Dissolved oxygen and its response to eutrophication in a tropical black water river

The Siak is a typical, nutrient-poor, well-mixed, black water river in central Sumatra, Indonesia, which owes its brown color to dissolved organic matter (DOM) leached from surrounding, heavily disturbed peat soils. We measured dissolved organic carbon (DOC) and oxygen concentrations along the river, carried out a 36-h experiment in the province capital Pekanbaru and quantified organic matter and nutrient inputs from urban wastewater channels into the Siak. In order to consider the complex dynamic of oxygen in rivers, a box-diffusion model was used to interpret the measured data. The results suggest that the decomposition of soil derived DOM was the main factor influencing the oxygen concentration in the Siak which varied between ～100 and 140 μmol l^?1. Additional DOM input caused by wastewater discharges appeared to reduce the oxygen concentrations by ～20 μmol l^?1 during the peak-time in household water use in the early morning and in the early evening. Associated enhanced nutrient inputs appear to reduce the impact of the anthropogenic DOM by favoring the photosynthetic production of oxygen in the morning. A reduction of 20 μmol l^?1, which although perhaps not of great significance in Pekanbaru, has strong implications for wastewater management in the fast developing areas downstream Pekanbaru where oxygen concentrations rarely exceed 20 μmol l^?1.     

A methodology for evaluating environmental planning systems: A case study of Canada

Sustainable environmental management is contingent on having an effective environmental planning system. A new methodology for designing and evaluating environmental planning systems is described and applied to a case study evaluation of the Canadian environmental planning process. The methodology is based on eight international best practice principles for environmental planning and 45 indicators. The research illustrates the benefits of the evaluation methodology in identifying how to improve environmental planning systems to achieve desired results. The methodology is applicable to a wide variety of jurisdictions.     

Research priorities for managing the impacts and dependencies of business upon food,energy, water and the environment

Delivering access to sufficient food, energy and water resources to ensure human wellbeing is a major concern for governments worldwide. However, it is crucial to account for the ‘nexus’ of interactions between these natural resources and the consequent implications for human wellbeing. The private sector has a critical role in driving positive change towards more sustainable nexus management and could reap considerable benefits from collaboration with researchers to devise solutions to some of the foremost sustainability challenges of today. Yet opportunities are missed because the private sector is rarely involved in the formulation of deliverable research priorities. We convened senior research scientists and influential business leaders to collaboratively identify the top forty questions that, if answered, would best help companies understand and manage their food-energy-water-environment nexus dependencies and impacts. Codification of the top order nexus themes highlighted research priorities around development of pragmatic yet credible tools that allow businesses to incorporate nexus interactions into their decision-making; demonstration of the business case for more sustainable nexus management; identification of the most effective levers for behaviour change; and understanding incentives or circumstances that allow individuals and businesses to take a leadership stance. Greater investment in the complex but productive relations between the private sector and research community will create deeper and more meaningful collaboration and cooperation.     

Digital sustainability: basic conditions for sustainable digital artifacts and their ecosystems

The modern age has heralded a shift from the industrial society, in which natural resources are crucial input factors for the economy, towards a knowledge society. To date, sustainability literature has treated knowledge—and in particular digital artifacts—mainly as a means to the end of achieving sustainable development. In this conceptual paper, we argue that digital artifacts themselves ought also to be considered as resources, which also need to be sustainable. While over-consumption is a problem facing natural resources, with sustainable digital artifacts, underproduction, and underuse are the biggest challenges. In our view, the sustainability of digital artifacts improves their potential impact on sustainable development. A theoretical foundation for digital artifacts and their ecosystem allows us to present the relevant research on digital information, knowledge management, digital goods, and innovation literature. Based on these insights, we propose ten basic conditions for sustainable digital artifacts and their ecosystem to ensure that they provide the greatest possible benefit for sustainable development. We then apply those characteristics to four exemplary cases: Linux kernel development, Bitcoin cryptocurrency, the Wikipedia project, and the Linking Open Drug Data repositories. The paper concludes with a research agenda identifying topics for sustainability scholars and information systems academics, as well as practitioners. A number of suggestions for future studies on digital sustainability are also put forward.     

The true distribution and accumulation of radiocaesium in stem of Scots pine (Pinus sylvestris L.)

