全文获取类型
收费全文 | 3014篇 |
免费 | 42篇 |
国内免费 | 25篇 |
专业分类
安全科学 | 163篇 |
废物处理 | 154篇 |
环保管理 | 612篇 |
综合类 | 334篇 |
基础理论 | 725篇 |
环境理论 | 5篇 |
污染及防治 | 752篇 |
评价与监测 | 212篇 |
社会与环境 | 106篇 |
灾害及防治 | 18篇 |
出版年
2023年 | 21篇 |
2022年 | 37篇 |
2021年 | 26篇 |
2020年 | 21篇 |
2019年 | 31篇 |
2018年 | 66篇 |
2017年 | 67篇 |
2016年 | 89篇 |
2015年 | 58篇 |
2014年 | 84篇 |
2013年 | 280篇 |
2012年 | 143篇 |
2011年 | 177篇 |
2010年 | 120篇 |
2009年 | 122篇 |
2008年 | 154篇 |
2007年 | 187篇 |
2006年 | 152篇 |
2005年 | 105篇 |
2004年 | 104篇 |
2003年 | 116篇 |
2002年 | 89篇 |
2001年 | 67篇 |
2000年 | 46篇 |
1999年 | 51篇 |
1998年 | 38篇 |
1997年 | 43篇 |
1996年 | 43篇 |
1995年 | 40篇 |
1994年 | 41篇 |
1993年 | 34篇 |
1992年 | 37篇 |
1991年 | 26篇 |
1990年 | 29篇 |
1989年 | 19篇 |
1988年 | 13篇 |
1987年 | 20篇 |
1986年 | 25篇 |
1985年 | 17篇 |
1984年 | 18篇 |
1983年 | 28篇 |
1982年 | 28篇 |
1981年 | 25篇 |
1980年 | 19篇 |
1979年 | 16篇 |
1977年 | 11篇 |
1976年 | 9篇 |
1975年 | 9篇 |
1974年 | 10篇 |
1971年 | 11篇 |
排序方式: 共有3081条查询结果,搜索用时 343 毫秒
951.
A new all season passive sampling system for monitoring O3 in the atmosphere has been developed in the laboratory and validated in the field. The unique features for this system include a newly designed passive sampler and a rain shelter, which allow the passive sampler to be installed in the field facing downwards. An equation associated with meteorological parameters is used to calculate the passive sampling rates. This system has been extensively tested in the lab (temperature from –18 to 20°C, relative humidity from 13 to 81%, and wind speed from 0.5 to 150 cm/s) and validated in the field in climates of all seasons. The accuracy of the ozone concentrations in the atmosphere obtained with the use of the new passive sampling system was higher than 85% compared to those obtained with continuous ozone analyzers. The new ozone passive sampling system can be used to measure ambient O3 concentrations ranging from 3 ppb to 1000 ppb based on one-day exposure and 0.1 ppb to 140 ppb for a monthly exposure period. It is also reasonable to conclude that the new passive sampling system can be used for eight-hour exposure study because of the low field blanks and high sampling rates. 相似文献
952.
This study evaluated the spatial and temporal distribution of metals in the coral reef system Cayos Arcas and Triangulos in the Campeche Bank region, off the Yucatan peninsula in Mexico. No information has been generated before for the incorporation of natural and non-natural occurring metals, some of which are possibly endowed by the oil marine station Cayo Arcas. The multivariate exploratory study of the metals on the coral skeletons, showed the formation of two distinct groups. The metals that have the highest influence on the differentiation of the groups are the metals that are natural constituents of the coral skeletons, in particular Sr can explain much of the differences between the groups, and to a much lesser extent are the metals that could be indicators of pollution. This differentiation suggests that, in our case, the environment around the corals has a higher impact than the non-naturally occurring metals (and possible indicators of pollution). The two groups formed corresponded to: the coral cores influenced by open sea variables and the coral cores in the inner part of the keys which is less exposed to open sea variables. A chronological study was made to two samples that had the longest coral section and were situated in two clearly distinctive zones: an exposed surface subjected to high wave forces and another that was less exposed. Ni and Zn show an accumulation trend in both coral samples, while Ba showed an increase in incorporation around 1980 when the Cayo Arcas oil marine station was constructed. 相似文献
953.
