Cattle egrets as a biosentinels of persistent organic pollutants exposure

We investigated selected chlorinated pollutants (β-HCH, γ-HCH, DDDs, DDEs, o,p′-DDT, p,p′-DDT, heptachlor, aldrin, dieldrin, and endrin) in the Lahore and the Sialkot districts of Pakistan, using eggs of cattle egret (Bubulcus ibis) collected during May and June 2007. The pollutant with highest level and frequency was ΣDDT, followed by β-HCH, γ-HCH, heptachlor, aldrin, dieldrin, and endrin in descending order. The concentration(s) were significantly higher in Sialkot heronry for all the pollutants (except p,p′-DDT) than in Lahore. The values for DDTs, β-HCH, γ-HCH, and heptachlor were significantly higher (p < 0.05) in the egg(s) than in sediment(s) and in the chicks’ diet, due to biomagnification. Among DDTs analogues, p,p′-DDD was the major contaminant with >60 % of total DDT burden, reflecting the widespread aged as well as recent use of DDT as well as anaerobic degradation (DDD/DDE > 1 in many cases) in the nearby paddy soils. In few samples, p,p′-DDT/(DDD + DDE) > 0.5 suggested the recent emission patterns from surrounding contaminated areas of demolished DDT units and obsolete pesticide stores. The higher levels of HCHs (i.e., β-HCH) in the samples collected from Sialkot indicate exposure from long-term agricultural use. Overall, concentrations of all studied POPs were less than the threshold levels known to affect reproduction. Nevertheless, total DDTs and/or HCHs burdens in some eggs contained concentrations of greater than what would educe adverse effects on birds. This is among few studies on OCPs exposure to avian species, which provide the evidence of Pakistan’s contribution toward the Global POPs emission.     

Application of Zr(IV) tungstate for removal of metal ions from aqueous solutions

A heteropolyacid Zr(IV) tungstate-based cation exchanger has been synthesized. An amorphous sample, prepared at pH 1.2 and having a Na⁺ ion exchange capacity of 0.92?meq?g^?1, was selected for further studies. Its physicochemical properties were determined using Fourier transform infrared spectrometer, X-ray diffraction, thermogravimetric, and scanning electron studies. To understand the cation exchange behavior of the material, distribution coefficients (K _d) for metal ions in various solvent systems were determined. Some important binary separations of metal ions, namely Mg²⁺–Bi³⁺, Cd²⁺–Bi³⁺, Fe³⁺–Bi³⁺, Th⁴⁺–Bi³⁺, and Fe³⁺–Zn²⁺, were achieved on such columns. The practical utility of these separations was demonstrated by separating Fe³⁺ and Zn²⁺ ions quantitatively in commercial pharmaceutical formulation. The cation exchanger has been successfully applied also for the treatment of industrial wastewater and a synthetic mixture. All the results suggests that Zr(IV) tungstate has excellent potential for the removal of metals from aqueous systems using packed columns of this material.     

Sol-gel immobilisation of methyl parathion degrading bacteria isolated from agricultural areas of Pakistan

The following areas are discussed in this paper: immobilisation of bacterial consortium in sol-gel; methyl parathion degradation and bioremediation applications; evaluation of indigenous bacterial isolates of contaminated soils. Bacterial strains were isolated from agricultural areas of Pakistan which were contaminated with methyl parathion. A bacterial consortium of seven (out of 64) Enterobacteriaceae isolates including Citrobacter, Enterobacter and Proteus vulgaris capable of degrading methyl parathion (enzyme activity ranging 410–675 mU mL^?1 for individual isolates and 982 mU/mL for consortium) was selected and subsequently immobilised in tetraethyl orthosilicate (TEOS) and sodium-silicate-based sol-gel matrices. Cell viability of suspended and immobilised bacterial consortium was monitored using a minimal salt medium supplemented with methyl parathion. The results indicate that sol-gel immobilisation can be helpful to increase the shelf life of methyl parathion degrading bacterial strains along with preservation of biological activity for bioremediation applications in field.     

Metal contamination of surface soils of industrial city Sialkot,Pakistan: a multivariate and GIS approach

In this study concentrations of selected metals viz., Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Na, Ni, Pb and Zn in surface soils of Sialkot city known worldwide for tanneries and pharmaceutical industries were measured to assess the status of urban soil pollution and to identify sources of contamination. Hierarchical cluster analysis (HACA) indicated concentrations of Mg and Ca related to parent rock material, Cd, Co, and Pb with traffic related activities, Cr, Cu, Ni and Zn either associated with automobiles activities or industrial pollution and Fe, K and Na related with anthropogenic activities or lithogenous materials. Correlation analyses and principal component analysis based on factor analysis confirmed the results of HACA. Spatial distribution maps exhibited relatively higher concentrations of Cd, Co, Cu, Ni, Pb, Cr and Zn along traffic routes in the city and streams. The results highlighted concentration of Cd, Ni, Cr, Zn, and Pb measured in urban soil exceeded the permissible limit of surface soils and advocated an imperative need for detailed baseline investigations of spatial distribution of heavy metals and other contaminants for the formulation of geochemical database that should be made available to stakeholder involved in monitoring, assessment and conservation of soil contamination for future planning and management of the Sialkot city.     

