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461.
Sulphate, Nitrogen and Base Cation Budgets at 21 Forested Catchments in Canada, the United States and Europe 总被引:1,自引:0,他引:1
Watmough SA Aherne J Alewell C Arp P Bailey S Clair T Dillon P Duchesne L Eimers C Fernandez I Foster N Larssen T Miller E Mitchell M Page S 《Environmental monitoring and assessment》2005,109(1-3):1-36
To assess the concern over declining base cation levels in forest soils caused by acid deposition, input-output budgets (1990s
average) for sulphate (SO4), inorganic nitrogen (NO3-N; NH4-N), calcium (Ca), magnesium (Mg) and potassium (K) were synthesised for 21 forested catchments from 17 regions in Canada,
the United States and Europe. Trend analysis was conducted on monthly ion concentrations in deposition and runoff when more
than 9 years of data were available (14 regions, 17 sites). Annual average SO4 deposition during the 1990s ranged between 7.3 and 28.4 kg ha−1 per year, and inorganic nitrogen (N) deposition was between 2.8 and 13.8 kg ha−1 per year, of which 41–67% was nitrate (NO3-N). Over the period of record, SO4 concentration in deposition decreased in 13/14 (13 out of 14 total) regions and SO4 in runoff decreased at 14/17 catchments. In contrast, NO3-N concentrations in deposition decreased in only 1/14 regions, while NH4-N concentration patterns varied; increasing at 3/14 regions and decreasing at 2/14 regions. Nitrate concentrations in runoff
decreased at 4/17 catchments and increased at only 1 site, whereas runoff levels of NH4-N increased at 5/17 catchments. Decreasing trends in deposition were also recorded for Ca, Mg, and K at many of the catchments
and on an equivalent basis, accounted for up to 131% (median 22%) of the decrease in acid anion deposition. Base cation concentrations
in streams generally declined over time, with significant decreases in Ca, Mg and K occurring at 8, 9 and 7 of 17 sites respectively,
which accounted for up to 133% (median 48%) of the decrease in acid anion concentration. Sulphate export exceeded input at
18/21 catchments, likely due to dry deposition and/or internal sources. The majority of N in deposition (31–100%; median 94%)
was retained in the catchments, although there was a tendency for greater NO3-N leaching at sites receiving higher (<7 kg ha-1 per year) bulk inorganic N deposition. Mass balance calculations show that export of Ca and Mg in runoff exceeds input at
all 21 catchments, but K export only exceeds input at 16/21 sites. Estimates of base cation weathering were available for
18 sites. When included in the mass balance calculation, Ca, Mg and K exports exceeded inputs at 14, 10 and 2 sites respectively.
Annual Ca and Mg losses represent appreciable proportions of the current exchangeable soil Ca and Mg pools, although losses
at some of the sites likely occur from weathering reactions beneath the rooting zone and there is considerable uncertainty
associated with mineral weathering estimates. Critical loads for sulphur (S) and N, using a critical base cation to aluminium
ratio of 10 in soil solution, are currently exceeded at 7 of the 18 sites with base cation weathering estimates. Despite reductions
in SO4 and H+ deposition, mass balance estimates indicate that acid deposition continues to acidify soils in many regions with losses of
Ca and Mg of primary concern.
The U.S. Government's right to retain a non-exclusive, royalty free licence in and to any copyright is acknowledged.
The Canadian Crown reserves the right to retain a non-exclusive, royalty free licence in and to any copyright. 相似文献
462.
463.
A simple, sensitive, convenient and low cost spectrofluorometric technique for determination of quinalphos is described. Quinalphos is decomposed with sodium ethoxide. Resultant sodium diethyl thiophosphate (Na-DETP) is extracted with a cationic fluorescein as ion pair complex into 1-chloro-2-nitrobenzene. The fluorescence of the ion pair, fluorescein-DETP is measured at 530 nm after excitation at 490 nm. This technique is applicable for the determination of quinalphos in water, food grains and vegetable samples up to ng level with Amberlite XAD-4. 相似文献
464.
Mehaffey MH Nash MS Wade TG Ebert DW Jones KB Rager A 《Environmental monitoring and assessment》2005,107(1-3):29-44
The Catskill/Delaware reservoirs supply 90% of New York City’s drinking water. The City has implemented a series of watershed protection measures, including land acquisition, aimed at preserving water quality in the Catskill/Delaware watersheds. The objective of this study was to examine how relationships between landscape and surface water measurements change between years. Thirty-two drainage areas delineated from surface water sample points (total nitrogen, total phosphorus, and fecal coliform bacteria concentrations) were used in step-wise regression analyses to test landscape and surface-water quality relationships. Two measurements of land use, percent agriculture and percent urban development, were positively related to water quality and consistently present in all regression models. Together these two land uses explained 25 to 75% of the regression model variation. However, the contribution of agriculture to water quality condition showed a decreasing trend with time as overall agricultural land cover decreased. Results from this study demonstrate that relationships between land cover and surface water concentrations of total nitrogen, total phosphorus, and fecal coliform bacteria counts over a large area can be evaluated using a relatively simple geographic information system method. Land managers may find this method useful for targeting resources in relation to a particular water quality concern, focusing best management efforts, and maximizing benefits to water quality with minimal costs.The United States Environmental Protection Agency through its Office of Research and Development funded and managed the research described here. It has been subjected to Agency’s administrative review and approved for publication as an EPA document. 相似文献
465.
