基于地理探测器的土地开发度时空差异及其驱动因素

土地开发度（LDD）是衡量区域人类活动对土地开发利用的程度。分析土地开发度的时空差异和驱动机制能更加深刻的认识人类活动与区域土地利用之间的关系,为研制区域差别化的土地管控政策提供依据。通过分析全国345个城市2009~2015年土地开发度的时空差异,并采用地理探测器探测其驱动因素及其空间差异。研究表明：（1）全国土地开发度从2009年的4.1%持续增加到2015年的4.47%,并在东、中、西3个区域上表现出显著的空间差异;（2）345个城市的土地开发度总体呈上升趋势,且呈现明显的空间差异。土地开发度高的城市主要在城市群集聚,并在长江经济带、丝绸之路经济带等区域表现较快增长。（3）全国土地开发度由投资驱动和人口驱动为主转变为产业驱动和人口驱动为主,东、中、西3个区域土地开发度的主导驱动因素有所差异。     

异形柱组合框架结构力学性能有限元对比分析

对钢筋混凝土异形柱承载力低、轴压比限值低、节点薄弱和抗震性能不理想等特点,将异形柱分别与型钢混凝土结构和钢管混凝土结构相结合,基于OpenSees建立三层两跨平面实腹式异形柱中框架模型,进行静力推覆分析和滞回性能分析,通过改变轴压比参数,获得结构滞回曲线和骨架曲线,进一步分析其承载力、延性和耗能等相关力学特性。研究结果表明:同钢筋混凝土异形柱框架相比,型钢混凝土异形柱框架和钢管混凝土异形柱框架的承载力和延性均有提高;随着轴压比增大,两种异形柱框架的弹性刚度基本不变,但荷载一顶点位移曲线下降段越陡而导致延性降低;同样配筋率下,钢管混凝土异形柱框架的承载力和延性均高于型钢混凝土异形柱框架,并且可以提高施工速度;相关研究成果可为科研和工程设计提供研究参考。     

Impact of climate factors on cyanobacterial dynamics and their interactions with water quality in South Taihu Lake,China

Cyanobacterial bloom events in South Taihu Lake cause serious water quality problems and disturb aesthetic view of lake’s environment. In this study, correlations between cyanobacterial blooms and hydro-meteorological factors, including water quality, temperature and precipitation were investigated. Results demonstrated that South Taihu Lake was heavily affected by cyanobacteria and the proliferation of cyanobacteria due to variations in hydro-meteorological factors and water quality conditions. Water quality parameters, including COD, NH₃-N, TN and TP improved significantly since 2008 even at an elevated cyanobacterial bloom situation. Correlation analyses have shown that the development of cyanobacterial density and chlorophyll a concentration was sensitive to a wider temperature variation. The optimum temperature for cyanobacteria was 20°C, while extremely low and high temperatures were found to suppress their growth. Moreover, unusual rainfall patterns were measured during the study period (2003–2009), which showed an adverse impact on cyanobacterial development. Findings from this study suggested that seasonal lake’s water quality monitoring; suitable treatment of cyanobacterial blooms and strict policy implementation can solve the water quality issues in highly eutrophic lakes like Taihu.     

Polyoxometalates for photocatalytic degradation of aqueous dyestuff solutions and quantitative structure–property relationship study on photolysis rate constants

Polyoxometalate, K₆TiW₁₁O₃₉Sn·7H₂O (TiW₁₁Sn), was synthesized and characterized. TiW₁₁Sn and K₆ZrW₁₁O₃₉Sn·12H₂O (ZrW₁₁Sn) were evaluated for their photocatalytic degradation of triarylmethane (brilliant green and acid blue 9), bisazo (C.I. reactive black 5), and monoazo dyestuffs (C.I. reactive red 24, C.I. reactive red 194, and C.I. reactive orange 5) with natural sunlight in homogeneous aqueous solutions. TiW₁₁Sn and ZrW₁₁Sn effectively and photocatalytically decolorized the dyestuffs. The TiW₁₁Sn- and ZrW₁₁Sn-mediated photocatalytic degradation of the dyestuffs involved a pseudo-first-order reaction and was modeled by Langmuir–Hinshelwood-type kinetics. The observed pseudo-first-order rate constants (K^/) of triarylmethane dyestuffs were generally bigger than that of the azo dyestuffs. Quantitative structure–property relationship models of the K^/ of the dyestuffs were developed using partial least-square regression. The cumulative variance of the dependent variable explained by the partial least-square components was > 0.753 for each optimal model. This value indicated that the model had good predictive ability and robustness. The K^/ values of the dyestuffs were related to the energy of the lowest unoccupied molecular orbital, and the most positive net atomic charges on a sulfur atom of dyestuffs. The linear correlation coefficients between the predicted and experimental values were all > 0.9950.     