Impact assessment of subsurface drainage on waterlogged and saline lands

Waterlogging and salinity due to seepage from canals have polluted land and environment in various parts of Pakistan. A sustainable environment requires urgent remedial measures for this problem. The research in this paper presents the impacts of the Fourth Drainage Project, Faisalabad on the twin problem of waterlogging and salinity. Monitoring of the project was made on regular basis. The key performance indicators for the project include the lowering of water table, improvement of water quality and soil salinity, increase in area under cultivation, cropping intensity, and socioeconomic status of the project population. Data regarding water levels and discharge from the drain pipes were collected to monitor the impact on waterlogging. Soil samples were tested to evaluate the impact of drainage on land. It has been found that the percentage of the contaminated land in the project area has considerably been decreased, while the cropping intensities have been increased.     

Evaluating repeated patient handling injuries following the implementation of a multi-factor ergonomic intervention program among health care workers

Objective

The objective of this study was to evaluate repeated patient handling injuries following a multi-factor ergonomic intervention program among health care workers.

Methods

This was a quasi-experimental study which had an intervention group and a non-randomized control group. Data were collected from six hospitals in Saskatchewan, Canada from September 1, 2001 to December 1, 2006.

Results

A total of 1,480 individuals who had a previous injury were eligible for the study. Medium and small size hospitals in the intervention group had significantly fewer repeated injuries than in the control group. Multivariate analysis showed that the intervention group had 38.1% lower odds of having repeated injury compared to the control group, after adjusting for hospital size.

Conclusions

The work-related repeated injury after a multi-factor intervention program was reduced. The synergistic relationships between components of multi-factor intervention and applicability of injury prevention programs to different settings need to be further explored.

Impact on Industry

Implementing a multi-factor program with the right equipment and training can lower the risk of injury among health care workers.     

Process Optimization and Adsorptive Mechanism for Reactive Blue 19 Dye by Magnetic Crosslinked Chitosan/MgO/Fe3O4 Biocomposite

Journal of Polymers and the Environment - A new biocomposite cross-linked glutaraldehyde-chitosan/MgO/Fe3O4 (CTS-GL/MgO/Fe3O4) adsorbent with magneto-responsiveness was prepared and applied for the...     

Determinants of CO2 emissions: exploring the unexplored in low-income countries

Environmental Science and Pollution Research - In thirst for economic growth, economies are engaged in anti-environmental activities that drive them towards climate change and CO2 emissions....     

Role of casting and curing conditions on the strength and drying shrinkage of greener concrete

The shrinkage of cement-based materials is a critical dimensional property that needs proper attention as it can influence the corresponding characteristics especially when the preparation of such cement-based material is done in hot weather. Studies have shown that the casting or curing conditions influence the performance of concrete. However, there is limited understanding of the combined role of casting temperature and curing conditions, especially for concrete made with unconventional binders. In this study, five supplementary cementitious materials (SCMs) were utilized as the substitute of the ordinary Portland cement (OPC) at different ratios to produce greener concrete and improve its characteristics and sustainability. The influence of four casting temperatures (i.e., 25 °C, 32 °C, 38 °C, and 45 °C) and two curing regimes (i.e., covering of samples using wet burlap and applying curing compound on the surface of samples) on the corresponding compressive strength and drying shrinkage at various ages was studied. The outcomes of this research revealed that the composition of the binders has a substantial impact on the characteristics of concrete. In addition, the casting temperature and curing regimes also have a huge role on the compressive strength of concrete produced with binary binders. For example, the compressive strength at 3 days of concrete made at 25 °C made with binary binders was reduced up to 31% compared to that made with only OPC as the binder when cured using wet burlap. Nonetheless, less than 38 ℃ was suitable to minimize the durability issues in the studied blended cement mixes.

     

Forty years studies on polychlorinated biphenyls pollution,food safety,health risk,and human health in an e-waste recycling area from Taizhou city,China: a review

Environmental Science and Pollution Research - E-waste generation has become a serious environmental challenge worldwide. Taizhou of Zhejiang Province, situated on the southeast coastline of China,...