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421.
Ming-Hong Wu Liang Tang Gang Xu Jing Ma Ning Liu Liang Wang Jian-Qiu Lei 《Environmental science and pollution research international》2013,20(4):2651-2660
Fourteen and 17 sediment samples were collected from three main rivers of Shanghai in July and November, respectively. Eight polybrominated diphenyl ether (PBDE) congeners (BDE-28, BDE-47, BDE-99, BDE-100, BDE-153, BDE-154, BDE-183, and BDE-209) were detected in these samples to clarify the pollution status in the metropolis. Instrumental analyses showed that the concentrations of ∑8PBDEs ranged from 10.97 to 64.05 ng/g dry weight (dw), with an average value of 29.71 ng/g dw. BDE-209 was the predominant congener accounting for more than 97 % of total PBDEs, followed by BDE-47 and BDE-99. Remarkable spatial and seasonal distributions of PBDE concentrations were observed, suggesting that local sources, seasonal climates, and hydrologic conditions might be the influencing factors. Moderate correlations (r 2?=?0.28–0.51, p?<?0.05) were found between total organic carbon and PBDEs, which indicated that organic carbon content influenced the distributions of PBDEs in sediment of Shanghai at some extent. Hazard quotients revealed PBDEs posed no potential risk to benthic organisms in the study area at present. 相似文献
422.
Xian-De Xie Xiao-Bo Min Li-Yuan Chai Chong-Jian Tang Yan-Jie Liang Mi Li Yong Ke Jie Chen Yan Wang 《Environmental science and pollution research international》2013,20(9):6050-6058
Floatation tailings (FT) are the main by-products of the hydrothermal sulfidation–flotation process. FT (FT1 and FT2) were obtained by treating two different neutralization sludges (NS) (NS1 and NS2). This paper quantitatively evaluated the environmental risks of heavy metals (Zn, Cd, Cu, Pb, and As) in FT versus NS. The total concentration and leaching rates (R 2) of heavy metals in FT were much lower than those in NS, demonstrating that the hydrothermal sulfidation–flotation process was able to effectively suppress the mobility and leachability of heavy metals. The BCR-three sequence leaching procedure of FT confirmed that all metals were transformed into more stable forms (residue and oxidizable forms) than were found that in NS. The potential ecological risk index indicated that the overall risks caused by heavy metals decreased significantly from 6627.59 and 7229.67 (very serious risk) in NS1 and NS2, respectively, to 80.26 and 76.27 (low risk) in FT1 and FT2, respectively. According to the risk assessment code, none of the heavy metals in FT posed significant risk to the natural environment except Zn (with low risk). In general, the risk of heavy metals in FT had been well controlled. 相似文献
423.
污泥中重金属的稳定化研究进展与去除方法简述 总被引:1,自引:0,他引:1
通过"十一五"污水处理厂的建设,我国污泥产量也随之大幅增长,污泥的处理处置已经成为制约社会经济发展的重要问题。国际上的经验表明土地利用是污泥最终处置的主要发展方向,然而污泥中的重金属成为其土地利用的主要障碍。越来越多的研究者意识到,重金属的环境危害不仅仅取决于其总量,更取决于重金属存在形态。目前,Tessier分步提取法作为主流的污泥重金属划分方法,取得了广泛应用,该法将污泥中的重金属分成5种形态,分别为可交换态、碳酸盐结合态、铁锰氧化物结合态、有机结合态和残渣态。本文以此为基础综述了目前国内外主要的污泥重金属稳定和去除方法的原理及研究进展,比较了不同重金属稳定及去除方法的优点与不足,并提出了新的展望。 相似文献
424.
在我国提出大力发展乡村旅游的背景下,乡村旅游已成为社会主义新农村建设和城乡统筹发展的主要内容,并成为解决“三农”问题的一条重要途径。由于乡村旅游良好的“城乡联动”机制和广阔发展前景,将成为重庆城市带农村发展的重要举措。但从旅游学的角度看,乡村旅游产品具有一般旅游产品的特征,其发展历史较短而速度过快,已出现了众多棘手的问题。通过对重庆市乡村旅游资源及其发展现状分析,对发展中存在的问题进行了重点分析,从规划编制、精品培育、设施完善、资源保护、市场拓展、人才培养、示范带动等方面对乡村旅游发展对策进行了探讨。 相似文献
425.
