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461.
A comparison of sediment quality guidelines for toxicity assessment in the Sunderban wetlands (Bay of Bengal, India) 总被引:3,自引:0,他引:3
Binelli A Sarkar SK Chatterjee M Riva C Parolini M Bhattacharya Bd Bhattacharya AK Satpathy KK 《Chemosphere》2008,73(7):1129-1137
The aim of this paper was to obtain the first screening ecotoxicological risk evaluation in the Sunderban wetlands, the largest prograding delta in the estuarine phase of the River Ganges. The characterization of exposure was conducted by means of an extensive survey of several persistent organic pollutants (PAHs, PCBs, DDTs, PBDEs, HCHs, HCB) measured in seven core sediments from the Sunderban wetlands, obtaining a dataset with more than 2200 analyses. The pollutant effects were assessed by the use of three different sediment quality guidelines (SQGs) previously developed in the literature to evaluate toxicity induced in sediment-dwelling organisms. The three different approaches chosen for risk assessment of the Sunderban were the consensus SQGs obtained by TEC (threshold effect concentration), PEC (probable effect concentration) and EEC (extreme effect concentration), the threshold/probable effect level (TEL/PEL) approach and, finally, the ERL-ERM guidelines, including the m-ERM-Q (mean ERM quotient). The evaluation of the toxicity induced by a mixture of the target pollutants indicated the importance of gamma-HCH contamination in the Sunderban sediments despite the very low concentrations measured in core sediments. A different sensitivity for toxicity assessment due to quality guidelines was obtained, as the consensus SQGs based on TEC were less conservative and protective than the TEL and ERL approaches, while the use of m-ERM-Q seems to be the most powerful tool to predict the toxicity related to a contaminant mixture. 相似文献
462.
This study focuses on the verification of test interpretations for different state analyses of diffusion experiments. Part 1 of this study identified that steady, quasi-steady and equilibrium state analyses for the through- and in-diffusion tests with solution reservoirs are generally feasible where the tracer is not highly sorptive. In Part 2 we investigate parameter identifiability in transient-state analysis of reservoir concentration variation using a numerical approach. For increased generality, the analytical models, objective functions and Jacobian matrix necessary for inverse analysis of transient-state data are reformulated using unified dimensionless parameters. In these dimensionless forms, the number of unknown parameters is reduced and a single dimensionless parameter represents the sorption property. The dimensionless objective functions are evaluated for individual test methods and parameter identifiability is discussed in relation to the sorption property. The effects of multiple minima and measurement error on parameter identifiability are also investigated. The main findings are that inverse problems for inlet and outlet reservoir concentration analyses are generally unstable and well-posed, respectively. Where the tracer is sorptive, the inverse problem for the inlet reservoir concentration analysis may have multiple minima. When insufficient measurement data is collected, multiple solutions may result and this should be taken into consideration when inversely analyzing data including that of inlet reservoir concentration. Verification of test interpretation by cross-checking different state analyses is feasible where the tracer is not highly sorptive. In an actual experiment, test interpretation validity is demonstrated through consistency between theory and practice for different state analyses. 相似文献
463.
Oliveira M Delgado L Ribeiro H Abreu I 《Journal of environmental monitoring : JEM》2010,12(5):1187-1194
Fungal spores are a significant fraction of the atmospheric bioparticles (bioaerosols) and many species are capable of inducing the production of specific immunoglobulin E (IgE), aggravating the clinical symptoms of allergic respiratory diseases in sensitized individuals. The aim of this work was to evaluate the distribution of potentially allergenic Pleosporales spores in two locations with different urbanization indexes, characterizing its seasonal pattern. The seasonal distribution of several spore types belonging to the Pleosporales (Alternaria, Drechslera, Epicoccum, Paraphaeosphaeria, Pithomyces, Pleospora and Stemphylium) in Amares (rural area) and Porto (urban area) was continually studied from January 2005 to December of 2007, using Hirst-type volumetric spore traps. Alternaria was the most abundant fungal spore type found in the atmosphere of Amares and Porto. This fungal type, together with Drechslera, Epicoccum, Pithomyces and Stemphylium, was mainly present during summer. Nevertheless, Leptosphaeria, Pleospora and Venturia spores were detected during winter and spring, while Paraphaeosphaeria spores were also observed during summer and autumn. These different seasonal patterns were responsible for the expansion of the exposure period for the Alt a 1 allergen. The concentration of the studied spore types was higher in the rural area than in the urban one, with exception for Pleospora and Drechslera. According to the correlations with meteorological factors, the selected fungal spores can be divided into two groups: (i) Alternaria, Drechslera, Epicoccum, Pithomyces and Stemphylium presented positive correlations with temperature and negative correlations with relative humidity and rainfall; (ii) Leptosphaeria, Paraphaeosphaeria, Pleospora and Venturia presented a contrary behavior. Usually, the occurrence of the Alt a 1 allergen has been associated with the presence of airborne Alternaria spores; the present work follows the seasonal distribution of other fungal spore species known to contain this molecule. The widespread occurrence of Alt a 1 plays an important role in the incidence and aggravation of allergic disorders. 相似文献
464.
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466.
