掺杂负载型纳米TiO2降解橙黄G的光催化活性及其动力学研究

采用溶胶-凝胶法和浸渍-焙烧法制备了掺杂Sn(Ⅳ)的TiO2/AC光催化剂,以偶氮染料橙黄G为目标降解物,对光催化反应条件进行了优化.结果表明:利用Sn(Ⅳ)掺杂量为2.5 at.%的TiO2/AC光催化剂,在进水浓度50 mg/L,催化剂的用量12.5 g/L,pH值2.0,H2O21.5 mL/L,主波长为365 nm的300W高压汞灯光照条件下,反应60 min,橙黄G的光催化去除率可达99.1%.该反应符合Langmuir-Hinshelwood动力学方程,其速控步为吸附反应.共存阴离子SO42-和H2PO4-,对橙黄G的光催化降解反应均有一定的抑制作用.     

Enhancement of photocatalytic oxidation of humic acid in TiO2 suspensions by increasing cation strength

This study aimed at improving the photocatalytic (PC) oxidation of humic acids (HA) in TiO2 suspensions by adding cationic ion such as calcium or magnesium. A set of tests was first conducted in the dark to study the adsorption of HA onto TiO2 in suspensions at different pH and calcium concentrations. The experiment demonstrated that the adsorption of HA onto the TiO2 particles was either pH-dependent or calcium strength-dependent due to electrostatic interaction and calcium ion bridging. The photodegradation of HA in the presence of UV irradiation was investigated as a function of pH and the concentration of calcium and magnesium ions. The results showed that the adsorption behavior between HA and TiO2 played a very important role during the PC oxidation process. The PC oxidation could be enhanced at neutral pH by increasing the cation strength. The kinetics of HA PC degradation in TiO2 suspensions with different initial concentrations was also studied using the Langmuir-Hinshelwood model.     

新型烟气冷凝节能与脱硫装置研究

烟气冷凝节能与脱硫装置是适用于燃油燃气锅炉的新装置。本文介绍了该装置节能及脱硫的基本原理,利用81.4KW天然气锅炉实验系统对装置的传热和脱硫特性进行了研究。实验表明,该装置提高锅炉效率为3％-8％,脱硫效率为20％-40％。     

城市室内环境多环芳烃污染与源的相关性

本实验选择了天津市４类典型室内环境和２处室外对照点，共１９个采样点。现场采样测定了１０种ＰＡＨｓ组成含量。结果显示，室内燃煤和室内吸烟是室内环境中多环芳烃排放的主要污染源。同作为对照的室外大气中多环芳烃组成和含量进行了对比，研究了室内环境不同污染源排放多环芳烃组成和含量的特征性。提出了室内燃煤污染同燃煤型室外大气源排放多环芳烃具有相似组成含量特征，而室内烟草烟雾污染源的多环芳烃组成含量特征则与室外     

Distribution normality of pH and H<Superscript>+</Superscript> activity in soil

Soil pH, a log-transformed form of hydrogen ion (H⁺) activity, is often used for various statistics. However whether soil pH meets the requirement of distribution normality for statistical analyses is unknown. We studied the statistical suitability of both soil pH and H⁺ activity by examining their distribution normalities. Results show that the variability of H⁺ activity is higher and its distribution is skewer, which is significantly different from the normal and soil pH, regardless of soil conditions and analytical methods. Here we demonstrate that soil pH is more appropriate than the H⁺ activity for performing statistical analysis in terms of distribution normality.     

大气污染预测预报研究

以排放到大气环境中的烟尘为例，进行大气污染预测预报，并利用保证率的概念表示预测的结果，为大气污染的预测预报工作提供了一种基本方法。     

Current status of applying microwave-associated catalysis for the degradation of organics in aqueous phase – A review

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不同来源废水中TOC与COD相关性研究

对纺织染整、化工、制药、食品加工各行业生产废水及城镇污水厂处理设施出水中的TOC(自动仪器监测)与COD(实验室手工分析)测定值进行回归分析,并检验一元线性回归方程的显著性和有效性。结果表明,各行业生产废水中TOC与COD值均存在非常显著的相关性,且废水组成成分越单一稳定,其相关性越好,同行业废水中TOC与COD回归方程的斜率b较为接近。利用TOC自动在线监测值换算所得的COD值,准确性和稳定性高,能满足水质实时连续监测的需要。     

重金属-多氯联苯复合污染土壤同步洗脱

电子垃圾拆解区土壤具有重金属与有机物复合污染的特性,尤其以Cu、Pb、Cd和多氯联苯(PCBs)的复合污染较为突出。为了同步脱除土壤中重金属与PCBs,选用增溶物质:Tween 80、TX-100、SDBS、β-环糊精与螯合剂柠檬酸依次组合进行复合污染土壤淋洗实验,应用批量平衡震荡法研究它们对重金属(Cu、Pb、Cd)与PCBs(Aroclor 1254)的洗脱效果。通过比较洗脱效果、环境友好性等方面,得出非离子表面活性剂Tween 80与天然螯合剂柠檬酸2种淋洗剂复合最佳;进一步研究两者的淋洗先后顺序、浓度配比、洗脱时间及淋洗剂pH对污染土壤洗脱效果的影响,结果表明,在Tween 80和柠檬酸均为10 g/L、pH=6、淋洗时间12 h时淋洗效果达到最佳,对Cu、Pb、Cd及PCBs的洗脱率分别达到98.77%、55.92%、66.82%和58.01%。因此,利用Tween80和柠檬酸组合可同时有效去除土壤重金属和PCBs,是复合污染土壤淋洗修复的有效淋洗剂。     

石油石化行业急性中毒事故的现场抢救

石油石化行业工艺复杂,存在的有害因素种类繁多,一旦发生急性中毒其涉及面广、影响大,有时可造成严重危害。文章较为详细地介绍了该行业存在的主要有毒物质以及发生急性中毒事故的必要条件和特点,阐述了有毒物质侵入人体的途径主要为直接接触或通过呼吸,最后针对一般情况、吸入性中毒、直接接触造成危害的情况介绍了相应的现场急救处理措施。