Dairy farm effluent effects on urine patch nitrous oxide and carbon dioxide emissions

Dairy farm effluent (DFE) comprises animal feces, urine, and wash-down water collected at the milking shed. This is collected daily during the milking season and sprayed onto grazed dairy pastures. Urine patches in grazed pastures make a significant contribution to anthropogenic N(2)O emissions. The DFE could potentially mitigate N(2)O emissions by influencing the N(2)O to dinitrogen (N(2)) ratio, since it contains water-soluble carbon (WSC). Alternatively, DFE may enhance N(2)O emissions from urine patches. The application of DFE may also provide a substrate for the production of CO(2) in pasture soils. The effects of DFE on the CO(2) and N(2)O emissions from urine patches are unknown. Thus a laboratory experiment was performed where repeated DFE applications were made to repacked soil cores. Dairy farm effluent was applied at 0, 7, or 14 d after urine deposition. The urine was applied once on Day 0. Urine contained (15)N-enriched urea. Measurements of N(2)O, N(2), and carbon dioxide (CO(2)) fluxes, soil pH, and soil inorganic N concentrations were made. After 43 d the DFE had not mitigated N(2)O fluxes from urine patches. A small increase in the N(2)O flux occurred from the urine-treated soils where DFE was applied 1 wk after urine deposition. The amount of WSC applied in the DFE proved to be insignificant compared with the amount of soil C released as CO(2) following urine application. The priming of soil C in urine patches has implications for the understanding of soil C processes in grazed pasture ecosystems and the budgeting of C within these ecosystems.     

Experimental and natural changes in the peacock's (Pavo cristatus) train can affect mating success

Petrie et al. (1991) demonstrated a correlation between the degree of elaboration of peacocks' trains and their mating success, and also showed that this correlation occurred because females preferred to mate with the male that had the most elaborate train of those sampled on the lek. Although these data suggest that female choice is responsible for non-random mating in this species, they do not conclusively show that train morphology is the cue that females respond to, because they do not rule out the possible influence of another unidentified variable which is correlated with train elaboration. This paper presents an experimental test of the importance of the peacock's train in determining male mating success. If the number or arrangement of eye-spots in the peacock's train influences mating success, then changing the number of eye-spots should change mating success. This prediction was tested in an experiment where the trains of male peafowl (Pavo cristatus) were manipulated by removing a number of eye-spots between mating seasons. Peacocks with eye-spots removed showed a significant decline in mating success between seasons compared with a control group. This result, together with the observational data, supports the hypothesis that the peacock's train has evolved, at least in part, as a result of female choice.     

Development of a hazardous air pollutants monitoring program using the Data Quality Objectives process

To effectively reduce the environmental compliance costs associated with meeting hazardous air pollutant emission requirements, the U.S. Environmental Protection Agency's Data Quality Objective (DQO) process has been proposed as a suitable framework for establishing a defensible monitoring program. Through the use of a hazardous materials pilot study, the variability in the composite vapor pressure for regulated handwipe cleaning solvents was established. These results served as inputs to the DQO process, which identified that for facility decision-makers to claim with a 99% confidence level that the facility is in compliance with the National Emission Standards for Hazardous Air Pollutants (NESHAP), a minimum of 12 handwipe cleaning solvent compliance samples (taken at random every 6 months) must have a composite vapor pressure equal to or below the regulatory limit of 45 mmHg at 20 degrees C. Implementation of the DQO-based compliance-sampling plan eliminates the need for an affected facility to sample all regulated handwipe cleaning solvents while still maintaining a reasonably high level of confidence in the compliance status of its regulated sources. The approach described for designing a defensible compliance sampling plan can be extended to other aspects of the aerospace NESHAP rule, including compliance sampling for surface coating, chemical depainting, and hazardous waste disposal.     

The estimation of PAH bioavailability in contaminated sediments using hydroxypropyl-beta-cyclodextrin and Triton X-100 extraction techniques

A study was conducted to investigate whether cyclodextrins and surfactants can be used to predict polycyclic aromatic hydrocarbon (PAH) bioavailability in contaminated sediments. Two sediment samples were extracted with aqueous solutions of hydroxypropyl-beta-cyclodextrin (HPCD) and Triton X-100. PAH removal during extraction was compared with PAH removal during biodegradation and solid-phase extraction. The latter two methods were used as reference methods to establish which part of the PAHs could be biodegraded and to what extent biodegradation was governed by bioavailability limitations. It was demonstrated that HPCD extraction followed solid-phase extraction and removed primarily readily bioavailable PAHs, while Triton X-100 extracted both readily and poorly bioavailable PAHs. Moreover, HPCD did not affect the degradation of PAHs in biodegradation experiments, while Triton X-100 enhanced the degradation of low molecular weight PAHs. It was concluded that HPCD extraction may provide a good method for the prediction of PAH bioavailability. Triton X-100 extraction is unfit for the prediction of PAH bioavailability.     