The increasing use of the landscape by humans has led to important diminutions of natural surfaces. The remaining patches
of wild habitat are small and isolated from each other among a matrix of inhospitable land-uses. This habitat fragmentation,
by disabling population movements and stopping their spread to new habitats, is a major threat to the survival of numerous
plant and animal species. We developed a general model, adaptable for specific species, capable of identifying suitable habitat
patches within fragmented landscapes and investigating the capacity of populations to move between these patches. This approach
combines GIS analysis of a landscape, with spatial dynamic modeling. Suitable habitat is identified using a threshold area
to perimeter ratio. Potential movement pathways of species between habitat patches are modeled using a cellular automaton.
Habitat connectivity is estimated by overlaying habitat patches with movement pathways. The maximum potential population is
calculated within and between connected habitat patches and potential risk of inbreeding within meta-populations is considered.
The model was tested on a sample map and applied to scenario maps of predicted land-use change in the Peoria Tri-county region
(IL). It (1) showed area of natural area alone was insufficient to estimate the consequences on animal populations; (2) underscored
the necessity to use approaches investigating the effect of land-use change spatially through the landscape and the importance
of considering species-specific life history characteristics; and (3) highlighted the model's potential utility as an indicator
of species likelihood to be affected negatively by land-use scenarios and therefore requiring detailed investigation. 相似文献
466.
Bhanarkar AD Srivastava A Joseph AE Kumar R 《Environmental monitoring and assessment》2005,109(1-3):73-80
Air pollution in the workplace environment due to industrial operation have been found to cause serious occupational health
hazard. Similarly, heat stress is still most neglected occupational hazard in the tropical and subtropical countries like
India. The hot climate augments the heat exposure close to sources like furnaces. In this study an attempt is made to assess
air pollution and heat exposure levels to workers in the workplace environment in glass manufacturing unit located in the
State of Gujarat, India. Samples for workplace air quality were collected for SPM, SO2, NO2 and CO2 at eight locations. Results of workplace air quality showed 8-hourly average concentrations of SPM: 165–9118 μg/m3, SO2: 6–9 μg/m3 and NO2: 5–42 μg/m3, which were below the threshold limit values of workplace environment. The level of CO2 in workplace air of the plant was found to be in the range 827–2886 μg/m3, which was below TLV but much higher than the normal concentration for CO2 in the air (585 mg/m3). Indoor heat exposure was studied near the furnace and at various locations in an industrial complex for glass manufacturing.
The heat exposure parameters including the air temperature, the wet bulb temperature, and the globe parameters were measured.
The Wet Bulb Globe Temperature (WBGT), an indicator of heat, exceeded ACGIH TLVs limits most of the time at all the locations
in workplace areas. The recommended duration of work and rest have also been estimated. 相似文献
467.
Watson RJ Butler EC Clementson LA Berry KM 《Journal of environmental monitoring : JEM》2005,7(1):37-42
A method using flow-injection, gas-diffusion, derivatisation and then fluorescent detection has been established for ammonium ion determination in seawater. The fluorescent derivative formed by reacting ortho-phthaldialdehyde (OPA) and sulfite with ammonia gives high sensitivity while removing potential interferences. This is required to measure the low concentrations of ammonium often seen in the open ocean. The experimental conditions (flow-rate, reagent concentrations, membrane configurations, etc.) were manipulated to improve performance. For a sample throughput of 30 samples h(-1), the limit of detection was 7 nM, the coefficient of variation was 5.7% at 800 nM, and the calibration curve was linear to at least 4 micromol L(-1). Interferences were minimised by a gaseous diffusion step. Volatile small molecular-weight amines as interferents were discriminated against by this method. They neither passed through the membrane as efficiently as ammonia, nor reacted as readily with OPA when sulfite was the reductant. Contamination by ammonia from laboratory and shipboard sources complicates application of the method to natural waters, especially measurement of low concentrations (<100 nM) in open-ocean waters. Steps to overcome contamination are described in detail. Some results are presented for ammonium determination in Southern Ocean and Huon Estuary (Tasmania) waters. 相似文献
468.
Wiersma YF 《Environmental monitoring and assessment》2005,100(1-3):1-9
Environmental benchmarks are widely used in Canadian environmental assessment as a standard against which to monitor air or water quality in response to human activities in the environment. Recent work in Canada has developed the concept of ecological benchmarks as a complement to environmental benchmarks. However, implementation of ecological benchmarks may be challenging. This paper presents an analogy between ecological benchmarks and the more commonly used environmental benchmarks, as an attempt to increase understanding and use of ecological benchmarks in resource management, assessment, and monitoring. Ecological benchmarks, and their corresponding indicators, will be challenging to identify and use. However, through the use of the principles of adaptive management, effective ecological indicators and benchmarks can be established. Although it is essential that ecological benchmarks are site-specific, the analogy and general principles outlined here are applicable to assessment and monitoring in any part of the world. 相似文献
469.
A modular approach to Integrated Assessment modeling 总被引:1,自引:0,他引:1
In this paper, we present a new approach to model coupling that probably forms the methodological basis of a new generation of Integrated Assessment models. This approach respects the knowledge and expertise that is embodied in existing models and encourages their gradual evolution. Modularity is the guiding principle. Our approach is distinguished by the way modules are coupled which is based on an interplay of a job control module, a numerical coupling module, and a couple of stand-alone functional modules. The numerical coupling module - the core component - serves to treat the feedbacks between the functional modules. A first implemented example that couples an economic and a climate module by means of a two-phase meta-optimization is presented here. The algorithm and mathematical structure behind are discussed as well as important features such as convergence behavior and reliability. 相似文献
470.