Phosphorus-doped graphene supported palladium (Pd/PG) electrocatalyst for the hydrogen evolution reaction in PEM water electrolysis

PEM water electrolysis is one of the most efficient methods for the production of hydrogen because of produced high purity of the gases and environmentally friendly. In the present study, Phosphorus-doped Graphene (PG) was synthesized by thermal annealing of triphenylphosphine (TPP) and graphene oxide (GO). The PG supported palladium (Pd/PG) electrocatalysts were synthesized by chemical reduction method and used as the cathode for hydrogen evolution reaction (HER) electrode. Structural properties and electrochemical performances of the synthesized Pd/PG electrocatalyst were studied by FE-SEM, EDS, ICP, FT-IR, XRD, and Cyclic voltammetry (CV) methods, respectively. The membrane electrode assemblies (MEA’s) were fabricated using Pd/PG as cathode for HER electrode and RuO₂ as anode for OER electrode. Also, their electrochemical performances along with the corresponding hydrogen yields were evaluated in single cell PEM water electrolyzer at various experimental conditions such as different current densities from 0.1 to 2.0 A cm^?2 and temperatures (28–80°C). The synthesized Pd/PG electrocatalyst was observed a current density of 1 A cm^?2 with 1.95 V at 80°C. Further, long-term stability studies were carried out continuously up to 2000 h which showed a reasonable stability. Hence, the synthesized Pd/PG can be used as an alternative to Pt-based electrocatalysts for the HER in PEM water electrolysis.     

Assessment of biomass and lipid productivity and biodiesel quality of an indigenous microalga Chlorella sorokiniana MIC-G5

Generation of biodiesel from microalgae has been extensively investigated; however, its quality is often not suitable for use as fuel. Our investigation involved the evaluation of biodiesel quality using a native isolate Chlorella sorokiniana MIC-G5, as specified by American Society for Testing and Materials (ASTM), after transesterification of lipids with methanol, in the presence of sodium methoxide. Total quantity of lipids extracted from dry biomass, of approximately 410–450 mg g^?1 was characterized using FTIR and ¹H NMR. After transesterification, the total saturated and unsaturated fatty acid methyl esters (FAMEs) were 43% and 57%, respectively. The major FAMEs present in the biodiesel were methyl palmitate (C16:0), methyl oleate (C18:1), and methyl linoleate (C18:2), and the ¹H NMR spectra matched with criteria prescribed for high-quality biodiesel. The biodiesel exhibited a density of 0.873 g cm^–3, viscosity of 3.418 mm² s^?1, cetane number (CN) of 57.85, high heating value (HHV) of 40.25, iodine value of 71.823 g I₂ 100 g^?1, degree of unsaturation (DU) of 58%, and a cold filter plugging point (CFPP) of –5.22°C. Critical fuel parameters, including oxidation stability, CN, HHV, iodine value, flash point, cloud point, pour point, density, and viscosity were in accordance with the methyl ester composition and structural configuration. Hence, C. sorokiniana can be a promising feedstock for biodiesel generation.     

Microbial population dynamics under fertigation by distillery effluent in sugarcane-ratoon cropping system

Distillery effluents, a major by-product of distilleries are a major environmental hazard as they are rich in organic matter, micro- and macroelements. Management of this enormous amount of nutrient-rich effluent and its effective utilization is a major challenge. These effluents can be used as a source of nutrient by C₄ crops like sugarcane and subsequent ratoon crops under fertigation system. Impact of fertigation in sugarcane-ratoon cropping system on soil microbial biomass is important as the microbial population plays an important role in the nutrient and biogeochemical recycling. Keeping this in mind, a field experiment was carried out in the sandy loam soil of semi-arid to humid sub-tropical climate of Gajraula (28.85°N, 78.23°E) region, India with different doses of diluted and undiluted effluent for fertigation of sugarcane crop in presence and absence of 50 % recommended dose of fertilizers with suitable replicates. Two post-sown irrigations with four times diluted effluent gave the maximum yield in case of sugarcane crop. Taking into consideration the yield and the culturable microbial population sizes, it can be concluded that one to two post-sown irrigations with diluted effluent can be used to enhance soil fertility in terms of microbial population and to enhance sugarcane and ratoon crop productivity. This package is economically viable and can also take care of distillery waste management and reduction in consumption of chemical fertilizers by 50 %, a key for sustainable agricultural development.     