Xiaojiao Chen Minjian Chen Bo Xu Rong Tang Xiumei Han Yufeng Qin Bin Xu Bo Hang Zhilei Mao Weiwei Huo Yankai Xia Zhengfeng Xu Xinru Wang 《Chemosphere》2013
Widespread use of phenols has led to ubiquitous exposure to phenols. In experimental animals, phenols increased resorptions, reduced live litter size and fetal body weights. However, there are limited epidemiological evidences of the relationships between exposure to phenols and pregnancy outcomes. We evaluated the associations between parental urinary levels of various phenols and spontaneous abortion in a Chinese population residing in the middle and lower reaches of the Yangtze River. A case-control study was conducted that included 70 case couples with medically unexplained spontaneous abortion and 180 control couples who did not have a history of spontaneous abortion and had at least one living child. Both parental urinary phenols were measured by ultra-high performance liquid chromatography-tandem mass spectrometry including bisphenol A (BPA), benzophenone-3 (BP-3), 2,3,4-trichlorophenol (2,3,4-TCP), pentachlorophenol (PCP), 4-n-octylphenol (4-n-OP) and 4-n-nonylphenol (4-n-NP). Compared with the low exposure group, there was an increased risk of spontaneous abortion with high paternal urinary PCP concentration [odds ratio (OR) = 2.09, 95% Confidence Interval (CI), 1.05–4.14], and maternal exposure to 4-n-OP and alkylphenol(s) also significantly increased the risk of spontaneous abortion (OR = 2.21, 95% CI, 1.02–4.80; OR = 2.81, 95% CI, 1.39–5.65, respectively). Our study firstly provides the evidence that paternal PCP exposure, maternal 4-n-OP and alkylphenol(s) exposure are associated with spontaneous abortion in humans. 相似文献
426.
Zhiqiang Nie Zhenwu Tang Xiaohua Zhu Yufei Yang Haihui Fu Qingqi Die Qi Wang Qifei Huang 《Environmental science and pollution research international》2013,20(12):8751-8762
The concentrations, compositional profiles, and possible sources of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/PCDF) in water column and surface sediment samples from the lower reaches of the Yangtze River were investigated, and the potential risks posed by these chemicals were evaluated. Concentrations of the 17 2,3,7,8-substituted PCDD/PCDF in the water and sediment samples ranged from 0.45 to 10.0 pg TEQ/L (mean 2.34 pg TEQ/L) and from 0.31 to 51 pg TEQ/g dw (mean 5.25 pg TEQ/g dw), respectively. Water and sediments from the Nanjing–Nantong sections of the Yangtze River were found to have elevated PCDD/PCDF levels, and the PCDD/PCDF TEQ concentrations in 13 sediment samples exceeded the probable effect levels (PEL), above which adverse biological effects are likely. Multivariate statistical analysis indicated that the principal PCDD/PCDF contamination source for the water and sediment was the production and use of pentachlorophenol (PCP) or sodium pentachlorophenate (PCP-Na). PCDD/PCDF concentrations were stable over time near the Yangtze River Estuary but had increased sharply in recent decades in the Nanjing–Nantong section, which will have been related to the growth in industrial activities and other anthropogenic PCDD/PCDF sources. Total organic carbon (TOC) and PCDD/PCDF concentrations correlated significantly (R?=?0.474, P?<?0.01), suggesting that TOC plays an important role in the transport and re-distribution of PCDD/PCDF in the Yangtze River basin. 相似文献
427.
虚拟生态工业园(VEIP)是一种基于循环经济的新型的大循环生态工业组织形式,是对实体生态工业园的补充和扩展.而核心企业作为VEIP的组建者,是整个园区日常运营的信息指挥中枢,对VEIP的成功运营至关重要.分析了核心企业的内涵和应具备的特质,然后从核心企业的视角出发,给出了核心企业构建VEIP的一般流程,并阐述了核心企业在VEIP构建过程中的主要职能. 相似文献
428.
基于BP人工神经网络的城市PM2.5浓度空间预测 总被引:1,自引:0,他引:1
针对PM2.5日均质量浓度,采用BP人工神经网络模型,预测研究区空气中PM2.5浓度的空间变异,通过与普通克里格(Ordinary Kriging)插值方法对比验证BP人工神经网络预测模型的精度.结果表明:BP人工神经网络预测模型下研究区检验样本点位置的PM2.5仿真浓度与观测浓度之间的均方差、平均绝对误差、平均相对偏差和相关系数分别为0.296 μg2/m6、0.412 μg/m3、1.650%和0.851;而与此同时,普通克里格插值方法下的对应结果分别为1.041 μg2/m6、0.689 μg/m3、11.910%、0.638.研究成果在肯定BP人工神经网络预测模型可用于揭示PM2.5浓度空间变异特征的同时,也证实了其相对于普通克里格插值方法在固定空间点位准确预测PM2.5浓度方面的优势. 相似文献
429.
战场环境下单兵防常规炸弹爆炸抗震减震技术装备及器材,由于受经费投入、战场环境等因素影响,一直没有成功研制并得到装备.通过室内砂箱振动台震动模拟试验,测试了不同柔性散粒材料在震动条件下的加速度值,对其减震性能作了一些初步的探讨.通过研究,可以看到柔性散粒材料在隔震方面具有其他材料所不具有的优越性能,可以作为制造隔震器材的首选. 相似文献
430.