The current study utilizes social identity theory to investigate employees' work hours. Specifically, we use meta‐analysis to examine the relationships between hours worked and indicators of organizational identity (e.g., organizational support and tenure), occupational identity (e.g., human capital investments and work centrality), and family identity (e.g., family responsibilities and family satisfaction). The meta‐analysis also allowed us to explore other important correlates of hours worked (e.g., situational demands, job performance, mental health, and physical health), moderating variables (e.g., age, gender, and job complexity), and curvilinear relationships of work hours to social identity indicators. Overall, we found that occupational factors and situational demands had the strongest relationships with hours worked, hours worked were negatively associated with measures of employee well‐being, gender had several significant moderating effects, and there were curvilinear relationships between hours worked and well‐being and work–family conflict variables. The article concludes with directions for future theoretical and empirical research. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
954.
In recent years there has been continuing interest in the potential hazards from detonations in pipelines. The interest has arisen in several instances due to the introduction of vapour recover systems, as part of measures to limit environmental emissions. These environmental pressures initially coincided with the preparation of new European-wide test procedures for explosion arrester devices and, more recently, moves to develop a new international ISO standard for the certification and approval of detonation arrester devices. It is an opportune time therefore to review current understanding of explosion development in pipelines and to consider the implications for plant design and explosion arrester selection and testing. 相似文献
955.
956.
Dairy operations have the potential to elevate dissolved organic carbon (DOC) levels in ground water, where it may interact with organic and inorganic contaminants, fuel denitrification, and may present problems for drinking water treatment. Total and percent bioavailable DOC and total and carbon-specific trihalomethane (THM) formation potential (TTHMFP and STHMFP, respectively) were determined for shallow ground water samples from beneath a dairy farm in the San Joaquin Valley, California. Sixteen wells influenced by specific land management areas were sampled over 3 yr. Measured DOC concentrations were significantly elevated over the background as measured at an upgradient monitoring well, ranging from 13 to 55 mg L(-1) in wells downgradient from wastewater ponds, 8 to 30 mg L(-1) in corral wells, 5 to 12 mg L(-1) in tile drains, and 4 to 15 mg L(-1) in wells associated with manured fields. These DOC concentrations were at the upper range or greatly exceeded concentrations in most surface water bodies used as drinking water sources in California. DOC concentrations in individual wells varied by up to a factor of two over the duration of this study, indicating a dynamic system of sources and degradation. DOC bioavailability over 21 d ranged from 3 to 10%, comparable to surface water systems and demonstrating the potential for dairy-derived DOC to influence dissolved oxygen concentrations (nearly all wells were hypoxic to anoxic) and denitrification. TTHMFP measurements across all management units ranged from 141 to 1731 microg L(-1), well in excess of the maximum contaminant level of 80 microg L(-1) established by the Environmental Protection Agency. STHMFP measurements demonstrated over twofold variation ( approximately 4 to approximately 8 mmol total THM/mol DOC) across the management areas, indicating the dependence of reactivity on DOC composition. The results indicate that land management strongly controls the quantity and quality of DOC to reach shallow ground water and hence should be considered when managing ground water resources and in any efforts to mitigate contamination of ground water with carbon-based contaminants, such as pesticides and pharmaceuticals. 相似文献
957.
