巴黎协定下中国碳排放权省域分配及减排潜力评估研究

通过构建碳排放权区域分配模型完成了省域分配,在此基础上与当前各地实际碳排放量进行比对,明晰了各自初始空间余额;而后对碳排放权欠缺地区的碳减排潜力进行了综合评估。研究结果表明：（1）我国30个省区碳排放权分配存在较大差异,其中云南配额最高,占比高达10.53%;宁夏配额最少,占比仅为0.28%。（2）全国有14个省区碳排放权初始空间余额表现出盈余状态,根据成因差异可大致分为“低排放、高配额”“低排放、低配额”以及“高排放、高配额”等三种类型;其他16个地区均表现出一定程度的欠缺,结合数值差异可划分为以江苏等4地为代表的轻度欠缺地区,以天津等7地为代表的中度欠缺地区,以及以辽宁等5地为代表的重度欠缺地区。（3）浙江、天津、山东等3地目前所具备的碳减排潜力要明显高于其他地区,而各地区的碳减排潜力水平虽与其碳排放权欠缺量表现出了一定趋同性但并非完全一致。     

Does green credit affect the green innovation performance of high-polluting and energy-intensive enterprises? Evidence from a quasi-natural experiment

Environmental Science and Pollution Research - Taking the green credit policy in 2012 as a quasi-natural experiment, this paper applies the methods of propensity score matching and...     

Potential effects of soil chemical and biological properties on wood volume in Eucalyptus urophylla × Eucalyptus grandis hybrid plantations and their responses to different intensity applications of inorganic fertilizer

Environmental Science and Pollution Research - Long-term and high-intensity application of inorganic fertilizer leads to a strong variation of soil characteristics. The changes in soil chemical and...     

Assessment of Water Availability and Scarcity Based on Hydrologic Components in an Irrigated Agricultural Watershed Using SWAT

This study assesses the water availability and the water scarcity based on the hydrologic behavior under different weather conditions and crop coverages in an irrigated agricultural area of Rincon Valley in New Mexico using the SWAT (Soil and Water Assessment Tool) model. Two spatial crop coverages included normal (2008) and dry (2011) years with 14 different crop sets for each year. The SWAT was applied to generate the five essential indicators (surface flow, evapotranspiration, soil water, groundwater recharge, and irrigation water) to evaluate the integrated water availability based on hydrologic response units (HRUs) along with the Arrey Canal to supply irrigation water in the crop areas. The water availability index scores (0–1 range with 1 being the most available and 0 the least available) of alfalfa, corn, cotton, and pecans were 0.21, 0.56, 0.91, and 0.20, respectively, in the normal year and 0.16, 0.78, 0.88, and 0.24, respectively, in the dry year. In the dry year, water scarcity values were high in mostly alfalfa areas, whereas cotton areas have mostly no stress with good water availability. The major water users of crops, ranked in order, were alfalfa, pecans, cotton, and corn. During the dry year, water availability showed to be balanced in terms of water supply and demand by controlling crop patterns from reducing alfalfa acreage by 12% and increasing cotton acreage by 13%.     

Shark fin,a symbol of wealth and good fortune may pose health risks: the case of mercury

There is a lack of information concerning human health risks due to exposure to mercury contained in shark fins, through dietary intake. Health risk assessment of shark fins, collected from 5 cities in China: Hong Kong (HK), Beijing, Shanghai (SH), Haikou (HN) and Wenzhou (WZ), was conducted, based on total mercury and methylmercury, and analyzed by a cold vapor atomic fluorescence spectrometry equipped with high-performance liquid chromatography, respectively. The results showed that 16.8 % samples from HK, 8.3 % from SH, 33.3 % from HN, and 16.8 % from WZ were regarded as unsafe for human consumption. Extremely high consumption rates of shark fins for an adult and a child (0.150 and 0.0807 kg/day, respectively), at 95th centile, samples from WZ demonstrated high non-cancer risks (adverse health effects) (Hazard Quotient = 16.0) on adults (aged 25–65), and samples from SH, HN and WZ also showed high non-cancer risks (Hazard Quotient = 12.9, 21.0, and 34.4, respectively) on children (aged 1–7). Consumption of shark fins may be detrimental to human health.     

Colloidal diatomite, radionickel, and humic substance interaction: a combined batch, XPS, and EXAFS investigation

This work determined the influence of humic acid (HA) and fulvic acid (FA) on the interaction mechanism and microstructure of Ni(II) onto diatomite by using batch experiments, X-ray photoelectron spectroscopy (XPS), and extended X-ray absorption fine structure (EXAFS) methods. Macroscopic and spectroscopic experiments have been combined to see the evolution of the interaction mechanism and microstructure of Ni(II) in the presence of HA/FA as compared with that in the absence of HA/FA. The results indicated that the interaction of Ni(II) with diatomite presents the expected solution pH edge at 7.0, which is modified by addition of HA/FA. In the presence of HA/FA, the interaction of Ni(II) with diatomite increased below solution pH 7.0, while Ni(II) interaction decreased above solution pH 7.0. XPS analysis suggested that the enrichment of Ni(II) onto diatomite may be due to the formation of (≡SO)₂Ni. EXAFS results showed that binary surface complexes and ternary surface complexes of Ni(II) can be simultaneously formed in the presence of HA/FA, whereas only binary surface complexes of Ni(II) are formed in the absence of HA/FA, which contribute to the enhanced Ni(II) uptake at low pH values. The results observed in this work are important for the evaluation of Ni(II) and related radionuclide physicochemical behavior in the natural soil and water environment.     

