Prediction of soil organic partition coefficients by a soil leaching column chromatographic method

The soil organic partition coefficient (Koc) is one of the most important parameters to depict the transfer and fate of a chemical in the soil-water system. Predicting Koc by using a chromatographic technique has been developing into a convenient and low-cost method. In this paper, a soil leaching column chromatograpy (SLCC) method employing the soil column packed with reference soil GSE 17201 (obtained from Bayer Landwirtschaftszentrum, Monheim, Germany) and methanol-water eluents was developed to predict the Koc of hydrophobic organic chemicals (HOCs), over a log Koc range of 4.8 orders of magnitude, from their capacity factors. The capacity factor with water as an eluent (k'w) could be obtained by linearly extrapolating capacity factors in methanol-water eluents (k'w) with various volume fractions of methanol (symbol in text). The important effects of solute activity coefficients in water on k'w and Koc were illustrated. Hence, the correlation between log Koc and log k'w (and log k') exists in the soil. The correlation coefficient (r) of the log Koc vs. log k'w correlation for 58 apolar and polar compounds could reach 0.987, while the correlation coefficients of the log Koc -log k' correlations were no less than 0.968, with (symbol in text)ranging from 0 to 0.50. The smaller the (symbol in text), the higher the r. Therefore, it is recommended that the eluent of smaller (symbol in text), such as water, be used for accurately estimating Koc. Correspondingly, the r value of the log Koc -log k'w correlation on a reversed-phase Hypersil ODS (Thermo Hypersil, Kleinostheim, Germany) column was less than 0.940 for the same solutes. The SLCC method could provide a more reliable route to predict Koc indirectly from a correlation with k'w than the reversed-phase liquid chromatographic (RPLC) one.     

甲醇溶液中多氯联苯的微波降解

采用微波降解多氯联苯，对影响多氯联苯降解率的反应温度、反应时间、搅拌方式、试剂加入量等因素进行了考察和优化，结果表明：在反应温度为50℃、反应时间为10min、充分搅拌的条件下，溶液中多氯联苯的降解率可达99．999％。经初步分析确定，多氯联苯的降解产物为无毒的烃类、碳、氯离子和水等物质。     

城市小康社会安全指标体系设计

城市安全是我国小康社会安全的关键和重要组成部分 ,科学地设计城市小康社会的安全指标体系 ,对于定量地分析和认识城市安全的状况 ,科学地评价安全的社会价值有着现实的意义。笔者首先提出了安全小康社会的概念及其发展目标的体系和原则 ;然后结合我国的政府管理部门需要 ,定义了城市安全的 12大领域 ,并设计了指标体系 ,包括社会稳定、社会治安、公共场所安全、公共卫生、交通安全、生产安全、食品安全、减灾防灾、人口安全、环境安全、能源安全及宏观综合。每个具体指标都是在研究该安全领域具体现状的基础上 ,经过分析影响其安全状况的重要因素设计而成的。城市小康社会安全指标体系能够应用于评价城市的总体安全状况。     

Elutriation characteristics of fine particles from bubbling fluidized bed incineration for sludge cake treatment

In this study, measurements of elutriation rate were carried out in a bench scale bubbling fluidized bed incinerator, which was used to combust sludge cake. The particle size distribution and ignition loss were analyzed to study the elutriation characteristics of bubbling fluidized bed incineration. Drawn from the experimental data, the elutriation rate constant K(i)* for fine particles were obtained and correlated with parameters. It was found that most of the solid particles (about 95%) elutriated came from the fluidized medium (inorganic matters), but few came from unburned carbon particles or soot (about 5%). Finally, this paper lists a comparison of K(i)* between this study and the published prediction equations derived or studied in non-incineration modes of fluidized bed. A new and modified correlation is proposed here to estimate the elutriation rate of fine particles emitted from a bubbling fluidized bed incinerator. Primary operation variables (superficial gas velocity and incineration temperature) affecting the elutriation rate are also discussed in the paper.     

中青年人群对于地铁站疏散标识的决策行为模拟分析

目的是模拟分析地铁火灾时不同行为特点中青年人群对疏散标识的决策反应。方法采用构建地铁站台火灾时烟气蔓延的三维空间模型,在中青年人群中进行应急疏散的仿真实验,利用统计分析软件SPSSv14.0对采集到的数据进行统计分析。结果得到性别、成长环境和专业背景等不同人员行为特点与疏散标识决策反应的相关性,并对疏散标识的字体、图案特性进行选优。得出结论,性别、成长环境和专业背景与人员对不同疏散标识的决策反应有一定的相关性。图形为主要设计元素的疏散标识是地铁站台火灾烟气条件下疏散人员的优先选择。     

贵州近期的滑坡活动及防治对策

贵州是一个生态环境脆弱、滑坡灾害频繁的山区省份。在调查分析２３７个典型滑坡的基础上，阐述了贵州近期滑坡活动的主要类型、特征及分布规律，探讨了滑坡的形成条件和机理。指出人为工程活动和降雨条件是诱发贵州近期滑坡活动的主要因子，并据此提出了相应的防治对策。     

农村生态环境分区的数量化方法─—以鞍山市为例

运用聚类分析和地理信息系统相结合的方法，选择了１８个指标和７８个分区单元，将鞍山市农村生态环境划分成８个区，作出分布图，并分别给出了各分区的主要特征。     

新生二氧化锰吸附法去除水中直接大红染料

研究了影响新生MnO2对直接大红4B染料废水脱附脱色的有关因素，结果表明，pH是影响脱色效果的关键因素，吸附脱色存在佳化pH范围，其上限随染料浓度的提高和MnO2投加量的增加而增大。投加0．3g/L的MnO2可使染料废水的脱色率达到98．2％，升高温度可提高脱色率。     

2001年农作物病虫害发生流行的气候影响评价

综合分析了 2001年气候条件对全国农作物病虫害发生流行的影响.春夏季全国大范围的持续严重高温干旱,造成全国农作物病虫害偏重发生,其特点是虫害重于病害,全国大部分地区以虫害为主,病害较轻.春夏季的高温干旱引发蝗虫全国大发生,但制约了小麦病虫害的严重发生,为中等发生年.全国主要稻区病虫害发生期间干旱、少雨、大雨频次低,限制了水稻病虫害的严重发生,为中等发生年.水稻稻飞虱中等偏轻发生,但造成长江流域水稻螟虫的中等偏重发生.东北、华北地区中后期温度降水配合相对适宜,造成玉米螟中等偏重发生.     

强震前后短期内的异常天气及灾害叠加

列叙了部分强震前后短期的异常气象情况，探讨了其与强震间的机理，并结合１９７６年松潘７．２有地震波及汉中地区引起的破坏，讨论了异常天气带来的灾害叠加问题，对编制防震减灾规划和地震短临前兆探索，无疑是有益的。