The radial and vertical distributions of radiocaesium, potassium and calcium were determined in two Scots pine stands (17 and 58 yr old) similarly affected by the Chernobyl fallout. For both age classes, concentrations are always the lowest in the stemwood, highest in the inner bark and intermediary levels were observed for the outer bark. Due to the cumulative character of its biomass. however. stemwood is a long-term major reservoir of 137Cs. With tree development, changes in the 137Cs radial distribution are well described by variations in the sap ascent pattern and reveal an important transfer between tree rings. It is shown that. both the biomass evolution and knowledge of the evolution of the 137Cs radial gradient are important to predicting 137Cs accumulation in wood with time. According to the common transfer factor (TF) approach, one would expect a decrease in radiocaesium accumulation with time (from 0.0047 +/- 0.0013 to 0.0035 +/- 0.0008 m2kg(-1) for the 17 and 58 yr old trees, respectively). With the wood immobilisation potential (WIP) approach, it was, however, clearly shown that additional annual uptake was highest for the older stand (3.12 +/- 0.23 Bq cm(-3) yr(-1) for the 58-year-old stand compared to 1.99 +/- 0.30 Bq cm(-3) yr(-1) for the younger stand). Following the WIP approach, it was moreover possible to distinguish between the 137Cs incorporated via the root uptake process and a possible lasting effect of interception. It is shown that, whereas for the younger stand (5 yr old at the time of the accident) root uptake contributed exclusively to the wood contamination, the former process explained only 48% of the measured total 137Cs content in the wood of the older tree.     

An input-output balance study for PCBs in humans

Polychlorinated biphenyl (PCB) input-output balance studies were performed on five male volunteers, aged between 24 and 30, for periods of 8-14 days in 1998. Dietary exposure was quantified by the duplicate meals method and varied between 220 and 460 ng of sigmaPCB (sum of 20 congeners) per day for each of the five individuals over the study period. Dietary intake was dominated by congeners 118, 138, 153 and 180. Average faecal outputs for the five volunteers were 50-290 ng of sigmaPCB (sum of 20 congeners) per day for each of the five individuals over the same period and was dominated by the same four congeners. Whilst the total PCB fluxes were therefore into the body (i.e., accumulation), important differences were noted for different individual congeners. PCBs 44, 47, 49, 52, 60, 66, 101, 105, 110, 118, 149, 151 and 183 all showed net absorption for all five volunteers. Some congeners showed a net absorption in some of the individuals but net excretion in others, as seen by other workers. These congeners (PCBs 138, 153, 180, 187 and 194) are all higher chlorinated congeners and lack meta-para-vicinal hydrogen atoms. There were differences in the net absorption/excretion between individuals, which appeared to be a function of body fat index (BFI). The volunteers with the lowest BFIs showed net excretion for the greatest number of congeners, whilst the individual with the highest BFI was a net absorber of all the congeners studied. The problems in determining and interpreting absorption efficiency values for use in quantitative exposure assessments are discussed. Various factors that influence net absorption of PCBs and other persistent organic pollutants are identified. These include compound properties (including susceptibility to metabolism), the individual's fat status and balance, exposure history and diet.     

Spatial identification by satellite imagery of the crop–fallow rotation cycle in northern Laos

In the mountainous regions of northern Laos, shifting cultivation, or slash-and-burn agriculture, is widely practiced. However, the crop–fallow rotation cycle is becoming shorter owing to forest conservation policies and population pressure, causing loss of productivity that deleteriously affects farmers’ livelihoods in the region. To investigate regional land use conditions, we have developed a method of identifying the crop–fallow rotation cycle from Landsat Thematic Mapper (TM) and Enhanced Thematic Mapper+ (ETM+) data. We assessed the impact of the identified cycle on plant production measured by Normalized Difference Vegetation Index (NDVI). The study site was an area in Luang Prabang Province. Using eight TM and ETM+ images acquired annually from 1995 to 2003, except for 1998, when cloud-free data were not collected, we classified land use in each year as crop or fallow by the presence of vegetation in the late dry season. Conformity with fallow age determined by field investigation was 69.1%. The cultivation frequency from 1995 to 2002 showed that 77,000 ha (17.3% of the study site) had not been used for cropping during the period, but 41,000 ha (9.2%) had been used every year. Of the study site, 129,000 ha (29.1%) was cultivated one or two times, 83,000 ha (18.7%) was three or four times, and 54,000 ha (12.2%) was five or six times. The NDVI of crops in November did not provide sufficient evidence to prove the assumption that a longer fallow period would result in better crop yields. Instead, the regeneration of fallow vegetation was evidenced by the higher NDVI values after longer fallow. More than 8 years would be needed to reach the same NDVI as forest. From the produced maps indicating fallow age and cultivation frequency, we found that areas with high potential for regeneration decreased as cultivation frequency increased. Areas near rivers were intensively used, and fallow length was accordingly short. Low-potential areas were found in the western basin of the Mekong River. This spatial information can be used to detect areas where biomass productivity is at high risk of deteriorating. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