全氟和多氟化合物替代品的研究进展

全氟和多氟化合物(per-and polyfluoroalkyl substances,PFASs)是一类新型持久性有机污染物(POPs),广泛应用于工业和人类日常生活用品中。此类化合物具有高能量的C-F共价键,因此具有优良的理化特性和生物稳定性。由于存在持久性、生物累积性、长距离迁移以及毒性等问题,长链PFASs(C7)已经成为全世界关注的焦点之一,寻找能够替代PFASs的新型化合物具有重要意义。本文介绍了几种可能替代PFASs的新型氟化替代品,PFASs替代品在各类环境介质中的分布、持久性、人体暴露及毒性等几个方面进行了综述,特别对目前存在的问题及今后的研究方向进行了讨论和展望,以期为PFASs替代品的环境污染及风险评估提供参考。     

Pollution of hazardous substances in industrial construction and demolition wastes and their multi-path risk within an abandoned pesticide manufacturing plant

Exploration of heavy metals and organic pollutants, their leaching capacity along with health and environmental risks in contaminated industrial construction and demolition waste (ICDW) within a pesticide manufacturing plant were investigated. A maximum content of 90.8 mg?kg^–1 Cd was found present in the wastes, which might originate from phosphorus rocks and industrial sulfuric acid used in pesticide production processes. An average concentration of 979.8 mg?kg^–1 dichlorovos and other 11 organophosphorus pesticide were also detected. Relatively high leaching rates of around 4.14‰were obtained from laboratory simulated ICDW using both glacial acetic acid-sodium hydroxide and deionized water. Pesticide pollutants had the strongest tendency to retaining on dry bricks (leaching rate 1.68‰) compared to mortar-coatings, etc. due to their different physical characteristics and octanol-water partioning coefficient. Mobility of pesticide from on-site ICDW by water was spatially correlated to waste types, process sections and human activities, with a flux of leaching rate between 5.9‰ to 27.4%. Risk-based corrective action (RBCA) model was used to simulate the risk of contaminated ICDW debris randomly scattered. Oral and dermal ingestion amount by local workers was 9.8 × 10^–3 and 1.9 × 10^–2 mg?(kg?d)^–1, respectively. Potential leaching risk to aquatic systems exceeded the limit for nearly 75% waste. Environmental and health risk exceedance was found in most ICDW, while the risk value of the most severely contaminated brick waste was 660 times beyond critical level. Implications for waste management involving construction and deconstruction work, waste transferring and regulation supplying were also provided.

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酸浸出法回收冶金污泥中的有价金属

采用二次酸浸出的方法回收镍钴湿法冶金工业污泥中的有价金属。先采用水和硫酸作为浸出剂浸出Mg和Na,最佳工艺条件为浸出液的pH 7.5、浸出时间5 min、浸出剂体积与干污泥质量的比(ω)为10 mL/g。再采用硫酸作为浸出剂、焦亚硫酸钠作为还原剂进行二次酸浸,在硫酸与污泥质量比为1.3、焦亚硫酸钠与污泥质量比为0.3、ω为5 mL/g、浸出温度85℃、浸出时间20 min的最佳工艺条件下,Co、Ni、Cu、Mn和Zn的浸出率分别达92.45%、93.48%、89.52%、97.78%和94.79%。经XRD表征,浸出后污泥中未见原污泥中的矿物相,说明原污泥中的矿物几乎全部被溶解。     

黄河流域区域发展优势与经济带生成可能

基于进化经济学和进化经济地理学的理论,文章重点讨论了黄河流域的区域发展优势和建成黄河流域经济带的可能性。研究从黄河流域发展的历史出发,论证了黄河流域经济发展的区域地理学本性(nature)条件和现实可能性:第一,黄河流域经济发展的区域地理学本性条件是,该区域已经完成了农业经济建设,出现了遍在性的工业化和经济区人口聚集,特别是经过长期聚集,黄河流域已经形成了中国的人口密集带,形成了具有区域发展优势的中原城市群。第二,在分析黄河流域区域发展优势基础上,提出建成“大中原-黄河经济带”的可能性及其发展途径,即在生态保护的前提下,坚持地理环境的鲁棒性建设,坚持城市创新发展,坚持发展新型产业。第三,地区发展政策重点应该关注中原城市群的工业化-城市化发育和一体化产业链的形成,根据新经济地理学理论,提倡城市产业专业化方向,打破省界限制,发挥经济区的地缘结构优势,在空间上与环渤海经济带融合,完成黄河流域经济带高质量发展的战略构想。     

近地层氮氧化物和臭氧的区域分布研究

介绍了近地层氮氧化物和臭氧的区域分布研究方法,使用简化的区域尺度大气污染物传输模型和光化学反应模型,模拟计算了1990年中国主要城市排放氮氧化物的情景下,夏季(7月)主要城市的氮氧化物和相应的臭氧在近地层的浓度分布。      

人工神经元网络辅助酚类化合物构效关系研究

分子连接性指数（^tXv）与在正辛醇和水之间的分配系数logP是反映化合物性能的重要结构参数。本文计算了酚类化合物的分子连接性指数及分配系数,运用新型的模式识别方法──人工神经元网络对酚类化合物的构效关系进行了研究。所得结果优于逐步判别法,对于预测未知化合物的毒性,具有重要意义。