Pyrolysis and dehalogenation of plastics from waste electrical and electronic equipment (WEEE): A review

Plastics from waste electrical and electronic equipment (WEEE) have been an important environmental problem because these plastics commonly contain toxic halogenated flame retardants which may cause serious environmental pollution, especially the formation of carcinogenic substances polybrominated dibenzo dioxins/furans (PBDD/Fs), during treat process of these plastics. Pyrolysis has been proposed as a viable processing route for recycling the organic compounds in WEEE plastics into fuels and chemical feedstock. However, dehalogenation procedures are also necessary during treat process, because the oils collected in single pyrolysis process may contain numerous halogenated organic compounds, which would detrimentally impact the reuse of these pyrolysis oils. Currently, dehalogenation has become a significant topic in recycling of WEEE plastics by pyrolysis. In order to fulfill the better resource utilization of the WEEE plastics, the compositions, characteristics and dehalogenation methods during the pyrolysis recycling process of WEEE plastics were reviewed in this paper. Dehalogenation and the decomposition or pyrolysis of WEEE plastics can be carried out simultaneously or successively. It could be ‘dehalogenating prior to pyrolysing plastics’, ‘performing dehalogenation and pyrolysis at the same time’ or ‘pyrolysing plastics first then upgrading pyrolysis oils’. The first strategy essentially is the two-stage pyrolysis with the release of halogen hydrides at low pyrolysis temperature region which is separate from the decomposition of polymer matrixes, thus obtaining halogenated free oil products. The second strategy is the most common method. Zeolite or other type of catalyst can be used in the pyrolysis process for removing organohalogens. The third strategy separate pyrolysis and dehalogenation of WEEE plastics, which can, to some degree, avoid the problem of oil value decline due to the use of catalyst, but obviously, this strategy may increase the cost of whole recycling process.     

Monitoring nitrogen deposition in typical forest ecosystems along a large transect in China

The nitrogen (N) deposition fluxes were investigated in eight typical forest ecosystems along the North–South Transect of Eastern China (NSTEC; based on the ChinaFLUX network) by ion-exchange resin (IER) columns from May 2008 to April 2009. Our results demonstrated that the method of IER columns was both labor cost saving and reliable for measuring dissolved inorganic nitrogen (DIN) deposition at the remote forest stations. The deposition of DIN in the throughfall ranged from 1.3 to 29.5 kg N ha^?1 a^?1, increasing from north to south along NSTEC. The relatively high average ratio of ammonium to nitrate in deposition (1.83) indicated that the N deposition along the NSTEC in China mostly originated in farming and animal husbandry rather than in industry and vehicle activities. For seasonal variability, the DIN deposition showed a single peak in the growing season in the northern part of NSTEC, while, in the southern part, it exhibited double-peaks in the early spring and the mid-summer, respectively. On the annual scale, the DIN deposition variations of the eight sites could be mainly explained by precipitation and the distances from forest stations to provincial capital cities.     

Variations of organochlorine pesticides and polychlorinated biphenyls in atmosphere of the Tibetan Plateau: Role of the monsoon system

Monsoon transport is an important process that influences the global transport of persistent organic pollutants. Only a few studies focused on the influence of monsoon on organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) levels in the Tibetan Plateau. In this study, 19 samples were collected in Lhasa, the capital of Tibet Autonomous Region, using a high-volume air sampler. The average concentrations of α-HCH, γ-HCH, p-p′-DDT, p-p′-DDE, o-p′-DDT, α-endosulfan, β-endosulfan and PCBs (including PCB-28, 101, and 118) were 2.3, 10.3, 3.2, 2.9, 5.8, 6.3, 2.2, and 10.6 pg m^?3, respectively. The weak correlation coefficients between lnp (natural logarithm of partial pressure) and 1/T (reciprocal temperature) were obtained for DDTs and β-endosulfan (r² values ranged from 0.13 to 0.41). However, no significant correlations were obtained for HCHs and PCBs. These results suggested that both local emission and long-range atmospheric transport (monsoon) may influence the distribution of OCPs at Lhasa. In this study, peak concentrations of DDTs, endosulfans and PCBs were found in August, when Eastern Monsoon system occurred. However, the maximum concentrations of HCHs appeared in June (Indian Monsoon is the dominant air circulation pattern). Monthly variation of OCP/PCB levels was likely associated with the different air sources of monsoon system.     

基于行为安全的建筑事故预防量化方法与实证研究

在阐述安全行为(BBS)预防事故原理及其应用效果的基础上,选取某工程项目作为试验对象,结合我国建筑业一线工人的特点,对BBS实施中的培训方法、关键行为确认、观察方法3个关键环节进行具体试验。试验中建立了行为变化指数的图线,使用了安全行为指数(SI)来评定一线工人的安全行为及变化趋势。试验结果显示施工现场一线工人作业过程中的SI比基线期提高15%,表明所设计的BBS方法对于提高施工现场一线工人的行为安全性具有明显的效果。