Brominated flame retardants and organochlorines in the European environment using great tit eggs as a biomonitoring tool

Large-scale studies are essential to assess the emission patterns and spatial distribution of organohalogenated pollutants (OHPs) in the environment. Bird eggs have several advantages compared to other environmental media which have previously been used to map the distribution of OHPs. In this study, large-scale geographical variation in the occurrence of OHPs, such as polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and organochlorine pesticides (OCPs), was investigated throughout Europe using eggs of a terrestrial residential passerine species, the great tit (Parus major). Great tit eggs from 22 sampling sites, involving urban, rural and remote areas, in 14 European countries were collected and analysed (5-8 eggs per sampling site). The environmentally most important congeners/compounds of the analysed pollutants were detectable in all sampling locations. For PCBs, PBDEs and OCPs, no clear geographical contamination pattern was found. Sum PCB levels ranged from 143 ng/g lipid weight (lw) to 3660 ng/g lw. As expected, PCB concentrations were significantly higher in the sampled urban compared to the remote locations. However, the urban locations did not show significantly higher concentrations compared to the rural locations. Sum PBDEs ranged from 4.0 ng/g lw to 136 ng/g lw. PBDEs were significantly higher in the urbanized sampling locations compared to the other locations. The significant, positive correlation between PCB and PBDE concentrations suggests similar spatial exposure and/or mechanisms of accumulation. Significantly higher levels of OCPs (sum OCPs ranging from 191 ng/g lw to 7830 ng/g lw) were detected in rural sampling locations. Contamination profiles of PCBs, PBDEs and OCPs differed also among the sampling locations, which may be due to local usage and contamination sources. The higher variance among sampling locations for the PCBs and OCPs, suggests that local contamination sources are more important for the PCBs and OCPs compared to the PBDEs. To our knowledge, this is the first study in which bird eggs were used as a monitoring tool for OHPs on such a large geographical scale.     

Occurrence and fate of pharmaceutical products and by-products,from resource to drinking water

Among all emerging substances in water, pharmaceutical products (PPs) and residues are a lot of concern. These last two years, the number of studies has increased drastically, however much less for water resources and drinking water than for wastewater. This literature review based on recent works, deals with water resources (surface or groundwater), focusing on characteristics, occurrence and fate of numerous PPs studied, and drinking water including water quality. Through this review, it appears that the pharmaceutical risk must be considered even in drinking water where concentrations are very low. Moreover, there is a lack of research for by-products (metabolites and transformation products) characterization, occurrence and fate in all water types and especially in drinking water.     

Quantifying summed fullerene nC60 and related transformation products in water using LC LTQ Orbitrap MS and application to environmental samples

The application of engineered nanomaterials increases strongly. Development of analytical techniques and their application to environmental samples is essential for human and environmental risk assessment of the nanoparticles. The objective of this study was to develop a sensitive analytical method to quantify nC(60) in water, using accurate mass screening liquid chromatography-hybrid linear ion trap Orbitrap mass spectrometry. nC(60) can be transformed by oxidation, reduction and photochemical reaction. Therefore, the formation of some transformation products of nC(60) was studied as well. Finally, the developed analytical method was applied to surface water samples from several locations in the Netherlands. The developed method enabled to detect and quantify aqueous concentrations of the summed nC(60) and its transformation products as low as 5 ng/L. It was observed that nC(60) transformation products exceed quantities of the parent C(60). Despite the high sensitivity of the developed method, no nC(60) or transformation products were detected in an array of Dutch surface waters. This might be due to low emissions, losses in the aqueous phase by sedimentation, sorption or further transformation processes.