity of analytical results. The accuracy of the determination of Cr(vi) in solid matrices remains a challenging field in terms of maximum extraction efficiency and minimum species interconversion.     

Source to sink tracking of selected human pharmaceuticals from two Oslo city hospitals and a wastewater treatment works

The occurrence of twenty pharmaceutical compounds was quantitatively determined in effluents from two major Oslo city hospitals, Rikshospitalet and Ullev?l, along with influent, sludge and final effluent from the city's VEAS wastewater treatment works (WTW). Composite hospital effluents were collected over a twelve week period and were showed to contain paracetamol, metoprolol, diclofenac, ibuprofen, 17beta-Estradiol, estriol, estrone, oxytetracycline, tetracycline, doxycycline, chlorotetracycline, demeclocycline, trimethoprim, ciprofloxacin, sulfamethoxazole, cyclophosphamide and ifosfamide. Three pharmaceuticals were not detected above the limit of detection; cefuroxime, 17alpha-ethinylestradiol and meclocycline. Composite influent, sludge and effluent samples were collected from VEAS WTW over a seven week period. The influent into VEAS WTW contained all of the same selected substances detected in the hospital effluents, except for oxytetracycline, chlorotetracycline, demeclocycline, cyclophosphamide and ifosfamide. The percentage of pharmaceuticals entering the works from the hospitals was <10% for all of the selected compounds. VEAS sludge samples contained a different profile of substances reflecting their physico-chemical properties. Hydrophobic antibiotics, such as oxytetracycline, tetracycline and ciprofloxacin, were detected in all of the collected sludge samples. Their absence in the collected influent samples suggests that they enter the works bound to effluent particles, with the dissolved fraction observed in the hospital effluents partitioning onto particulate matter within the sewerage network. The final effluent from VEAS WTW contained reduced concentrations of many pharmaceuticals, including paracetamol, ibuprofen and sulfamethoxazole. For other compounds, such as metoprolol, diclofenac and trimethoprim, there were often higher concentrations in the effluent than the influent. These effluent concentrations represent median inputs varying from low g day(-1) (e.g. paracetamol and ibuprofen) to nearly 200 g day(-1) (e.g. metoprolol and trimethoprim) into Oslofjord. A simple risk assessment showed that the antibiotic ciprofloxacin may at times pose an acute risk to the Oslofjord aquatic environment.     

Strategic planning for post-disaster temporary housing

Temporary housing programmes suffer from excessively high cost, late delivery, poor location, improper unit designs and other inherent issues. These issues can be attributed in part to a prevalence of ad hoc tactical planning, rather than pre-disaster strategic planning, for reconstruction undertaken by governments and non-governmental organisations (NGOs) in the chaotic post-disaster environment. An analysis of the process and outcomes from six case studies of temporary housing programmes after disasters in Turkey and Colombia in 1999, Japan in 1995, Greece in 1986, Mexico in 1985, and Italy in 1976 yields information about the extent to which strategic planning is employed in temporary housing programmes, as well as common issues in temporary housing. Based on an understanding of these common issues, this paper proposes a framework for strategic planning for temporary housing that identifies organisational designs and available resources for temporary housing before the disaster, but allows modifications to fit the specific post-disaster situation.     

Children and the Sphere standard on mental and social aspects of health

Most of the world's children live in resource-poor countries where people are at a relatively high risk of exposure to catastrophic situations arising from conflict and natural disasters.(6) Given the potential social, psychological and psychiatric consequences of exposure to disaster, mental health and psychosocial support programmes are increasingly part of humanitarian aid. A minimum standard on mental and social aspects of health is included in the recently revised Humanitarian Charter and Minimum Standards in Disaster Response (Sphere Handbook) (Sphere Project, 2004). Most recommendations for mental health and psychosocial interventions in guidance documents are based on expert opinion rather than research. Consequently, interventions are being implemented without full understanding of their potential benefit or harm. This paper offers a child-focused review of the evidence for each of the interventions described as indicators for the Sphere standard on mental and social aspects of health. It suggests some, but limited, support for each of them. However, the evidence base needs substantial strengthening.