QUANTIFICATION OF ACTINIDE MIGRATION PATHWAYS AT ROCKY FLATS,COLORADO1

ABSTRACT: Migration of plutonium, americium, and uranium (actinides) in the environment at the Rocky Flats Environmental Technology Site (RFETS) is the subject of ongoing studies to develop effective strategies for cleanup and regulatory closure of the Department of Energy facility. The Actinide Migration Evaluation pathway analysis quantified actinide transport processes to validate a qualitative conceptual model of environmental actinide transport. Major actinide transport mechanisms evaluated include surface water, ground water, airborne, and biological pathways. Relative quantities of actinide movement via different pathways were compared in terms of actinide loads delivered off the RFETS, using a combination of monitoring data, predictive transport models and results from historic RFETS studies. Results indicate air and surface water constitute the dominant transport mechanisms for plutonium and americium. In ground water, shallow alluvial flow is a limited pathway for plutonium and americium because of the low aqueous solubility of these actinides and their tendency to sorb to soil. However, localized flow in shallow alluvium is a more significant pathway for uranium movement, because of the relatively higher solubility of uranium (VI) species, though isotopic ratios indicate much of the uranium is from natural sources. Biological transport of actinides by mammals, birds, fish, and arthropods is small compared to the other pathways.     

THE FRESHWATER STREAM,A COMPLEX ECOSYSTEM1

A stream is set apart from all other aquatic ecosystems in that the water is continually entering and leaving the stream and is in almost constant motion. Thus, there is essentially a unidirectional flow, a constant mixing of the watery medium, a continuous erosion of the substrate with concomitant changes in the characteristics of the stream bed, and little or no opportunity for the accumulation and retention of the dissolved nutrients. The physical and chemical characteristics of the stream are largely reflections of the physical and chemical makeup of the watershed. Because of the constant replacement of the water as it flows away, new nutrients must be brought into the stream continually in order to support the biotic communities. The kinds and amounts of nutrients that enter the stream determine, to a large extent, the numbers and kinds of organisms in the different communities. The organisms that comprise those communities may be categorized as representative species indigenous to springs, riffles, and pools. Most plants in streams are sessile whereas most of the animals are vagile, at least during some phase of their life cycle. All sessile organisms must depend on the current bringing their foodstuffs to them, but the vagile forms may seek out their foods in different parts of the stream and may even move from one community to another. Each community is adapted to its particular environment. Spring communities, because of the constancy of the physical and chemical environment, may reach what is essentially a “climax” situation and remain stable over long periods of time. Communities that occupy riffle and pool habitats may change from season to season and from year to year depending on changes in temperature, volume of flow, and the character of the substrate. Between each of these kinds of communities there are transitional areas that may be occupied by wider varieties of organisms than any of the three principal kinds of communities. In any event, the continuity of these communities in time and space is determined by the speed of the current which in turn depends upon the volume of flow. On this basis it becomes evident that the characteristics of the biotic communities are different at the source of a stream than at any other location. Similarly, riffle communities are different than those living in pools. The most difficult evaluation to be made in studying a stream ecosystem is that of the interlocking relationships among the many kinds of organisms. The plants, whatever kind they may be, fix carbon and other elements into organic compounds that can be utilized as food by the animals. The multitude of organisms that make up the bottom fauna of any stream are largely supported by the food formed directly by the plants. Such animals as small crustaceans, insect larvae, worms, turbellarians, mollusks, and the like serve as food for the carnivorous species. To determine the role of each organism in maintaining such a complex structure is a tremendous challenge. Many tools and methods are at the disposal of the biologist who dares to undertake such a project. Still, the greatest of all these is the dedication to spending long hours of tedious and, frequently, very hard work.     

Crisis Management to Controlled Recovery: The Emergency Planning Response to the Bombing of Manchester City Centre

Fuelled by terrorist attacks on urban areas, emergency planning responses to manmade disasters is a growing area of critical debate within the field of urban management. The response of a major British city--Manchester--to the 1996 bombing of its commercial core, is examined in this paper. It focuses on the transformation of the emergency planning response from dealing with the immediate crisis during the first week, to a stage of controlled recovery that still continues. The response to the devastation caused by the bomb was co-ordinated by the city council, which developed a range of short- and long-term initiatives, but the re-opening of the city centre could not have happened so quickly had the council not worked in collaboration with other key organisations and agencies. Working partnerships were crucial to the immediate response and subsequent recovery, with such capacity for organisational learning built upon existing co-operative arrangements within the city, which had developed over the previous decade.     