Waliszewski SM Caba M Herrero-Mercado M Saldariaga-Noreña H Meza E Zepeda R Martínez-Valenzuela C Gómez Arroyo S Villalobos Pietrini R 《Environmental monitoring and assessment》2012,184(9):5613-5621
The objective of the present study was to monitor the levels of organochlorine pesticides HCB; α-, β-, γ-HCH; pp'DDE; op'DDT; and pp'DDT in blood serum of Veracruz, Mexico inhabitants. Organochlorine pesticides were analyzed in 150 blood serum samples that constituted that which remained after clinical analyses, using gas chromatography-electron-capture detection (GC-ECD). The results were expressed as milligrams per kilogram on fat basis and micrograms per liter on wet weight. Only the following pesticides were detected: p,p'-DDE was the major organochlorine component, detected in 100% of samples at mean 15.8 mg/kg and 8.4 μg/L; p,p'-DDT was presented in 41.3.% of monitored samples at mean 3.1 mg/kg and 1.4 μg/L; β-HCH was found in 48.6% of the samples at mean 4.9 mg/kg and 2.7 μg/L; op'DDT was determined to be in only 3.3% of monitored samples at mean 2.7 mg/kg and 1.4 μg/L. The pooled samples divided according to sex showed significant differences of β-HCH and pp'DDE concentrations in females. The samples grouped according to age presented the third tertile as more contaminated in both sexes, indicating age as a positively associated factor with serum organochlorine pesticide levels in Veracruz inhabitants. 相似文献
467.
Li YX Han W Yang M Feng CH Lu XF Zhang FS 《Environmental monitoring and assessment》2012,184(8):5035-5041
Concentrated animal feeding operations have been recognized as one of the most important contributors of natural estrogens which show significant endocrine-disrupting properties in aquatic environments. In this study, the concentrations of 17α-estradiol (17α-E2), 17β-estradiol (17β-E2), estrone (E1), and estriol (E3) in several matrices, including soils (surface and deep), sediments (surface and deep), and groundwaters, around a typical dairy farm were surveyed using gas chromatography/mass spectrometry. Of the two farmlands, surface and subsurface sediments in waste lagoon and along effluent drainage drench, the concentrations of 17α-E2, 17β-E2, and E1 ranged from below detection limit to the highest level of 6.60 μg/kg, except that E3 was not detectable. Three estrogens of 17α-E2, 17β-E2, and E1 with the concentrations of 3.18-31.61 ng/L were observed in two groundwater samples. The results clearly demonstrated the vertical migration and horizontal transport of estrogens in the investigated area. Within 750-m distance, it was observed the attenuation of 17α-E2, 17β-E2, and E1 along the effluent route and the horizontal migration of estrogens was less than 1,350 m in this survey. 相似文献
468.
Tahir MW Mumtaz MW Tauseef S Sajjad M Nazeer A Farheen N Iqbal M 《Environmental monitoring and assessment》2012,184(8):4879-4888
The present study describes the estimation of particulate matter (cotton dust) with different sizes, i.e., PM(1.0), PM(2.5), PM(4.0), and PM(10.0 μm) in small-scale weaving industry (power looms) situated in district Hafizabad, Punjab, Pakistan, and the assessment of health problems of workers associated with these pollutants. A significant difference was found in PM(1.0), PM(2.5), PM(4.0), and PM(10.0) with reference to nine different sampling stations with p values <0.05. Multiple comparisons of particulate matter with respect to size, i.e. PM(1.0), PM(2.5), PM(4.0), and PM(10.0), depict that PM(1.0) differs significantly from PM(2.5), PM(4.0), and PM(10.0), with p values <0.05 and that PM(2.5) differs significantly from PM(1.0) and PM(10.0), with p values <0.05, whereas PM(2.5) differs non-significantly from PM(4.0), with a p value >0.05 in defined sampling stations on an average basis. Majority of the workers were facing several diseases due to interaction with particulate matter (cotton dust) during working hours. Flue, cough, eye, and skin infections were the most common diseases among workers caused by particulate matter (cotton dust). 相似文献
469.
Kokorite I Klavins M Rodinov V Springe G 《Environmental monitoring and assessment》2012,184(8):4999-5008
This study revealed significant (P?0.1 and P?0.05) increasing trends of total organic carbon (TOC) and water colour in most of the studied Latvian rivers during the last decade. However, over longer time periods, there were pronounced oscillations of TOC concentrations, similar to patterns of long-term changes of river discharge regime. On a yearly basis, there was a positive correlation between parameters of organic matter concentration and discharge in all selected rivers (r (S)?=?0.540-0.803; P?0.01). The impact of discharge on concentrations of organic matter could be masked by other factors, such as changes in precipitation, biological processes, soil types or land use. 相似文献
470.
Mecozzi M Pietroletti M Scarpiniti M Acquistucci R Conti ME 《Environmental monitoring and assessment》2012,184(10):6025-6036
The aim of this study is to present and to discuss some characteristics of recalcitrant organic matter mechanism and formation. These aggregates called mucilages that are produced by the degradation reactions of several algae, have been investigated by infrared (FTIR) spectroscopy. FTIR spectra of macroaggregates produced by different algal samples have been daily collected in order to investigate the steps of aggregation. Afterwards, they have been elaborated by means of Independent Component Analysis (ICA). ICA investigation of FTIR spectra showed that the global aggregation process of marine mucilage always consisted of two different phases or independent components (ICs). One IC is related to the first degradation step of algal cells leading to the production of mono and oligosaccharides with aminoacids and oligopeptides. The second IC is related to the polymerization of oligosaccharides with aminoacids and oligopeptides and to their interaction with less polar compounds such as lipids thus producing supramolecular structures. The emerging mechanisms of anomalous size aggregates of organic matter match those of natural organic matter aggregation. The approach we suggest is to use synthetic mucilages which allows to monitor the macroaggregates formation because it can hardly be performed by means of natural marine macroaggregates. 相似文献