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231.
232.
This work was designed to explore the characteristics of photodegradation of herbicides in the copper-polluted water body. The
results showed that Cu(II) alone could induce a photo Fenton-like reaction to enhance the degradation of atrazine, in which hydroxyl
radical ( OH) was a main active species. Humic acids restrained atrazine degradation, nevertheless, when introducing Cu(II), the
photodegradation was accelerated, in which singlet oxygen (1O2) replaced OH acting as the prevailing species. A feasible mechanism
for the photochemical process was also proposed, which is helpful for better understanding the environmental photochemistry of
atrazine in the copper-polluted water. 相似文献
233.
The nitrogen (N) biological cycle of the Suaeda salsa marsh ecosystem in the Yellow River estuary was studied during 2008 to 2009.
Results showed that soil N had significant seasonal fluctuations and vertical distribution. The N/P ratio (15.73±1.77) of S. salsa was
less than 16, indicating that plant growth was limited by both N and P. The N absorption coefficient of S. salsa was very low (0.007),
while the N utilization and cycle coefficients were high (0.824 and 0.331, respectively). The N turnover among compartments of S.
salsa marsh showed that N uptake from aboveground parts and roots were 2.539 and 0.622 g/m2, respectively. The N translocation
from aboveground parts to roots and from roots to soil were 2.042 and 0.076 g/m2, respectively. The N translocation from aboveground
living bodies to litter was 0.497 g/m2, the annual N return from litter to soil was far less than 0.368 g/m2, and the net N mineralization
in topsoil during the growing season was 0.033 g/m2. N was an important limiting factor in S. salsa marsh, and the ecosystem was
classified as unstable and vulnerable. S. salsa was seemingly well adapted to the low-nutrient status and vulnerable habitat, and the
nutrient enrichment due to N import from the Yellow River estuary would be a potential threat to the S. salsa marsh. Excessive nutrient
loading might favor invasive species and induce severe long-term degradation of the ecosystem if human intervention measures were
not taken. The N quantitative relationships determined in our study might provide a scientific basis for the establishment of effective
measures. 相似文献
234.
Polyaspartic acid (PASP) has been extensively studied in recent years as a green scale inhibitor. PASP was synthesized by thermal polycondensation of maleic anhydride and ammonium carbonate in this study. The optimal polycondensation reaction conditions were the raw material (maleic anhydride and ammonium carbonate) molar ratio of 1.0:1.2, the polymerization temperature of 180°C and reaction time of 2.0 hr. The results showed that PASP exhibits very good scale inhibiting performance. The inhibition rate was 95% for calcium carbonate and 90% for calcium sulfate by the application of 5 mg/L PASP. 相似文献
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238.
Catalytic bubble-free hydrogenation reduction of azo dye by porous membranes loaded with palladium (Pd) nanoparticles was studied for the first time. The effects of Pd loading, dye concentration and reuse repetitions of membranes were investigated. In reduction, the dye concentration decreased whereas the pH rose gradually. An optimal Pd loading was found. The catalytic membranes were able to be reused more than 3 times. 相似文献
239.
Pinpin Lu Xiaojian Zhang Chiqian Zhang Zhangbin Niu Shuguang Xie Chao Chen 《环境科学学报(英文版)》2014,26(2):323-331
This study investigated the bacterial regrowth in drinking water distribution systems receiving finished water from an advanced drinking water treatment plant in one city in southem China. Thirteen nodes in two water supply zones with different aged pipelines were selected to monitor water temperature, dissolved oxygen (DO), chloramine residual, assimilable organic carbon (AOC), and heterotrophic plate counts (HPC). Regression and principal component analyses indicated that HPC had a strong correlation with chloramine residual. Based on Chick-Watson's Law and the Monod equation, biostability curves under different conditions were developed to achieve the goal of HPC 100 CFU/mL. The biostability curves could interpret the scenario under various AOC concentrations and predict the required chloramine residual concentration under the condition of high AOC level. The simulation was also carded out to predict the scenario with a stricter HPC goal (≤50 CFU/mL) and determine the required chloramine residual. The biological regrowth control strategy was assessed using biostability curve analysis. The results indicated that maintaining high chloramine residual concentration was the most practical way to achieve the goal of HPC ≤ 100 CFU/mL. Biostability curves could be a very useful tool for biostability control in distribution systems. This work could provide some new insights towards biostability control in real distribution systems. 相似文献
240.
Plastics such as polyvinyl chlorides (PVC) are widely used in many indoor constructed environments; however, their unbound chemicals, such as di-(2-ethylhexyl) phthalates (DEHP), can leach into the surrounding environment. This study focused on DEHP's effect on the central nervous system by determining the precise DEHP content in mice brain tissue after exposure to the chemical, to evaluate the specific exposure range. Primary neuronal-astrocyte co-culture systems were used as in vitro models for chemical hazard identification of DEHP. Oxidative stress was hypothesized as a probable mechanism involved, and therefore the total reactive oxygen species (ROS) concentration was determined as a biomarker of oxidative stress. In addition, NeuriteTracer, a neurite tracing plugin with ImageJ, was used to develop an assay for neurotoxicity to provide quantitative measurements of neurological parameters, such as neuronal number, neuron count and neurite length, all of which could indicate neurotoxic effects. The results showed that with 1 nmol/L DEHP exposure, there was a significant increase in ROS concentrations, indicating that the neuronal-astrocyte cultures were injured due to exposure to DEHP. In response, astrocyte proliferation (gliosis) was initiated, serving as a mechanism to maintain a homeostatic environment for neurons and protect neurons from toxic chemicals. There is a need to assess the cumulative effects of DEHP in animals to evaluate the possible uotake and effects on the human neuronal system from exoosure to DEHP in the indoor environment. 相似文献