Humic acids (HAs) determine the distribution, toxicity, bioavailability, and ultimate fate of heavy metals in the environment. In this work, ten HA fractions (F1–F10) were used as adsorbent, which were sequentially extracted from natural sediments of Lake Wuliangsuhai, to investigate the binding characteristics of Cu2+ to HA. On the basis of the characterization results, differences were found between the ten extracted HA fractions responding to their elemental compositions and acidic functional groups. The characterization results reveal that the responses of ten extracted HA fractions to their elemental compositions and acidic functional groups were different. The O/C and (O + N)/C ratio of F1–F8 approximately ranged from 0.66 to 0.53 and from 0.72 to 0.61, respectively; the measured results showed that the contents of phenolic groups and carboxyl groups decreased from 4.46 to 2.60 mmol/g and 1.60 to 0.58 mmol/g, respectively. The binding characteristics of Cu2+ to the ten HA fractions were well modeled by the bi-Langmuir model; the binding behavior of Cu2+ to all the ten HA fractions were strongly impacted by pH and ionic strength. The FTIR and SEM-EDX image of HA fractions (pre- and post-adsorption) revealed that carboxyl and phenolic groups were responsible for the Cu2+ sorption on the ten sequentially extracted HA fractions process, which is the same with the analysis of the ligand binding and bi-Langmuir models Accordingly, the adsorption capacity of the former HA fractions on Cu2+ were higher than the latter ones, which may be attributed to the difference of carboxyl and phenolic group contents between the former and latter extracted HA fractions. Additionally, the functional groups with N and S should not be neglected. This work is hopeful to understand the environmental effect of humic substances, environmental geochemical behavior, and bioavailability of heavy metals in lakes.
Environmental Fluid Mechanics - Experimental tests were conducted on a rectangular flume with different grid-type dam grid sizes, channel slopes and debris flow bulk density. We use the Bernoulli... 相似文献
AbstractAndrographolide sodium bisulfite (ASB) widely used for intestinal infections and respiratory tract infections. It has been reported to frequently cause acute renal failure in clinical practice. The purpose of this study was to evaluate the nephrotoxicity and toxicokinetics in Sprague-Dawley rats after a single-dose injection of ASB administered at 100, 600, and 1000?mg/kg via intravenous tail injections. The concentrations in plasma and kidney microdialysates were analyzed by high-performance liquid chromatography. Blood urea nitrogen and creatinine levels in plasma were determined and toxicokinetic parameters were observed. In plasma and kidney, the elimination constant and clearance were decreased and the half-time was increased with increasing dose. Blood urea nitrogen and creatinine were positively correlated with ASB concentration indicating the potential for accumulation in kidney that can eventually lead to damage. 相似文献
Environmental Science and Pollution Research - Accurate quantification of the emission of CO2 from streams and rivers is one of the primary challenges in determining the global carbon budget... 相似文献
Environmental Science and Pollution Research - A recent work has shown that hydrophobic organic compounds solubilized in the micelle phase of some nonionic surfactants present substrate toxicity to... 相似文献
There are increasing attempts to define the measures of ‘dangerous anthropogenic inference with the climate system’ in context of Article 2 of the Framework Convention on Climate Change, due to its linkage to goals for stabilizing greenhouse gas concentrations. The criteria for identifying dangerous anthropogenic interference may be characterized in terms of the consequences of climate change. In this study, we use the water stress index (WSI) and agricultural net primary production (NPP) as indictors to assess where and when there might be dangerous effects arising from the projected climate changes for Chinese agricultural production. The results showed that based on HadCM3-based climate change scenarios, the region between the North China Plain and Northeast China Plain (34.25–47.75°N, 110.25–126.25°E) would be vulnerable to the projected climate change. The analyses on inter-annual variability showed that the agricultural water resources conditions would fluctuate through the period of 2001–2080 in the region under IPCC SRES A2 scenario, with the period of 2021–2040 as critical drought period. Agricultural NPP is projected to have a general increasing trend through the period of 2001–2080; however, it could decrease during the period of 2005–2035 in the region under the IPCC SRES A2 scenario, and during the period of 2025–2035 under IPCC SRES B2 scenario. Generally, while projected climate change could bring some potentially improved conditions for Chinese agriculture, it could also bring some critical adverse changes in water resources, which would affect the overall outcome. At this stage, while we have identified certain risks and established the general shape of the damage curve expressed as a function of global mean temperature increase, more works are needed to identify specific changes which could be dangerous for food security in China. Therefore, there is a need for the development of more integrated assessment models, which include social-economic, agricultural production and food trade modules, to help identify thresholds for impacts in further studies. 相似文献