The cement-based solidification/stabilization (S/S) of nitrobenzene (NB) contaminated soils, with cement and lime as binders, sodium silicate solution and powder activated carbon (PAC) as additives, was optimized through an orthogonal experiment, and S/S efficiency was estimated by both leaching test and volatilization measurement. The leaching test results showed that the factors affecting S/S efficiency were NB concentration, cement-to-lime ratio and binder-to-soils ratio, in sequence. With increasing curing time, the leaching concentration of NB between different levels of the same factor in the orthogonal experiment decreased, and less than 9% NB leached out from the 28 d cured samples. The volatilization measurement results indicated that 0.5‰ of NB was volatilized during the mixing and curing processes for the samples without PAC in the 28 d cycle, whereas adding 2 wt% and 5 wt% PAC, with respect to the weight of contaminated soils, could reduce NB volatilization to half of its original values either during the mixing or curing process. The optimizing formula, that is, contaminated soils (dry weight):cement:lime= 100:25:25, with 5 wt% additional sodium silicate and 2 wt% additional PAC, was applied to the engineering application of NB contaminated soils. Both the leaching test results of the product and the ambient air quality monitoring results met related regulations during the treating process. 相似文献
This paper is concerned with the evaluation of cyclic hardening models within the stress–strain behavior of aluminum alloy AC4C-T6 that can be used to LNG cargo pump operating in cryogenic temperature. To insure the strength assessment of LNG cargo pump, material model of cyclic hardening and plasticity for aluminum alloy AC4C-T6 is investigated through FEA (Finite Element Analysis) with various hardening options including linear and non-linear hardening, isotropic and kinematic hardening, and combined hardening model. Monotonic tensile and cyclic tensile experiments for AC4C-T6 alloy were performed at room temperature and temperature of ?165 °C. Parameters of each hardening model are obtained from the experimental data; thus five hardening models are numerically simulated thereafter. Appropriate hardening models which describe the cyclic stress–strain relationship are investigated through the simulations of cyclic hardening behavior by FEA. In order to verify the predicted behavior of cyclic hardening obtained by FEA, the results of FEA and those measured by experiments are compared. 相似文献
Construction and demolition debris (CDD) fines, a residue generated from mechanized CDD recycling, can often be beneficially reused. Concentrations of chemicals of potential concern in CDD fines should be evaluated prior to being reintroduced into the environment to assess risk and make informed decisions about appropriate reuse opportunities. The distribution of trace chemicals in CDD fines as a function of particle size was measured to evaluate if concentrations in the bulk material can be reduced by removing certain particle size ranges through screening. Chemicals of potential concern, including arsenic, lead, sulfate and polycyclic aromatic hydrocarbons (PAH), were characterized in four different size fractions (19–4.8 mm, 4.8–0.84 mm, 0.84–0.3 mm, < 0.3 mm) of CDD fine samples collected from 12 US CDD recycling facilities throughout the US. Results revealed that aluminum, arsenic and chromium concentrations were distributed evenly throughout all four size fractions. As for the remaining chemicals, most samples had lower concentrations in the 19–4.8 mm size range. In some samples and for certain chemicals, removal of the finer size fractions reduced overall concentrations in CDD fines, suggesting that additional processing may be worth further investigation. 相似文献
Objective: We studied the changes in driving fatigue levels of experienced and inexperienced drivers at 3 periods of the day: 9:00 a.m.–12:00 p.m., 12:00 p.m.–2:00 p.m., and 4:00 p.m.–6:00 p.m.Methods: Thirty drivers were involved in 120-min real-car driving, and sleepiness ratings (Stanford Sleepiness Scale, SSS; Hoddes et al. 1973Hoddes E, Zarcone V, Smythe H, Phillips R, Dement WC. Quantification of sleepiness: a new approach. Psychophysiology. 1973;10:431–436.[Crossref], [PubMed], [Web of Science ®], [Google Scholar]), electroencephalogram (EEG) signals, and heart rates (HRs) were recorded. Together with principal component analysis, the relationship between EEG signals and HR was explored and used to determine a comprehensive indicator of driving fatigue. Then the comprehensive indicator was assessed via paired t test.Results: Experienced and inexperienced drivers behaved significantly differently in terms of subjective fatigue during preliminary trials. At the beginning of trials and after termination, subjective fatigue level was aggravated with prolonged continuous driving. Moreover, we discussed the changing rules of EEG signals and HR and found that with prolonged time, the ratios of δ and β waves significantly declined, whereas that of the θ wave significantly rose. The ratio of (α + θ)/β significantly rose both before trials and after termination, but HR dropped significantly. However, one-factor analysis of variance shows that driving experience significantly affects the θ wave, (α + θ)/β ratio, and HR.Conclusions: We found that in a monotonous road environment, fatigue symptoms occurred in inexperienced drivers and experienced drivers after about 60 and 80 min of continuous driving, respectively. Therefore, as for drivers with different experiences, restriction on continuous driving time would avoid fatigued driving and thereby eliminate traffic accidents. We find that the comprehensive indicator changes significantly with fatigue level. The integration of different indicators improves the recognition accuracy of different driving fatigue levels. 相似文献
Material flow analysis (MFA) is an effective tool for waste management, but low- and middle-income countries lack essential data for MFA. This study proposed a simplified MFA (sMFA) utilizing local expert judgment (LEJ) and examining the impact of simplification on its uncertainty. A stochastic sMFA model was developed for nitrogen and phosphorus in urban Mandalay, Myanmar. This model was compared with the intensive MFA (iMFA) model employing intensive surveys for primary data collection. For the total loadings to the environment, the medians of the sMFA were higher by 3% and 11%, respectively, for nitrogen and phosphorus than those of the iMFA. The widths of the 80% confidence intervals of these loadings in the sMFA, normalized by those in the iMFA, were − 0.05 and − 0.11, respectively. The three largest flows to the environment were the same for the two models: on-site sanitation effluent/leakage, greywater, and industrial wastewater. Large median gaps between the models were observed for industrial wastewater, fecal sludge, and human excreta, associated with informal waste management, whereby LEJ did not work well. Overall, the sMFA demonstrated a good estimation of nitrogen and phosphorus flows with limited increase of uncertainty, still requiring focused attention on informal waste streams.
The potential benefits of nanoscale zero-valent iron (nZVI) on sludge stabilization, either the abatement of odor or the improvement of biogas production, were investigated in this study. Two commercial-grade microscale iron powders were also utilized for comparison. Adding 0.10 wt% of nZVI in sludge during anaerobic incubation significantly reduced the concentration of H2S in biogas by 98.0 % (96.2–98.9 %), probably attributed by reactions between sulfides and the neo-formed hydrous Fe(II)/Fe(III) oxides layer at the surface of ZVI nanoparticles. Meanwhile, the percentage of P in bioavailable fractions decreased from 76.8 to 52.5 %, possibly due to the formation of vivianite [Fe3(PO4)2]. Furthermore, 0.10 wt% of nZVI in anaerobic digestion for 17 days enhanced the concentration of CH4 in biogas by 5.1–13.2 % and improved the production of biogas and methane by 30.4 and 40.4 %, respectively. The amendment of iron nanoparticles during anaerobic digestion can not only effectively reduce H2S in biogas, but also potentially boost methane production significantly. 相似文献