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451.
Kazuharu Yoshizuka Syouhei Nishihama Hideki Sato 《Environmental geochemistry and health》2010,32(4):297-302
The objective of this study was to survey the cation and anion contents of geothermal waters to gather fundamental information
on geographical variations. Sixteen sites in hot spring areas on the island of Kyushu in Japan were studied. The study focused
on the arsenic content of the samples. Very high arsenic concentrations (more than 0.1 mg/l) were detected in most of the
geothermal waters sampled. High contents of boron and fluoride (more than 1.0 mg/l) were also detected in some samples. Arsenic
removal was performed on a laboratory scale using columns packed with a magnetite-type adsorbent. The reduction of arsenic
contamination to a concentration of less than 0.01 mg/l could be achieved in the early stages of adsorption (bed volume = 200). 相似文献
452.
Environmentally Friendly Polyurethane Composites: Preparation, Characterization and Mechanical Properties 总被引:1,自引:0,他引:1
J. L. Zhang D. M. Wu D. Y. Yang F. X. Qiu 《Journal of Polymers and the Environment》2010,18(2):128-134
The waterborne polyurethane (PU) prepolymer was prepared based on isophorone diisocyanate (IPDI), polyester polyol (N220), dimethylol propionic acid (DMPA) and hydroxyethyl methyl acrylate (HEMA). The modified waterborne polyurethane–acrylate (PUA) emulsions were obtained with different proportions of acrylate (butyl acrylate and methyl methacrylate) and initiating agent by in situ dispersion technique. The structures and thermal properties of prepared PU and PUA were analyzed and characterized with FT-IR, UV–Vis spectroscopy and DSC. The PUA hybrid samples had lower glass transition temperature of hard segment and higher decomposition temperatures than PU sample. Performances of the emulsion and film were studied by means of apparent viscidity, particle size and polydispersity, surface tension and mechanical properties. The results indicated that the particle sizes of the PUA dispersions were larger than those of the pure PU and the solvent resistance, mechanical properties of PUA films was improved compare with the unmodified polyurethane film. The film had the biggest hardness and the least water absorption when the BA/MMA mass ratio 5:5 modified PU. The obtained PUA have great potential application such as coatings, leather finishing, adhesives, sealants, plastic coatings and wood finishes. 相似文献
453.
454.
Maria J. Ferreira Manuel F. Almeida Sílvia C. Pinho Isabel C. Santos 《Waste management (New York, N.Y.)》2010,30(6):1091-1100
Due to the amounts of chromium in the leachate resulting from leather leaching tests, chromium sulfate tanned leather wastes are very often considered hazardous wastes. To overcome this problem, one option could be recovering the chromium and, consequently, lowering its content in the leather scrap. With this objective, chromium leather scrap was leached with sulfuric acid solutions at low temperature also aiming at maximizing chromium removal with minimum attack of the leather matrix. The effects of leather scrap dimension, sulfuric acid and sodium sulfate concentration in the solutions, as well as extraction time and temperature on chromium recovery were studied, and, additionally, organic matrix degradation was evaluated. The best conditions found for chromium recovery were leather scrap conditioning using 25 mL of concentrated H2SO4/L solution at 293 or 313 K during 3 or 6 days. Under such conditions, 30–60 ± 5% of chromium was recovered and as low as 3–6 ± 1% of the leather total organic carbon (TOC) was dissolved. Using such treatment, the leather scrap area and volume are reduced and the residue is a more brittle material showing enhanced anaerobic biodegradability. Although good recovery results were achieved, due to the fact that the amount of chromium in eluate exceeded the threshold value this waste was still hazardous. Thus, it needs to be methodically washed in order to remove all the chromium de-linked from collagen. 相似文献
455.
NOËLLE F. KÜMPEL E. J. MILNER‐GULLAND GUY COWLISHAW J. MARCUS ROWCLIFFE 《Conservation biology》2010,24(3):861-871
Abstract: Results of many studies show unsustainable levels of bushmeat hunting across West/Central Africa. Nevertheless, these results are usually derived from snapshot sustainability indices in which critical parameters are often taken from the literature. Simple, more informative tools for assessing sustainability are needed. We evaluated the impact of bushmeat hunting across a range of temporal, spatial, and taxonomic scales in a comparison of different measures of sustainability. Over 15 months in 2002–2004 in and around a village close to Equatorial Guinea's Monte Alén National Park, we collected data via a village offtake survey, hunter‐camp bushmeat‐consumption diaries, hunter interviews, and following hunters during hunts. We compared 2003 data with a previous offtake survey (1998–1999) and interview reports back to 1990. In the past 14 years, average distance from the village at which hunters operated remained constant, with hunters switching back and forth between long‐established camps, although trapping effort increased. In the past 5 years, overall offtake and number of active hunters did not change substantially, although catch per unit effort (CPUE) decreased slightly. Although the proportion of the two most commonly trapped species (Cephalophus monticola and Atherurus africanus) and gun‐hunted primates increased in the offtake, species presumably less robust to trapping decreased slightly. Apparent sustainability in economic terms may be masking gradual local extirpation of more vulnerable species before and during this study. Our results suggest that changes in prey profiles and CPUE may be the most accurate indicators of actual sustainability; these indices can be monitored with simple village‐based offtake surveys and hunter interviews to improve community management of bushmeat hunting. 相似文献
456.