Sandy beaches are the prime sites for human recreation and underpin many coastal economies and developments. In many coastal
areas worldwide, beach recreation relies on the use of off-road vehicles (ORVs) driven on the shore. Yet, the use of ORVs
is not universally embraced due to social conflicts with other beach user groups and putative environmental consequences of
vehicle traffic on sandy shores. Such ecological impacts of ORVs are, however, poorly understood for endobenthic invertebrates
of the intertidal zone seawards of the dunes. Consequently, this study quantified the degree to which assemblages of intertidal
beach invertebrates are affected by traffic. The study design comprised a series of temporally replicated spatial contrasts
between two reference sites (no ORVs) and two beaches with heavy ORV traffic (in excess of 250,000 vehicles per year) located
in South-East Queensland, Australia. Macrobenthic assemblages on ORV-impacted beaches had significantly fewer species at substantially
reduced densities, resulting in marked shifts in community composition and structure. These shifts were particularly strong
on the middle and upper shore where vehicle traffic was concentrated. Strong effects of ORVs were detectable in all seasons,
but increased towards the summer months as a result of heavier traffic volumes. This study provides clear evidence that ORVs
can have substantial impacts on sandy beach invertebrates that are manifested throughout the whole community. Demonstrating
such an ecological impact caused by a single type of human use poses a formidable challenge to management, which needs to
develop multi-faceted approaches to balance environmental, social, cultural, and economic arguments in the use of sandy shores,
including management of “beach traffic.” 相似文献
958.
Anthropogenic metal cycles in China 总被引:2,自引:0,他引:2
Tao Wang Jiansu Mao Jeremiah Johnson Barbara K. Reck Thomas E. Graedel 《Journal of Material Cycles and Waste Management》2008,10(2):188-197
The flows and stocks of seven important industrial metals were characterized for mainland China for several years in the dynamically
changing decade of 1994–2004. One-year snapshot cycles are provided for chromium, nickel, and silver. For copper, zinc, lead,
and iron, multiple-year cycles have been completed; they demonstrate that the flows of these metals into use in China doubled
between 2000 and 2004. Although the Chinese per capita flows from production to disposal are mostly shown to be below the
global average rate, they are increasing or are expected to increase dramatically. The metal resource efficiency is evaluated
for several indicators of material flow analysis; these metrics for China are also below the global average values. The research
quantitatively illustrates that China’s metal cycles may pose significant resource and environmental challenges in terms of
their magnitudes and potential for growth. 相似文献
959.
The use of spectroscopic techniques (especially phosphorus-31 nuclear magnetic resonance [(31)P-NMR] and X-ray absorption near edge structure spectroscopy) has recently advanced the analysis of the speciation of P in poultry litter (PL) and greatly enhanced our understanding of changes in P pools in PL that receive alum (aluminum sulfate) to reduce water-soluble P and control ammonia emissions from poultry houses. Questions remain concerning changes of P species during long-term storage, drying, or after application of PL to cropland or for other uses, such as turfgrass. In this study, we investigated a set of six PL samples (of which three were alum-amended and three were unamended) that had been characterized previously. The P speciation was analyzed using solid-state (31)P-NMR spectroscopy, and the mineralogy was analyzed by powder X-ray diffraction (XRD) after storing the samples moist and dried for up to 5 yr under controlled conditions. The magnesium ammonium phosphate mineral struvite was identified in all but one PL samples. Struvite concentrations were generally lower in dried samples (< or = 14%) than in samples stored moist (23 and 26%). The moist samples also had higher concentrations of phosphate bound to aluminum hydroxides. Solid-state NMR spectroscopy was in general more sensitive than XRD in detecting and quantifying P species. Although phosphate associated with calcium and aluminum made up a large proportion of P species, they were not detected by XRD. 相似文献
960.
This paper contributes with an applied policy analysis of the predator preservation policy in Sweden. We estimate the overall mean willingness to pay (WTP) for preserving the four large predators in the Swedish fauna by applying the contingent valuation method. Using survey data from 2004 we find that 50 percent of the Swedish population is willing to contribute financially toward implementation of the predator policy package, and that the estimated overall mean WTP is approximately SEK 290. Further, we test for spatial differences in attitudes and WTP and find that respondents in Stockholm have the highest overall mean WTP, while respondents living in wolf-territories have the lowest. Our mean WTP measure is flawed with upward bias, since we cannot estimate the willingness to accept for those with clearly negative preferences regarding the predator policy package (e.g. hunters). In this paper, we set their WTP equal to zero. Thus, we cannot rule out the possibility that the mean willingness to pay is, in fact, negative, i.e. the social-value of implementing the predator policy is negative. Finally, the estimates of the overall WTP are sensitive to response-uncertainty. When the respondents indicate uncertainty about their valuation, they tend to state higher values. 相似文献