The WHO/UNEP Pilot Project on Assessment of Human Exposure to Pollutants through Biological Monitoring

The objectives, development and current status of the WHO/UNEP Pilot Project on Assessment of Human Exposure to Pollutants through Biological Monitoring are described. The project is being carried out within the framework of UNEP's Global Environmental Monitoring System (GEMS) and is supported by funds from UNEP. The long-term objective is to develop and strengthen national, regional and global biological monitoring programmes that will make it possible to accurately assess human exposure to selected toxic pollutants by measuring their concentrations in human tissues and body fluids. In this pilot project the levels of lead and cadmium in venous blood, cadmium in kidney cortex and certain organochlorine compounds in breast milk are being determined in selected population groups in 10–12 countries in different parts of the world. Each participating laboratory has been required to achieve satisfactory results in the quality assurance phase of the project before starting to analyse the human samples and quality assurance has been continued during the monitoring phase. The project started in 1978 and is scheduled for completion by July 1982.     

Diffusive uptake in passive and active adsorbent sampling using thermal desorption tubes

Low flow active sampling techniques collecting vapors and gases using thermally desorbable adsorbents are now feasible and desirable in many applications as they permit long integration times, the potential for miniaturized sampling configurations, and other advantages. At very low air flow rates (< 1 ml min(-1)), diffusive uptake on adsorbents in conventional sorbent tubes may equal or exceed the active (pumped) uptake rate, and even at low flow rates (1-4 ml min(-1)), diffusive uptake may significantly bias measurements. Thus, corrections to account for the diffusive flux or means to limit the diffusive uptake are needed in low flow applications. This paper presents (1) a theoretical analysis of the role of diffusive and advective uptake for several sampling geometries of tube-type samplers; (2) experimental confirmation using both laboratory and field studies; (3) estimates of the tortuosity and porosity of the glass wool packing used to retain the adsorbent, parameters needed to estimate diffusive fluxes in passive and active sampling; (4) a demonstration that orifice-equipped low flow active samplers can reduce diffusive uptake and improve precision, and (5) a model predicting the saturated adsorbent layer that helps to account for the gradual decline in uptake rates seen in passive sampling. Diffusive uptake will depend on the tube configuration and diffusion coefficient of the substance of interest, but for conventional sampling tubes (0.4-0.5 cm id, 1.5 cm air gap), sample flow rates should be maintained above 1 to 4 ml min(-1) to keep errors below 5%. Laboratory experiments showed close agreement with theoretical calculations, and the field study using 1 to 4 d sampling periods and 0.3 ml min(-1) flows demonstrated that the orifice-equipped samplers essentially eliminated diffusive uptake. No significant practical difficulties are encountered using orifices, e.g., pressure drop is minimal. Experimental estimates of tortuosity (0.79 +/- 0.02) and porosity (0.92 +/- 0.10) of the glass wool packing (0.3 cm length) represent relatively little resistance to diffusion; however, variation in the packing and adsorbent placement can degrade the precision achievable by passive samplers. Diffusion barriers, consisting most simply of an orifice, may be used to lower the diffusive uptake. A needle-type orifice permits flows below 0.1 ml min(-1) and is suitable for sampling periods as long as several weeks, and it provided greater precision than conventional open-ended sampling tubes (8% compared to 13%). Finally, the gradual decrease in diffusive fluxes often seen in passive sampling is attributed to additional resistance posed by a saturated adsorbent layer, in agreement with a simple model based on total VOCs and specific adsorptivity of the adsorbent.     

