In-vehicle VOCs composition of unconditioned, newly produced cars

The in-vehicle volatile organic compounds （VOCs） concentrations gains the attention of both car producers and users. In the present study, an attempt was made to determine if analysis of air samples collected from an unconditioned car cabin can be used as a quality control measure. The VOCs composition of in-vehicle air was analyzed by means of active sampling on Carbograph 1TD and Tenax TA sorbents, followed by thermal desorption and simultaneous analysis on flame ionization and mass detector （TD-GC/FID-MS）. Nine newly produced cars of the same brand and model were chosen for this study. Within these, four of the vehicles were equipped with identical interior materials and five others differed in terms of upholstery and the presence of a sunroof; one car was convertible. The sampling event took place outside of the car assembly plant and the cars tested left the assembly line no later than 24 hr before the sampling took place. More than 250 compounds were present in the samples collected; the identification of more than 160 was confirmed by comparative mass spectra analysis and 80 were confirmed by both comparison with single/multiple compounds standards and mass spectra analysis. In general, aliphatic hydrocarbons represented more than 60% of the total VOCs （TVOC） determined. Depending on the vehicle, the concentration of aromatic hydrocarbons varied from 12% to 27% of total VOCs. The very short period between car production and sampling of the in-vehicle air permits the assumption that the entire TVOC originates from off-gassing of interior materials. The results of this study expand the knowledge of in-vehicle pollution by presenting information about car cabin air quality immediately after car production.     

Sea-level rise in Indonesia: on adaptation priorities in the agricultural sector

Adaptation to climate-change impacts requires understanding of where impacts are to be expected and what their magnitude may be. Adaptation funds are only a limited resource for helping affected parties in coping with climate-change impacts. The application of suitable methods helps to determine the recipients of adaptation aid. A quantification of impacts based on different impact analyses can aid in taking on various perspectives on the same problem in order to identify the appropriate perspective for the given decision-making context or for identifying impact patterns. Once executed, this prioritizes adaptation needs and finding a suitable allocation rule, given the policy makers perception of the decision-making context. The study introduces a set of methods of spatially explicit, sub-national (province level), and country-wide impact analyses regarding inundation impacts on agricultural areas for four important food crops in Indonesia. These methods are applied to a 1 and 2 m sea-level rise scenario and include a novel approach for impact analyses, data envelopment analysis, which is not widely used in environmental studies as of yet. Based on the given case study, the paper demonstrates the applicability of these methods and identifies impact patterns.     

Mitochondrial plasticity in brachiopod (Liothyrella spp.) smooth adductor muscle as a result of season and latitude

Habitat temperature and mitochondrial volume density (Vv_(mt,mf)) are negatively correlated in fishes, while seasonal acclimatization may increase Vv_(mt,mf) or the surface density of the mitochondrial cristae (Sv_(im,mt)). The effect of temperature on invertebrate mitochondria is essentially unknown. A comparison of two articulate brachiopod species, Liothyrella uva collected from Rothera Station, Antarctica in summer 2007, and Liothyrella neozelanica collected from Fiordland, New Zealand in winter 2007 and summer 2008, revealed a higher Vv_(mt,mf) in the Antarctic brachiopod. The Sv_(im,mt) was, however, significantly lower, indicating the Antarctic brachiopods have more, less reactive mitochondria. L. uva, from the colder environment, had larger adductor muscles in both absolute and relative terms than the temperate L. neozelanica. Furthermore, a seasonal comparison (winter vs. summer) in L. neozelanica showed that the absolute and relative size of the adductor increased in winter, Vv_(mt,mf) was unchanged, and Sv_(im,mt) was significantly increased. Thus, seasonal acclimatization to the cold resulted in the same number of more reactive mitochondria. L. neozelanica was clearly able to adapt to seasonal changes using a different mechanism, i.e. primarily through regulation of cristae surface area as opposed to mitochondrial volume density. Furthermore, given the evolutionary age of these living fossils (i.e. approximately 550 million years), this suggests that mitochondrial plasticity has roots extending far back into evolutionary history.     

Does more stringent environmental regulation induce or reduce technology adoption? When the rate of technology adoption is inverted U-shaped

We show that for a broad class of technologies the relationship between policy stringency and the rate of technology adoption is inverted U-shaped. This happens when the marginal abatement cost (MAC) curves of conventional and new technologies intersect, which invariably occurs when emissions are proportional to output and technological progress reduces emissions per output. This outcome does not result from policy failure. On the contrary, in social optimum, the relationship between the slope of the marginal damage curve and the rate of technology adoption is also inverted U-shaped. Under more general conditions, these curves can look even more complicated (e.g., such as inverted W-shaped).     

