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溶液中阴离子对UV/H2O2降解十二烷基苯磺酸钠的影响及其机理 总被引:2,自引:0,他引:2
研究了UV/H2O2工艺对十二烷基苯磺酸钠(LAS)的去除效果、溶液中阴离子对LAS降解的影响及机理.结果表明:UV/H2O2工艺可以有效地去除水中的LAS;在H2O2投加量为8 mg/L,14 W低压汞灯照射下,LAS在蒸馏水和自来水中的反应速率常数分别为0.018 0 、0.012 2 min-1;NO-3、Cl-、SO2-4和HCO-3对LAS光降解有抑制作用,当该4种离子摩尔浓度均分别为5、10、15 mmol/L时,对LAS光降解的抑制程度为HCO-3》NO-3》Cl-》SO2-4,且随着离子摩尔浓度的增大,抑制作用增强;LAS在自来水中的反应速率常数低于在蒸馏水中的反应速率常数是由于水中多种离子影响的结果. 相似文献
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Estrogenic effects of phenolic compounds on glucose-6-phosphate dehydrogenase in MCF-7 cells and uterine glutathione peroxidase in rats 总被引:6,自引:0,他引:6
In this study, we tested phenolic compounds such as bisphenol A (BPA), 4-nonylphenol (NP), 4-octylphenol (OP) and 4-propylphenol (PP) by using glucose-6-phosphate dehydrogenase (G6PD) in estrogen sensitive human breast cancer cells (MCF-7 cells) and glutathione peroxidase (GPx) in female immature Sprague-Dawley (SD) rats. This study was designed to investigate whether phenolic compounds have estrogenic effects in these useful screening methods for endocrine disruptors. We chose 6 h as the incubation period for the G6PD assay through a preliminary experiment using 17beta-estradiol (E2). Above the concentration of 1 x 10(-8) M, BPA significantly increased the G6PD activity in a concentration-dependent manner, relative to the control. NP (over the concentration of 1 x 10(-9) M) also enhanced the G6PD activity by about 1.8 times that of the control. OP produced weaker effects on G6PD than NP, and showed a tendency to increase the G6PD activity. PP did not affect the G6PD activity. These results show that BPA and NP have the effect of enhancing G6PD activities in MCF-7 cells. In the in vivo GPx assay, both BPA and E2 significantly increased the uterus wet weights and dramatically enhanced uterine GPx activities in immature female rats in a dose-dependent manner. Treatment with NP (500 mg/kg/day) increased significantly both the uterine GPx activity and the uterus wet weights in immature female rats. OP (500 mg/kg/day) also caused a significant increase in uterine GPx activity, but had no effect on the uterus wet weights. This finding indicates that the change in uterine GPx activities could be a more sensitive parameter than that of uterus wet weights in immature rats. This study implies that phenolic compounds have a weak estrogenic effects. 相似文献
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Trace analysis of dissolved polychlorinated organic compounds in the water of the Yangtse River (Nanjing, China) 总被引:15,自引:0,他引:15
Sun C Dong Y Xu S Yao S Dai J Han S Wang L 《Environmental pollution (Barking, Essex : 1987)》2002,117(1):9-14
Eighteen organochlorine contaminants from the water samples of the Yangtse River have been qualitatively and quantitatively analyzed. The analysis of polychlorinated organic compounds (PCOCs) extracted by C18 Solid Phase Extract (SPE) was performed using HP6890 gas chromatograph coupled by ECD detector. The analytical results demonstrate that the analytical methods are reliable based on the fact that most of the recoveries for the targeted compounds are 60-90%. Most of the concerned contaminants, i.e. chlorinated pesticides and PCBs were found in the water samples of the Yangtse River, but their concentration was very low, <2.97 ng l(-1), which is far less than 1 microg l(-1)--the standard of drinking water of China. It is apparent that the PCOCs were in high concentration during the dry season, and in low concentration during the rainy season. The situation of PCOCs contamination in the water of the Yangtse River in 1999 was greatly improved in comparison with 10 years ago. 相似文献
956.
为了提高硝酸吸收氮氧化物的效率,对活性填料催化氧化-硝酸吸收NOx进行了研究。结果表明:活性填料能明显提高NOx的吸收效率;当NOx中NO2体积百分含量增加,其吸收效率增加;随进气浓度和液气比的增大,NOx吸收效率增加;随NO2浓度的增加,NO的吸收效率先增加后减少,在NO/NO2为3时,NO吸收效率最高;随NO的增加NO2的吸收效率先增加后减少,在NO/NO2为0.6~1之间,NO2的吸收效果较好。 相似文献
957.
参杂负载型纳米TiO2降解橙黄G的光催化活性及其动力学研究 总被引:1,自引:0,他引:1
采用溶胶-凝胶法和浸渍-焙烧法制备了掺杂Sn(Ⅳ)的TiO2/AC光催化剂,以偶氮染料橙黄G为目标降解物,对光催化反应条件进行了优化。结果表明:利用Sn(IV)掺杂量为2.5at.%的TiO2/AC光催化剂,在进水浓度50mg/L,催化剂的用量12.5g/i,pH值2.0,H2O2 1.5mL/L。主波长为365nm的300W高压汞灯光照条件下,反应60rain,橙黄G的光催化去除率可达99.1%。该反应符合Langmuir-Hinshelwood动力学方程,其速控步为吸附反应。共存阴离子SO4^2-和H2PO4^-,对橙黄G的光催化降解反应均有一定的抑制作用。 相似文献
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