The effect of diesel fuel sulfur content on particulate matter emissions for a nonroad diesel generator

The effect of sulfur content on diesel particulate matter (DPM) emissions was studied using a diesel generator (Generac Model SD080, rated at 80 kW) as the emission source to simulate nonroad diesel emissions. A load simulator was used to apply loads to the generator at 0, 25, 50, and 75 kW, respectively. Three diesel fuels containing 500, 2100, and 3700 ppm sulfur by weight were selected as generator fuels. The U.S. Environmental Protection Agency sampling Method 5 "Determination of Particulate Matter Emissions from Stationary Sources" together with Method 1A "Sample and Velocity Traverses for Stationary Sources with Small Stacks or Ducts" was adopted as a reference method for measurement of the exhaust gas flow rate and DPM mass concentration. The effects of various parameters on DPM concentration have been studied, such as fuel sulfur contents, engine loads, and fuel usage rates. The increase of average DPM concentrations from 3.9 mg/Nm3 (n cubic meter) at 0 kW to 36.8 mg/Nm3 at 75 kW is strongly correlated with the increase of applied loads and sulfur content in the diesel fuel, whereas the fuel consumption rates are only a function of applied loads. An empirical correlation for estimating DPM concentration is obtained when fuel sulfur content and engine loads are known for these types of generators: Y = Zm(alphaX + beta), where Y is the DPM concentration, mg/m3, Z is the fuel sulfur content, ppm(w) (limited to 500-3700 ppm(w)), X is the applied load, kW, m is the constant, 0.407, alpha and beta are the numerical coefficients, 0.0118 +/- 0.0028 (95% confidence interval) and 0.4535 +/- 0.1288 (95% confidence interval), respectively.     

弘文重教十余年的《文教资料简报》

创刊于1972年12月的《文教资料简报》是由南京师范学院(1984年易名为南京师范大学)内部编印的资料性月刊,主要目的是为文科教研服务。本文回顾该刊从创办至拥有统一刊号、从非正式出版物至成为正式出版物的历史沿革,具体观照该刊的编辑理念,总结该刊的内容特色、文献价值及经验启示。     

Introduced and cryptogenic species in Port Phillip Bay, Victoria, Australia

Port Phillip Bay (PPB) is a large (1,930 km²), temperate embayment in southern Victoria, Australia. Extensive bay-wide surveys of PPB have occurred since 1840. In 1995/1996 the Commonwealth Scientific and Industrial Research Organization (CSIRO) Centre for Research on Introduced Marine Pests (CRIMP) undertook an intensive evaluation of the region with the aims of developing a comprehensive species list of native and introduced biota and contrasting previous bay-wide assessments with a current field survey in order to detect new incursions and discern alterations to native communities. Two methods were used to meet these aims: a re-evaluation of regional museum collections and published research in PPB to identify and determine the timing of introductions; and field surveys for benthic (infauna, epifauna and encrusting) organisms between September 1995 to March 1996. One hundred and sixty introduced (99) and cryptogenic (61) species were identified representing over 13% of the recorded species of PPB. As expected, the majority of these are concentrated around the shipping ports of Geelong and Melbourne. Invasions within PPB appear to be increasing, possibly due to an increase in modern shipping traffic and an increase in aquaculture (historically associated with incidental introductions); however the records of extensive biological surveys suggest that this may, in part, be an artefact of sampling effort. In contrast to Northern Hemisphere studies, PPB (and Southern Hemisphere introductions in general) have significantly different suites of successfully invading taxa. PPB is presented as one of the most invaded marine ecosystems in the Southern Hemisphere.Communicated by M.S. Johnson, Crawley     

Bewertung der potenziellen Grundwasserbelastung von deponierten Hochofengasschlämmen

Goal and Scope

Blast-furnace sludge is a waste originating from pig-iron production and contains contaminants such as lead, zinc, fluoride and cyanide assumably contaminating the groundwater by leaching.

Methods

We investigated the chemical composition of 27 samples of landfilled blast-furnace sludge in pore waters which were obtained by the centrifugation of fresh material and elution with water according to DIN 38414 part 4 (S 4).

Results

The pore waters as well as the eluates were neutral to alkaline (pH 7.3 to 10.7) and were dominated by alkali and alkaline-earth metals as well as sulphate and nitrate. The concentrations of all elements and compounds investigated were mostly clearly larger in the pore waters than in the eluates. The average concentrations of environmentally relevant constituents such as lead (0,18 mg?1), zinc (1,5 mg l?1), fluoride (10,6 mg l?1), and total cyanide (1.8 mg l?1) in the pore waters were distinctly larger than the inspection value of the German Federal soil Protection Ordinance for the pathway soil-groundwater. Lead, zinc, and total cyanide concentrations in the pore waters were largely underestimated by the eluates, as these concentrations were 70 to 90% lower in the eluates compared to the pore waters.

Conclusion

In the case of landfilled blast-furnace sludge, eluates according to DIN 38414 part 4 (S 4) provide low concentrations which are unrealistic to forecast concentrations in the seepage water.     

The organic composition of diesel particulate matter, diesel fuel and engine oil of a non-road diesel generator

Diesel-powered equipment is known to emit significant quantities of fine particulate matter to the atmosphere. Numerous organic compounds can be adsorbed onto the surfaces of these inhalable particles, among which polycyclic aromatic hydrocarbons (PAHs) are considered potential occupational carcinogens. Guidelines have been established by various agencies regarding diesel emissions and various control technologies are under development. The purpose of this study is to identify, quantify and compare the organic compounds in diesel particulate matter (DPM) with the diesel fuel and engine oil used in a non-road diesel generator. Approximately 90 organic compounds were quantified (with molecular weight ranging from 120 to 350), which include alkanes, PAHs, alkylated PAHs, alkylbenzenes and alkanoic acids. The low sulfur diesel fuel contains 61% alkanes and 7.1% of PAHs. The identifiable portion of the engine oil contains mainly the alkanoic and benzoic acids. The composition of DPM suggests that they may be originated from unburned diesel fuel, engine oil evaporation and combustion generated products. Compared with diesel fuel, DPM contains fewer fractions of alkanes and more PAH compounds, with the shift toward higher molecular weight ones. The enrichment of compounds with higher molecular weight in DPM may be combustion related (pyrogenic).