Emissions standards and ambient environmental quality standards with stochastic environmental services

Many important environmental policies involve some combination of emission controls and ambient environmental quality standards, for instance SO₂ emissions are capped under Title IV of the U.S. Clean Air Act Amendments while ambient SO₂ concentrations are limited under National Ambient Air Quality Standards (NAAQS). This paper examines the relative performance of emissions standards and ambient standards when the natural environment provides stochastic environmental services for assimilating pollution. For receiving media characterized by greater dispersion in the distribution of environmental services, the optimal emissions policy becomes more stringent, whereas the optimal ambient policy generally becomes more lax. In terms of economic performance, emissions policies are superior to ambient policies for relatively non-toxic pollutants, whereas ambient standards welfare dominate emissions standards for sufficiently toxic pollutants. In the case of combined policies that jointly implement emissions standards and ambient standards, we show that the optimal level of each standard relaxes relative to its counterpart in a unilateral policy, allowing for greater emissions levels and higher pollution concentrations in the environmental medium.     

Degradation of 4-fluorobiphenyl in soil investigated by 19F NMR spectroscopy and 14C radiolabelling analysis

The incubation of the model pollutant [U-14C]'-4-fluorobiphenyl (4FBP) in soil, in the presence and absence of biphenyl (a co-substrate), was carried out in order to study the qualitative disposition and fate of the compound using 14C-HPLC and 19F NMR spectroscopy. Components accounted for using the radiolabel were volatilization, CO2 evolution, organic solvent extractable and bound residue. Quantitative analysis of these data gave a complete mass balance. After sample preparation. 14C-HPLC was used to establish the number of 4FBP related components present in the organic solvent extract. 19F NMR was also used to quantify the organic extracts and to identify the components of the extract. Both approaches showed that the composition of the solvent extractable fractions comprised only parent compound with no metabolites present. As the 14C radiolabel was found to be incorporated into the soil organic matter this indicates that metabolites were being generated, but were highly transitory as incorporation into the SOM was rapid. The inclusion of the co-substrate biphenyl was to increase the overall rate of degradation of 4FBP in soil. The kinetics of disappearance of parent from the soil using the data obtained were investigated from both techniques. This is the first report describing the degradation of a fluorinated biphenyl in soil.     

Pragmatics of Policy: The Compliance of Dutch Environmental Policy Instruments to European Union Standards

Despite a general decrease in Dutch environmental emission trends, it remains difficult to comply with European Union (EU) environmental policy targets. Furthermore, environmental issues have become increasingly complex and entangled with society. Therefore, Dutch environmental policy follows a pragmatic line by adopting a flexible approach for compliance, rather than aiming at further reduction at the source of emission. This may be politically useful in order to adequately reach EU targets, but restoration of environmental conditions may be delayed. However, due to the complexity of today’s environmental issues, the restoration of environmental conditions might not be the only standard for a proper policy approach. Consequently this raises the question how the Dutch pragmatic approach to compliance qualifies in a broader policy assessment. In order to answer this question, we adapt a policy assessment framework, developed by Hemerijck and Hazeu (Bestuurskunde 13(2), 2004), based on the dimensions of legitimacy and policy logic. We apply this framework for three environmental policy assessments: flexible instruments in climate policy, fine-tuning of national and local measures to meet air quality standards, and derogation for the Nitrate Directive. We conclude with general assessment notes on the appliance of flexible instruments in environmental policy, showing that a broad and comprehensive perspective can help to understand the arguments to put such policy instruments into place and to identify trade-offs between assessment criteria.     

Armed conflict distribution in global drylands through the lens of a typology of socio-ecological vulnerability

Motivated by an inconclusive debate over implications of resource scarcity for violent conflict, and common reliance on national data and linear models, we investigate the relationship between socio-ecological vulnerability and armed conflict in global drylands on a subnational level. Our study emanates from a global typology of smallholder farmers’ vulnerability to environmental and socioeconomic stresses in drylands. This typology is composed of eight typical value combinations of variables indicating environmental scarcities, resource overuse, and poverty-related factors in a widely subnational spatial resolution. We investigate the relationships between the spatial distribution of these combinations, or vulnerability profiles, and geocoded armed conflicts, and find that conflicts are heterogeneously distributed according to these profiles. Four profiles distributed across low- and middle-income countries comprise all drylands conflicts. Comparing models for conflict incidence using logit regression and receiver operator characteristic analysis based on (1) the set of all seven indicators as independent variables and (2) a single, only vulnerability profile-based variable proves that the nonlinear typology-based variable is the better explanans for conflict incidence. Inspection of the profiles’ value combinations makes this understandable: A systematic explanation of conflict incidence and absence across all degrees of natural resource endowments is only reached through varying importance of poverty and resource overuse depending on the level of endowment. These are nonlinear interactions between the explaining variables. Conflict does not generally increase with resource scarcity or overuse. Comparison with conflict case studies showed both good agreement with our results and promise in expanding the set of indicators. Based on our findings and supporting literature, we argue that part of the debate over implications of resource scarcity for violent conflict in drylands may be resolved by acknowledging and accounting for nonlinear processes.