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991.
生物接触氧化法处理选矿废水的影响因素 总被引:1,自引:0,他引:1
选矿废水主要来源于有色金属矿山,具有水量大、悬浮物浓度高、重金属浓度高、有机浮选药剂浓度高等明显特征。选矿废水若直接排放,对环境的危害相当大。采用生物接触氧化法对模拟选矿废水进行了处理实验研究,考察了不同工艺条件对苯胺黑药、黄药及乙硫氮等浮选药剂去除效果的影响,结果表明:接触氧化反应器的最佳停留时间为8 h,进水最佳pH为6~7,葡萄糖投加量为0.1 mg/L时,降解效果达到最佳;此外,接触氧化反应器中微生物承受硫化物的浓度可达到120 mg/L。 相似文献
992.
Lei Chen Chaofeng Shen Minmin Zhou Xianjin Tang Yingxu Chen 《Environmental science and pollution research international》2013,20(3):1842-1848
The ubiquitous dissolved organic matter (DOM) has an important influence on transformation of organic contaminants through the production of reactive substances, such as ?OH, 1O2, and 3DOM*. The photolysis of a higher chlorinated polychlorinated biphenyl (PCB) congener (2,2′,4,4′,5,5′-hexachlorobiphenyl, PCB 153) under simulated sunlight in presence of humic acid (HA) was investigated. Degradation of PCB 153 was accelerated significantly by the addition of HA, with a rate constant of 0.0214, 0.0413, and 0.0358 h?1 in the initial 18 h of irradiation in presence of 1, 5, and 20 mg/L HA, respectively. The main photodegradation products analyzed by gas chromatography mass spectrometry were 4-hydroxy-2,2′,4′,5,5′-pentaCB and 2,4,5-trichlorobenzoic acid. Main reactive species involved were determined by the electron spin-resonance spectroscopy, including 1O2 and ?OH. Special scavengers were added to elucidate the photolysis mechanisms. By using the specific scavengers, it turned out that ?OH accounted for 29.3 % of the degradation, and the intra-DOM reactive species (1O2, ?OH, and 3DOM*) accounted for 59.6 % of the degradation. Photo-transformation sensitized by DOM, which involves both aqueous and intra-DOM reactions of PCBs with reactive species, may be one of the most important mechanisms for natural attenuation of PCBs. 相似文献
993.
Food utilization and growth of the 5th and 6th instar Spodoptera litura Fabricius larvae, and its effect on reproduction potential was evaluated by feeding larvae diets with different doses of Ni for 3 generations. Dose-dependent relationships between Ni levels and food consumption and growth were variable with different larval developmental period and Ni exposure duration. RCR, AD and RGR of the 6th instar larvae were much more affected by Ni exposure than those of 5th instar larvae, and the effects were strongest in the 3rd generation. It was found that RCR was significantly stimulated after 1 and 20 mg kg−1 Ni exposure, while AD was significantly inhibited after 1, 5, 10 and 40 mg kg−1 Ni exposure. However, lower levels of Ni (?5 mg kg−1) significantly increased and higher levels of Ni (?10 mg kg−1) significantly decreased RGR. In 3 successive generations, 10 mg kg−1 Ni significantly increased the ECI and ECD of the 5th instar larvae, and 5 mg kg−1 Ni significantly increased the ECD of the 6th instar larvae. However, ECD were all significantly inhibited with 20 mg kg−1 Ni exposure. Results also revealed that durations of larvae were shortened at low levels of Ni, but extended at high levels of Ni. Fecundity was inhibited by the highest Ni doses in each generation, while improved by low Ni doses in the 3rd generation. Hatching rates in all treatments were significantly decreased in a Ni dose-dependent manner. Study indicated that effects of Ni on these parameters were predominant with the increasing Ni exposure period. 相似文献
994.
