首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   154篇
  免费   49篇
  国内免费   9篇
安全科学   8篇
废物处理   5篇
环保管理   8篇
综合类   94篇
基础理论   40篇
污染及防治   43篇
评价与监测   5篇
社会与环境   5篇
灾害及防治   4篇
  2024年   4篇
  2023年   6篇
  2022年   5篇
  2021年   7篇
  2020年   4篇
  2019年   2篇
  2018年   2篇
  2017年   7篇
  2016年   15篇
  2015年   10篇
  2014年   14篇
  2013年   11篇
  2012年   15篇
  2011年   14篇
  2010年   11篇
  2009年   14篇
  2008年   15篇
  2007年   10篇
  2006年   5篇
  2005年   3篇
  2004年   2篇
  2003年   5篇
  2002年   7篇
  2001年   3篇
  2000年   2篇
  1999年   6篇
  1998年   3篇
  1997年   2篇
  1996年   4篇
  1995年   1篇
  1993年   1篇
  1992年   1篇
  1991年   1篇
排序方式: 共有212条查询结果,搜索用时 0 毫秒
31.
  总被引:1,自引:0,他引:1       下载免费PDF全文
Titanium dioxide(TiO2), which is the widely used photo-catalyst, has been synthesized by simple hydrothermal solution containing tetrabutyl titanate and hydrofluoric acid. The synthesized product has been applied to photo-degradation in aqueous phase of chlorinated solvents, namely tetrachloroethene(PCE), trichloroethene(TCE) and 1,1,1-trichloroethane(TCA). The photo-degradation results revealed that the degradation of these harmful chemicals was better in UV/synthesized TiO2 system compared to UV/commercial P25 system and UV only system. The photo-catalytic efficiency of the synthesized TiO2 was 1.4, 1.8 and 3.0 folds higher compared to the commercial P25 for TCA, TCE and PCE degradation, respectively. Moreover, using nitrobenzene(NB) as a probe of hydroxyl radical(.OH), the degradation rate was better over UV/synthesized TiO2, suggesting the high concentration of.OH generated in UV/synthesized TiO2system. In addition,.OH concentration was confirmed by the strong peak displayed in EPR analysis over UV/synthesized TiO2system. The characterization result using XRD and TEM showed that the synthesized TiO2 was in anatase form and consisted of well-defined sheet-shaped structures having a rectangular outline with a thickness of 4 nm, side length of 50 nm and width of 33 nm and a surface 90.3 m2/g. XPS analysis revealed that ≡Ti-F bond was formed on the surface of the synthesized TiO2. The above results on both photocatalytic activity and the surface analysis demonstrated the good applicability of the synthesized TiO2 nano-sheets for the remediation of chlorinated solvent contaminated groundwater.  相似文献   
32.
通过对目前国内外针对湖泊富营养化的恢复技术的分析,提出水体富营养化生态修复技术存在的问题,提出了水体富营养化生态修复的设想.  相似文献   
33.
In this study, ultrasound was used to control the membrane fouling online in an anaerobic membrane bioreactor (AMBR). Short-term running experiments were carried out under different operating conditions to explore feasible ultrasonic parameters. The experimental results indicated that when the crossflow velocity was more than 1.0 m/s, membrane fouling could be controlled effectively only by hydrodynamic methods without ultrasound. When ultrasound was applied, an ultrasonic power range of 60–150 W was suitable for the membrane fouling control in the experimental system. The experimental results showed that the membrane fouling was controlled so well that membrane filtration resistance (ΣR) could stay at 5 × 1011 m−1 for more than a week with the crossflow velocity of 0.75 m/s, which equaled the effect of crossflow velocity of more than 1.0 m/s without ultrasound. Translated from Techniques and Equipment for Environmental Pollution Control, 2006, 7(4): 25–29 [译自: 环境污染治理技术与设备]  相似文献   
34.
