载体对生物质油裂解镍基催化剂的性能影响

以改性处理的CaA分子筛、硅藻土和ZrO_2-CeO_2复合氧化物为载体,分别负载镍制备催化剂,并采用XRD、SEM、TPR、TG、FT-IR对催化剂的结构、形貌、表面酸中心种类、还原性能和积碳性能等进行了表征。结果表明,载体的种类影响催化剂性能,改性后的Ca A分子筛具有较大的比表面积和孔容,负载镍基催化剂表面具有较强的L酸和B酸中心,能与镍物种形成较强的相互作用,在生物质油催化裂解反应中表现出较好的活性,同时催化剂表面较强的酸中心也促进了积碳前驱物的形成;而Ni O/硅藻土催化剂和NiO/ZrO_2-CeO_2催化剂的酸中心强度相对较弱,影响了活性组分与载体的相互作用,活性组分在反应中烧结现象明显。     

Long-term trends in the Real real prices of primary commodities: Inflation bias and the Prebisch–Singer hypothesis

In his recent article on measuring the long-term trends in the real prices of primary commodities, Cuddington (2010) extends in several important respects our earlier efforts (Svedberg and Tilton, 2006) to correct real commodity price trends for biases in the Consumer Price Index and other deflators. First, he argues for a log-linear relationship between prices and time. Second, he proposes a simple and quick method for obtaining corrected price trends from the published but uncorrected estimates. Finally, he illustrates, for the case of copper and presumably for many other commodities as well, the difficulties of obtaining real price trends significantly different from zero when the log values of the price data contain a unit root, requiring the use of difference stationary models.We welcome these insights, which should improve and make easier efforts to estimate correctly real commodity price trends over the long run. We would stress, however, that it is still important to correct for the biases in inflation indices, notwithstanding the failure of difference stationary models to obtain long-run real price trends (both corrected and uncorrected) significantly different from zero.     

某滑坡坝坝后稳定性分析

某滑坡坝位于某拟建水电站的上游,在国家级自然保护区内,是著名的旅游景点,其安全性对旅游开发、工程建设和下游居民生命财产安全影响很大,为了评价该滑坡坝的稳定性,需要对其发生洪水漫坝和渍坝的可能性进行研究,论证其安全性。通过计算的各种工况表明,滑坡坝坝后(坝体靠下游部分)是稳定的,对电站建设和下游居民不会产生威胁,滑坡坝是稳定的,可以进行综合开发。本文研究思路对类似工程有一定的借鉴意义。     

中国茶叶中的氟近十年来的研究进展

主要对茶叶中氟的来源,氟含量,氟浸出率以及茶叶降氟措施研究作了详细的综述。大量的研究资料表明,土壤中的氟直接影响到茶叶中氟的含量,茶树吸收氟与土壤的pH值、有机质含量、粘粒含量、成土母质及土壤中的阳离子有关。大气污染影响茶叶氟含量主要是氟通过叶片气孔进入细胞,进而在茶树体内积累。水环境中氟的含量主要受土壤与大气环境的影响。茶叶中的氟含量随着叶片成熟度的增加而增加;茶叶等级越差,氟含量越高;原料粗老的茶类氟含量要比原料较嫩的茶类氟含量高;不同季节、茶树品种对氟吸收也存在差异性;茶树各部位氟累积强度依次为:叶>花蕾>籽>皮>细枝>骨干枝>细根>茎(主轴)>茎(主干)>主根>侧根;茶叶中氟浸出率与冲泡水温、冲泡时间、冲泡次数等有关。在茶叶加工过程中可以通过热水处理,添加化学试剂,改进生产工艺等措施来降低茶叶中的氟含量。此外,尚可以培育含氟量低的茶树品种。