Anti-estrogenic activity in wastewater is gaining increased attention because of its endocrine-disrupting function. In this study, the level and removal efficiency by coagulation of anti-estrogenic activity in secondary effluents of domestic wastewater treatment plants were studied. Anti-estrogenic activity was detected in secondary effluent samples at a tamoxifen (TAM) equivalent concentration level of 0.38–0.94 mg-TAM L−1. Dissolved organic matters (DOM) with the molecular weight (MW) less than 3000 Da in hydrophobic acids (HOA) and hydrophobic neutrals (HON) fractions of the secondary effluent were the key fractions related to anti-estrogenic activity. Coagulation with FeCl3 and polyaluminium chloride (PAC) can remove the anti-estrogenic activity of the secondary effluents, but the removal efficiency was limited. The removal efficiency using FeCl3 coagulant was higher than that induced by PAC. Dissolved organic carbon was continuously removed with increased coagulant dose (0–120 mg L−1 FeCl3 or 0–60 mg L−1 PAC). However, the removal of anti-estrogenic activity was not enhanced further when the coagulant concentration was beyond a critical value (30 mg L−1 FeCl3 or 10 mg L−1 PAC). The highest removal of anti-estrogenic activity was about 36% by FeCl3 and 20% by PAC. Size exclusion chromatography results indicated difficulty in removing DOM with MW less than 3000 Da in the secondary effluent during coagulation even at a high coagulant concentration, which led to low removal efficiency of anti-estrogenic activity. 相似文献
995.
土体的导热系数是能源岩土工程设计与研究中重要的热物理参数。工程中土体常处于非饱和状态。非饱和土体的导热系数会影响地下结构物的力学性能、热交换效率以及整个热工结构的工作效率。为给能源岩土工程设计与研究提供可靠的热物理参数,通过室内单元试验测量了不同含水率和温度下砾砂、粉土和黏土的导热系数,研究这三种非饱和土体的导热系数与含水率、基质吸力和温度的关系。研究结果表明,三种非饱和土体的导热系数都随含水率的增加而增加,最后趋于稳定。砾砂导热系数增加的速率最快,粉土次之,黏土最小。相同含水率下,砾砂导热系数最大,粉土次之,黏土最小。粉土的导热系数与基质吸力密切相关,其关系曲线趋势近似土 水特征曲线。三种土体的导热系数均随温度的增加近似线性增加,但增加幅度仅为10-3级别,可忽略其影响。 相似文献
996.
针对石西油田各区块采出液水质成分复杂、自结垢趋势严重、水质不配伍等情况,开展采出水稳定性控制等问题的攻关研究,采用预催化—强化絮凝水处理技术思路,评价药剂体系,复配除硫型净水剂,消耗水中还原性物质,使采出水稳定性提高。并通过对采出水走向进行合理调配,实现了石南采出水100%有效回注,达到了采出水资源合理化利用的目的。 相似文献
997.
生物可降解络合剂聚天冬氨酸治理土壤重金属污染 总被引:5,自引:0,他引:5
土壤重金属污染会产生严重的生态环境问题,土壤淋洗技术可达到土壤修复的目的,其中络合剂的选择是达到安全、有效修复效果的关键.聚天冬氨酸(PASP)可生物降解,对环境安全.文章选择PASP作为重金属的络合剂,研究其修复土壤重金属污染的效果.结果表明,PASP对金属离子Cd、Zn和Ca均有较好的提取率,均超过50%,并且络合剂/重金属的摩尔比越高,提取效果越好,受pH的影响就越少,提取速率开始比较快,而后趋于平缓.在PASP络合物的形态分布中,在pH较低阶段,PASP-Cd络合物所占的比例较大,随着pH的升高,PASP-Zn和PASP-Ca的比例增加,同时微生物对聚天冬氨酸的降解作用对治理效果产生负面影响.PASP可作为环保型的络合剂,达到修复土壤重金属污染的目的. 相似文献
998.
999.
Western China has lagged a lot in terms of industrial structure and economic development, compared with the national average. And China announced its target of CO2 emission reduction, i.e. by 2020, CO2 emission per GDP will drop by 40–45% compared with 2005. The target will be incorporated into China’s long-term industrial planning. Against this background, this paper will make a comprehensive examination of the industrial development of Western China, aiming to discover a green and compatible way. First, we analyze the spatiotemporal evolution of regional industrial structure for the period 2000–2010. Second, we try to discover the industrial structure optimization path for Western China by employing the Vector Auto Regression model. Lastly, we try to provide some advice and suggestions for further industrial development in Western China. Our examination shows that further industrial development in Western China should pay full attention to resource conservation and recycling, and develop on a green and compatible path. 相似文献
1000.
Canhui Deng Qing Tang Zemao Yang Zhigang Dai Chaohua Cheng Ying Xu Xiaojun Chen Xiaoyu Zhang Jianguang Su 《Frontiers of Environmental Science & Engineering》2022,16(10):134