A Landscape Approach for Detecting and Evaluating Change in a Semi-Arid Environment

Vegetation change in the American West has been a subject of concern throughout the twentieth century. Although many of the changes have been recorded qualitatively through the use of comparative photography and historical reports, little quantitative information has been available on the regional or watershed scale. It is currently possible to measure change over large areas and determine trends in ecological and hydrological condition using advanced space-based technologies. Specifically, this process is being tested in a community-based watershed in southeast Arizona and northeast Sonora, Mexico using a system of landscape pattern measurements derived from satellite remote sensing, spatial statistics, process modeling, and geographic information systems technology. These technologies provide the basis for developing landscape composition and pattern indicators as sensitive measures of large-scale environmental change and thus may provide an effective and economical method for evaluating watershed condition related to disturbance from human and natural stresses. The project utilizes the database from the North American Landscape Characterization (NALC) project which incorporates triplicate Landsat Multi-Spectral Scanner (MSS) imagery from the early 1970s, mid 1980s, and the 1990s. Landscape composition and pattern metrics have been generated from digital land cover maps derived from the NALC images and compared across a nearly 20-year period. Results about changes in land cover for the study period indicate that extensive, highly connected grassland and desertscrub areas are the most vulnerable ecosystems to fragmentation and actual loss due to encroachment of xerophytic mesquite woodland. In the study period, grasslands and desertscrub not only decreased in extent but also became more fragmented. That is, the number of grassland and desertscrub patches increased and their average patch sizes decreased. In stark contrast, the mesquite woodland patches increased in size, number, and connectivity. These changes have important impact for the hydrology of the region, since the energy and water balance characteristics for these cover types are significantly different. The process demonstrates a simple procedure to document changes and determine ecosystem vulnerabilities through the use of change detection and indicator development, especially in regard to traditional degradation processes that have occurred throughout the western rangelands involving changes of vegetative cover and acceleration of water and wind erosion.     

A New Framework for the Assessment of Animal Welfare: Integrating Existing Knowledge from a Practical Ethics Perspective

When making an assessment of animal welfare, it is important to take environmental (housing) or animal-based parameters into account. An alternative approach is to focus on the behavior and appearance of the animal, without making actual measurements or quantifying this. None of these tell the whole story. In this paper, we suggest that it is possible to find common ground between these (seemingly) diametrically opposed positions and argue that this may be the way to deal with the complexity of animal welfare. The model will have to be acceptable for the different parties that will be affected by it and real benefits for the animal should result from it. This will be the basis of a practical ethical approach. All this can be condensed into a model that essentially is made up out of three basic elements: the classical welfare analysis with an existing welfare assessment tool, an assessment of the stockholder, and an implementation of the Free Choice Profiling technique. This new framework does not pretend to be a different or better animal welfare matrix; it is intended to integrate existing knowledge and to provide a practical tool to improve animal welfare. It identifies whether there are welfare problems on a farm, if present whether these problems are caused by the housing system or the stockholder, and what can be done to improve the situation.     

Beliefs about ‘improvability’ of career‐relevant skills: relevance to job/task analysis,competency modelling,and learning orientation

Based on data obtained from three samples of participants from both a work organization and a college setting, this paper addressed two major research objectives relevant to organizational behavior and applied psychology. First, we wanted to explore the nature of implicit theory of skill malleability in more detail than has been done before. This was done by drawing on KSAO dimensions from the task/job analysis literature, and examining linkages among: (a) task/job analysis; (b) implicit theories; and (c) competency modelling (an area in which there has been little empirical research). The studies found multiple factors of beliefs about KSAO improvability and showed a clear ordering of improvability beliefs (from most to least improvable) that follow predictions made in the Iceberg model of competencies. The present studies also found relationships between perceptions of KSAO importance and KSAO improvability, as well as evidence that this relationship is stronger for people who have been in a role/job longer, having had greater opportunity to observe critical KSAOs improve over time. A second major objective of the research was to explore improvability beliefs within a nomological network that would help to further establish the construct validity of the beliefs within the learning/development area. Using structural modelling, the improvability beliefs were tied to learning‐oriented concepts including self‐efficacy for learning and development, tendency to compare oneself to others when learning, as well as learning‐oriented attitudes and behaviors. The potential practical value of improvability beliefs is discussed, as are suggestions for future research. Copyright © 2003 John Wiley & Sons, Ltd.