M. S. Zaman E. W. Hupp F. E. Lancaster 《Journal of environmental science and health. Part. B》2013,48(5):621-638
Abstract Effects of ionizing radiation on brain myelination and some physical development parameters were studied in laboratory rats (Fisher F‐344 inbred strain). Rats were treated with three different doses of radiation (150 rad, 15 rad, and 6.8 rad) delivered on the 20th day of prenatal life. Exposure to 150 rad reduced body, brain, ovary, kidney, heart and spleen weights. Prenatal exposure to 150 rad of radiation reduced the cerebral cortex weight by 22 percent at 30 days of age, and 20 percent at 52 days of age which caused a reduction in cerebral cortex myelin content by 20 and 23 percent at the ages of 30 and 52 days respectively. This dose did not affect the myelin content of the cerebellum or the brain stem, or the myelin concentration (mg myelin/g brain tissue) of the cerebral cortex, cerebellum, and the brain stem. The cerebral cortex weight of the 15 rad treated rats was reduced at the age of 30 days. Exposure to 15 rad, and 6.8 rad did not affect either the myelin content or the myelin concentration of these brain areas. 相似文献
457.
A. P. Altshuller S. L. Kopczynski D. Wilson W. Lonneman F. D. Sutterfield 《Journal of the Air & Waste Management Association (1995)》2013,63(10):791-794
Effects associated with photochemical air pollution were measured during irradiation of n-butane-nitrogen oxide or n-butane-ethane-nitrogen oxide mixtures, with small amounts of propylene or toluene added. The effects measured including nitrogen dioxide and oxidant dosages, yields of formaldehyde and peroxy-acetyl nitrate, and eye irritation response. The results obtained clearly show that beneficial effects result from selective changes in hydrocarbon composition as well as from reduction of total hydrocarbon concenfration. Exclusion of olefins and alkylbenzenes was highly effective in reducing oxidant dosage, formaldehyde and peroxyacetyl nitrate concentrations, and eye irritation response. The only penalty was a modest increase in nitrogen dioxide dosage. A large reduction in nitrogen oxide concentration reduced nitrogen dioxide dosage and eye irritation response, but with the penalty of a large increase in oxidant dosage. The desirability of preferentially reducing olefins and alkylbenzenes rather than paraffinic hydrocarbons, acetylene, and benzene is strongly supported by this study. Research and development efforts should be directed toward preferential hydrocarbon control by mechanical or catalytic control 相似文献
458.
F. Pacifico S.P. Harrison C.D. Jones S. Sitch 《Atmospheric environment (Oxford, England : 1994)》2009,43(39):6121-6135
Biogenic volatile organic compounds (BVOCs) play an important role in atmospheric chemistry and the carbon cycle. Isoprene is quantitatively the most important of the non-methane BVOCs (NMBVOCs), with an annual emission of about 400–600 TgC; about 90% of this is emitted by terrestrial plants. Incorporating a mechanistic treatment of isoprene emissions within land-surface schemes has recently become a focus for the modelling community, the aim being to quantify the potential magnitude of associated climate feedbacks. However, these efforts are hampered by major uncertainties about why plants emit isoprene and the relative importance of different environmental controls on isoprene emission. The availability and reliability of observations of isoprene fluxes from different types of vegetation is limited, and this also imposes constraints on model development. Nevertheless, progress is being made towards the development of mechanistic models of isoprene emission which, in conjunction with atmospheric chemistry models, will ultimately allow improved quantification of the feedbacks between the terrestrial biosphere and climate under past and future climate states. 相似文献
459.
The Role of Disaggregation of Asset Values in Flood Loss Estimation: A Comparison of Different Modeling Approaches at the Mulde River,Germany 总被引:3,自引:0,他引:3
Anja Wünsch Ulrich Herrmann Heidi Kreibich Annegret H. Thieken 《Environmental management》2009,44(3):524-541
In loss estimation there is a spatial mismatch of hazard data that are commonly modeled on an explicit raster level and exposure
data that are often available only for aggregated administrative units. Usually disaggregation methods that use ancillary
information to distribute lumped exposure data in a finer spatial resolution help to bridge this gap. However, the actual
influence of different mapping techniques and ancillary data on the final loss estimation has not been analyzed yet. In this
paper three methods are applied to disaggregate residential building assets using two kinds of land use/land cover (LULC)
data. The resulting disaggregated assets are validated and compared using census data of the residential building number on
the community and constituency level. In addition, the disaggregated assets are taken to estimate residential building losses
due to the flood in August 2002 in 21 municipalities on the River Mulde in Saxony, Germany. Losses are calculated with the
help of four loss models. In general, disaggregation helps to decrease the error variance within the loss estimation. It must,
however, be stated that the application of sophisticated disaggregation methods does not lead to significant improvements
compared to the straightforward binary method. Therefore more effort should instead be put into the provision of high-resolution
LULC data. Finally, the remaining uncertainties in loss estimation are high and demand further improvements in all modeling
aspects. 相似文献
460.