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101.
Polychlorinated biphenyl (PCB) congeners were analyzed by high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) of whole blood samples taken from 24 healthy adult Japanese volunteers (12 males and 12 females; age range 25–46 years). On average, 95 PCB congeners were detected in whole blood samples. The mean of total PCB concentration in whole blood was 771.9 pg g–1 whole blood (139.6 ng per g-lipid). Congener-specific analysis identified the predominant PCB congeners as #153 (22.2), #180 (11.6), #138 (8.4), #182/187 (6.6), #118 (5.6), #163/164 (5.0), #99 (3.9), #74 (3.6), #146 (3.3), #170 (3.0) and #156 (2.2), representing 75.6 of all PCBs detected in the human blood samples. Among the predominant PCB congeners, #153, #180, #138, #187 #118, #99 and #74 had chlorine as the substituent at the 2-, 4- and 5- positions of the phenyl-ring. In human blood in Japanese individuals, it is assumed that these congeners would be characteristic of the entire population, based on the relation between PCB ingestion and metabolism. Measuring 209 PCB congeners has the advantage of providing detailed information regarding the congener distribution within the blood samples, which can be compared to congener patterns in other matrices. Congener-specific analysis of 209 PCB congeners is especially useful in evaluating human exposure to PCBs. 相似文献
102.
Homologue and isomer patterns of polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF) in CuCl2-catalyzed formation were studied in an isothermal flow reactor using a distribution of 20 phenols as measured in municipal waste incinerator (MWI) exhaust gases. A mixture of 20 phenols was synthesized and used as reactants for this study because phenols are known to be key precursors in the formation of PCDD/F. Experiments were conducted at 400 degrees C. The 92% of nitrogen (N2) and 8% of oxygen (O2) were used as a carrier gas. PCDD/F homologue and isomer patterns with dibenzo-p-dioxin (DD) and dibenzofuran (DF) were obtained from a mixture of 20 phenols. DF+PCDF formation was favored over DD+PCDD formation. The major homologue groups formed were non-chlorinated DD and DF, and PCDD/F homologue fraction decreased with the degree of chlorination. PCDD/F homologue and isomer distributions were almost constant. Phenol and lower chlorinated phenols present in high amount played an important role in PCDD/F congener distributions. The results presented here can be used as characteristics or fingerprints for homologue and isomer patterns of PCDD/F formation attribution in CuCl2-catalyzed reaction from phenols. 相似文献
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105.
Effectsofsulfurdioxideongrowth,gasexchangerateandleafsulfurcontentofmassionpineseedlingsYangLiangUnitedGraduateSchool,TokyoUn... 相似文献
106.
To determine the fetal sex on 30 women who were 16–20 weeks pregnant, about 100 000 maternal blood nucleated cells were analysed by means of fluorescence in situ hybridization (FISH) with a Y-chromosome-specific DNA probe. Cells with the hybridization signal were detected in 12 of the 30 women. All the 12 mothers gave birth to a male child. Of the other 18 women who had no Y-positive cells in the peripheral blood, 14 gave birth to a female child and four gave birth to a male child. These false-negative results probably occurred because the number of cells examined was inadequate. The data obtained in this study suggest that fetal sex determination using maternal peripheral blood with FISH is possible and that this diagnostic method will be clinically useful when more cells are analysed. 相似文献
107.
Kentaro Hayashi Takeshi TokidaToshihiro Hasegawa 《Agriculture, ecosystems & environment》2011,144(1):117-123
The present study aimed to investigate the potential ammonia (NH3) emission from flag leaves of paddy rice (Oryza sativa L. cv. Koshihikari). The study was conducted at a paddy field in central Japan that was designed as a free-air CO2 enrichment (FACE) facility for paddy rice. A dynamic chamber method was used to measure the potential NH3 emissions. The air concentrations of NH3 at two heights (2 and 6 m from the ground surface) were measured using a filter-pack method, and the exchange fluxes of NH3 of the whole paddy field were calculated using a gradient method. The flag leaves showed potential NH3 emissions of 25-38 ng N cm−2 h−1 in the daytime from the heading to the maturity stages, and they showed potentials of approximately 22 ng N cm−2 h−1, even in the nighttime, at the heading and mid-ripening stages. The exchange fluxes of NH3 of the whole paddy field in the daytime were net emissions of 0.9-3.9 g N ha−1 h−1 whereas the exchange fluxes of NH3 in the nighttime were approximately zero. 相似文献
108.
Comparative studies on polycyclic aromatic hydrocarbon (PAH) pollution in residential air of Hangzhou (China) and Shizuoka (Japan) were conducted in summer (August, 2006) and winter (January, 2007). Total concentrations of 8 PAHs ranged from 7.1 to 320 ng/m3 and 0.15 to 35 ng/m3 in residential air of Hangzhou and Shizuoka, respectively. Air PAH concentrations in smoking houses were higher than that in nonsmoking houses. In nonsmoking houses, mothball emission and cooking practice were the emission sources of 2- and 3-ring PAHs in Hangzhou, respectively. The 2- and 3-ring PAHs were from use of insect repellent, kerosene heating and outdoor environment in nonsmoking houses in Shizuoka. The 5- and 6-ring PAHs in residential air were mainly from outdoor environment in both cities. Toxicity potencies of PAHs in residential air of Hangzhou were much higher than that in Shizuoka. 相似文献
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110.
Takeshi?TakegakiEmail author Takashi?Kaneko Yukio?Matsumoto 《Die Naturwissenschaften》2012,99(4):285-289
Sneaking tactic, a male alternative reproductive tactic involving sperm competition, is generally adopted by small individuals
because of its inconspicuousness. However, large size has an advantage when competition occurs between sneakers for fertilization
of eggs. Here, we suggest that both large- and small-size advantages of sneaker males are present within the same species.
Large sneaker males of the dusky frillgoby Bathygobius fuscus showed a high success rate in intruding into spawning nests because of their advantage in competition among sneaker males
in keeping a suitable position to sneak, whereas small sneakers had few chances to sneak. However, small sneaker males were
able to stay in the nests longer than large sneaker males when they succeeded in sneak intrusion. This suggests the possibility
of an increase in their paternity. The findings of these size-specific behavioural advantages may be important in considering
the evolution of size-related reproductive traits. 相似文献