全文获取类型
收费全文 | 2342篇 |
免费 | 290篇 |
国内免费 | 811篇 |
专业分类
安全科学 | 250篇 |
废物处理 | 90篇 |
环保管理 | 182篇 |
综合类 | 1674篇 |
基础理论 | 307篇 |
污染及防治 | 484篇 |
评价与监测 | 158篇 |
社会与环境 | 203篇 |
灾害及防治 | 95篇 |
出版年
2024年 | 13篇 |
2023年 | 64篇 |
2022年 | 171篇 |
2021年 | 149篇 |
2020年 | 150篇 |
2019年 | 102篇 |
2018年 | 97篇 |
2017年 | 125篇 |
2016年 | 119篇 |
2015年 | 135篇 |
2014年 | 168篇 |
2013年 | 219篇 |
2012年 | 200篇 |
2011年 | 190篇 |
2010年 | 167篇 |
2009年 | 164篇 |
2008年 | 162篇 |
2007年 | 159篇 |
2006年 | 199篇 |
2005年 | 142篇 |
2004年 | 86篇 |
2003年 | 78篇 |
2002年 | 66篇 |
2001年 | 46篇 |
2000年 | 56篇 |
1999年 | 39篇 |
1998年 | 21篇 |
1997年 | 25篇 |
1996年 | 27篇 |
1995年 | 16篇 |
1994年 | 26篇 |
1993年 | 19篇 |
1992年 | 9篇 |
1991年 | 9篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1982年 | 3篇 |
排序方式: 共有3443条查询结果,搜索用时 234 毫秒
871.
872.
873.
874.
基于GPRS的环境在线监测系统设计 总被引:6,自引:0,他引:6
介绍了在Delphi环境下,利用Socket控件,通过GPRS网络实现GPRS DTU和上位机之问的通信;采用力控PcAuto组态软件设计上位机监控画面;利用Dbcom控件,实现通信程序和力控数据的共享,对环境监测数据进行采集管理。 相似文献
875.
建立环境预警监测体系的探讨 总被引:3,自引:0,他引:3
要实现环境保护的"三个转变",环境预警监测处在最前沿.如何建立环境预警监测体系,充分发挥各组成部分的功能,成为目前环境监测的中心工作.本文从环境预警监测工作的作用和重要性入手,分析了体系的组成部分:人才、技术能力和监测质量. 相似文献
876.
Particle-facilitated lead and arsenic transport in abandoned mine sites soil influenced by simulated acid rain 总被引:1,自引:0,他引:1
The role of acid rain in affecting Pb and As transport from mine tailings was investigated by pumping simulated acid rain at a infiltration rate of 10.2 cm/h through soil columns. Simulated acid rain with pH of 3.0, 4.5 and 5.6 were used as leaching solutions. Results showed that 86.9–95.9% of Pb and 90–91.8% of As eluted from the columns were adsorbed by particles in the leachates. Scanning electron microscopy (SEM) analysis showed that particles released from the columns were mainly composed of flocculated aggregates and plate or rod shaped discrete grains. Transmission electron microscopy (TEM) coupled with energy dispersive X-ray analysis (EDX) showed that these particles were predominantly silicate minerals. Results from our experiments demonstrated that when rapid infiltration conditions or a rainstorm exist, particle-facilitated transport of contaminants is likely to the dominant metal transport pathway influenced by acid rain. 相似文献
877.
To evaluate the treatment capability of subsurface flow constructed wetland (SFCW) and the effect of salinity on the degradation of atrazine, the degradation of atrazine in SFCW was studied. Under the static condition, the degradation of atrazine in SFCW followed first-order kinetics: c=0.09679 exp(-0.0396t) (c, residue concentration, mg l(-1); t, retention time, d), with a half-life of approximately 17.5 days. The atrazine degradation kinetic functions were established for salinities of 1.5, 3.0, 5.0, 10.0 and 15.0 g l(-1), respectively, which appeared to approach first-order kinetics. The effect of salinity on the atrazine treatment efficiency showed an exponential inhibition: lnk=3.204+0.04991 C (k, degradation constant; C, NaCl concentration, mg l(-1)). The attenuation of atrazine in SFCW cannot be a result of hydrolysis or sorption process. It was considered that some bacteria in the wetland system degraded atrazine into deethylatrazine (DEA) and deisopropylatrazine (DIA) and sequentially into CO(2) and H(2)O. Salinity impacted on the growth of bacteria resulting in a switch of the microbial community. With the increase of salinity, Shannon-Wiener Diversity Index in the SFCW system declined. The relationship between atrazine degradation constant (k) and Shannon Index was established as shown in linear phase, y=-0.07286+0.0363x. The positive correlation between them indicated that microbial community played an important role in the atrazine degradation process. 相似文献
878.
879.
In this work, the formation of the inclusion complex of bisphenol Z (1,1-bis(4-hydroxyphenyl)cyclohexane, abbreviated as BPCH) with beta-cyclodextrin (beta-CD) has been studied, 1:1 inclusion complex can be obtained, the formation constant of the beta-CD/BPCH complex is 5.94x10(3)M(-1). The photodegradation behavior of BPCH was investigated under monochromatic UV irradiation (lambda=254 nm). The photodegradation rate constant of BPCH in aqueous solutions with beta-CD showed a 9.0-fold increase, and simultaneously the mineralization of BPCH can be enhanced by beta-CD. The influence factors on photodegradation of BPCH were also studied and described in details, such as concentration of beta-CD, initial concentration of BPCH, organic solvent and pH. The photodegradation of BPCH in the presence of beta-CD includes the direct photolysis and the photooxidation of BPCH during the photochemical process. Some predominant photodegradation products are 4-(2,4,5-trihydroxy-phenyl)-4-(4-hydroxyphenyl) butanoic acid, 5,5-bis(4-hydroxyphenyl)pentanoic acid, meta-hydroxylated BPCH, ortho-hydroxylated BPCH and 4-(1-(4-hydroxyphenyl)pentyl)phenol respectively. The enhancement of photodegradation of BPCH mainly results from moderate inclusion depth of BPCH molecule in the beta-CD cavity. This kind of inclusion structure allows BPCH molecule sufficient proximity to secondary hydroxyl groups of the beta-CD cavity, and these hydroxyl groups could be activated and converted to hydroxyl radicals under UV irradiation, which can enhance the photooxidation of BPCH. 相似文献
880.
A combined plasma photolysis (CPP) method for removal of CS2 from gas streams at atmospheric pressure 总被引:1,自引:0,他引:1
A combined plasma photolysis (CPP) reactor that utilizes a dielectric barrier discharge (DBD) plasma and 207 nm UV radiation from discharge-driven KrBr* excimers was designed and constructed. Gas streams containing CS2 were treated with stand-alone DBD and CPP at atmospheric pressure. In comparison to DBD, CPP greatly enhanced the removal efficiency at the same applied voltage, waste gas concentration and gas residence time. Thus the applied voltage could be reduced to a certain extent in the plasma processing of industrial wastes. Influences of the KrBr* radiation, inlet CS2 concentration and gas residence time on CS2 removal by CPP were also studied. In addition, the likely reaction mechanisms for the removal of CS2 by CPP are suggested based on the byproducts analysis. The enhanced removal efficiency and reaction mechanisms implied that the CPP process would probably be suitable for the removal of a large number of gaseous pollutants. 相似文献