Nanosensors for food quality and safety assessment

Food toxins are produced as defense tools by microorganisms that use nutrients for their growth. Microorganisms thus spoil food, taste and can infect humans, sometimes leading to death. Food adulteration and brand protection are also major issues in the food industry. Here we review the use of nanomaterials for sensing food quality. Nanosensors can detect pathogenic bacteria, food-contaminating toxins, adulterant, vitamins, dyes, fertilizers, pesticides, taste and smell. Food freshness can be monitored using time–temperature and oxygen indicators. Product authenticity and brand protection can be assessed using invisible nanobarcodes. Overall, nanosensors with unique properties are improving food security.     

Growth and metal removal potential of a Phormidium bigranulatum-dominated mat following long-term exposure to elevated levels of copper

The present study explores the tolerance and metal removal response of a well-developed 2-week-old Phormidium mat after long-term exposure to Cu²⁺-enriched medium. Cu²⁺ enrichment inhibited increase in mat biomass in a concentration-dependent manner. Mat area and the number of entrapped air bubbles decreased as Cu²⁺ concentration increased in the medium. Decrease in number of air bubbles obviously reflects the adverse effect of Cu²⁺ on photosynthetic performance of the mat. Metal enrichment did not substantially alter the amount of pigments, such as chlorophyll a, chlorophyll b, carotenoids, and phycocyanin, in the mat. Enhancement of Cu²⁺ concentration in the medium led to changes in species composition of the test mat; however, Phormidium bigranulatum always remained the dominant organism. Relative share of green algae and some cyanobacterial taxa, namely, Lyngbya sp. and Oscillatoria tenuis, in the mat were increased by Cu²⁺ enrichment. The mat successfully removed 80 to 94 % Cu²⁺ from the growth medium containing 10 to 100 μM Cu²⁺. Extracellular polysaccharides, whose share increased in the mat community after metal addition, seem to have contributed substantially to metal binding by the mat biomass.     

In vivo and in vitro control activity of plant essential oils against three strains of Aspergillus niger

Environmental Science and Pollution Research - Contamination of environment and food from the prevalent spores and mycotoxins of Aspergillus niger has led to several diseases in humans and other...     

Impacts of microwave pretreatments on the semi-continuous anaerobic digestion of dairy waste activated sludge

Microwave (MW) irradiation is one of the new and possible methods used for pretreating the sludge. Following its use in different fields, this MW irradiation method has proved to be more appropriate in the field of environmental research. In this paper, we focused on the effects of MW irradiation at different intensities on solubilization, biodegradation and anaerobic digestion of sludge from the dairy sludge. The changes in the soluble fractions of the organic matter, the biogas yield, the methane content in the biogas were used as control parameters for evaluating the efficiency of the MW pretreatment. Additionally, the energetic efficiency was also examined. In terms of an energetic aspect, the most economical pretreatment of sludge was at 70% intensity for 12 min irradiation time. At this, COD solubilization, SS reduction and biogas production were found to be 18.6%, 14% and 35% higher than the control, respectively. Not only the increase in biogas production was investigated, excluding protein and carbohydrate hydrolysis was also performed successfully by this microwave pretreatment even at low irradiation energy input. Also, experiments were carried out in semi continuous anaerobic digesters, with 3.5 L working volume. Combining microwave pretreatment with anaerobic digestion led to 67%, 64% and 57% of SS reduction, VS reduction and biogas production higher than the control, respectively.