冰对斜体结构作用的二维和三维力学模型分析   总被引:3,自引:0,他引:3  
通常情况下,作用在斜体结构表面的冰力小于垂直结构,因此斜体结构成为有冰海区海洋结构的优选结构,冰对斜体结构作用力学机制的分析是近些年来国际上研究的热点问题。本文运用简单的二维理论及较为复杂的三维理论,依据辽东湾环境条件,采用计算与作图分析的手段,对摩擦系数、坡角、冰强度及冰厚如何影响作用在斜体结构上的水平冰力进行了讨论,并验证了相应结论  相似文献   
35.
从城市的结构和功能出发,提出推广生态建筑,提倡生态工艺,搞好城乡生态和加强宏观调控的城市可持续发展策略,为人们科学认识现代城市的发展趋势提供新思路。  相似文献   
36.
介绍了美国、德国、日本等国的渗滤液排放标准,并与中国现行的<生活垃圾填埋污染控制标准>(GB16889-1997)中的渗滤液排放标准相比较,指出了其存在的排放标准统一化、限值过于严格、控制项目不足等问题,并针对这些问题提出了相关的建议.  相似文献   
37.
基于化学计量学与生物力能学确定生化反应的理论反应式,结合multiplicative Monod及non-competitive Monod方程,建立了反硝化耦合甲烷化的数学模型。以乙酸钠为电子供体,厌氧颗粒污泥为接种污泥,通过间歇实验获取模型的相关参数。结果表明:该模型能较好地分析反硝化耦合甲烷化过程底物降解、竞争规律及反硝化中间产物对甲烷化的抑制作用;预测气体的累积产气量及各菌群生物量变化。参数灵敏度分析表明:甲烷化、硝酸盐还原和亚硝酸盐过程的灵敏度因子分别为km,a、km,NO3和km,NO2,这证实最大比底物利用速率对底物降解过程影响最显著,其值分别为km,a=0.098 h-1,km,NO3=0.0824 h-1和km,NO2=0.0695 h-1。  相似文献   
38.
苏云  邵萍  眭国荣  沈树宝  祝社民 《环境工程》2012,30(4):73-75,52
结合玻璃熔窑烟气排放的特点,阐述了国内外玻璃熔窑烟气脱硝技术,湿法脱硝、选择性催化还原法(SCR)、选择性非催化还原法(SNCR)及其优缺点。探讨了SCR脱硝技术在玻璃熔窑烟气脱硝的运用,并给出了工程实例,最后提出了一些建议。  相似文献   
39.
Nowadays, iron ions as a ubiquitous heavy metal pollutant are gradually concerned and the convenient and quick removal of excessive iron ions in groundwater has become a major challenge for the safety of drinking water. In this study, boron-doped biochar (B-BC) was successfully prepared at various preparation conditions with the addition of boric acid. The as-prepared material has a more developed pore structure and a larger specific surface area (up to 897.97 m²/g). A series of characterization results shows that boric acid effectively activates biochar, and boron atoms are successfully doped on biochar. Compared with the ratio of raw materials, the pyrolysis temperature has a greater influence on the amount of boron doping. Based on Langmuir model, the maximum adsorption capacity of 800B-BC1:2 at 25 °C, 40 °C, 55 °C are 50.02 mg/g, 95.09 mg/g, 132.78 mg/g, respectively. Pseudo-second-order kinetic model can better describe the adsorption process, the adsorption process is mainly chemical adsorption. Chemical complexation, ions exchange, and co-precipitation may be the main mechanisms for Fe2+ removal.  相似文献   
40.
大亚湾核电站余氯排放对邻近海域环境的影响   总被引:7,自引:0,他引:7  
对大亚湾核电站冷却水排放口及邻近海域海水中余氯污染状况进行了调查,结果表明:余氯的含量为〈0.01~0.04mg.L^-1,各季节平均水平为0.01~0.02mg.L^-1,冬季较高。余氯在海水中的形态为化合态。选择若干养殖经济动物进行了余氯毒性胁迫试验。以0.5为安全因子,余氯胁迫作用时间不超过30min时,游离斜 氯对平鲷、黑鲷仔鱼的安全容许浓度约为0.10mg.L^-1,对斑节对虾幼苗为0.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号